Open Access. Powered by Scholars. Published by Universities.®

Physical Chemistry Commons

Open Access. Powered by Scholars. Published by Universities.®

SelectedWorks

Dihedral angle

Publication Year

Articles 1 - 2 of 2

Full-Text Articles in Physical Chemistry

2-(3-Nitrophenoxy)Quinoxaline, Hairul Anuar Bin Tajuddin Jan 2010

2-(3-Nitrophenoxy)Quinoxaline, Hairul Anuar Bin Tajuddin

Hairul Anuar Bin Tajuddin

In the title molecule, C(14)H(9)N(3)O(3), the dihedral angle between the quinoxaline and benzene rings is 77.13 (9)degrees. The molecule is twisted about the ether-benzene O-C bond, with a C-O-C-C torsion angle of -102.8 (2)degrees. In the crystal, molecules are linked by C-H center dot center dot center dot O hydrogen bonds, forming layers in the ab plane, with one nitro O atom accepting two such interactions. The layers stack along the c-axis direction via weak C-H center dot center dot center dot pi interactions.


Quinoxalin-2-Yl O-Tolyl Ether, Hairul Anuar Bin Tajuddin Jan 2008

Quinoxalin-2-Yl O-Tolyl Ether, Hairul Anuar Bin Tajuddin

Hairul Anuar Bin Tajuddin

The dihedral angle between the two aromatic ring systems in the title compound, C(15)H(12)N(2)O, is 85.9 (1)degrees; The angle at the O atom is widened to 118.2 (2)degrees. The quinoxalinyloxy part of the molecule lies on a mirror plane and the tolyl group is disordered over two positions about the mirror plane.