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Full-Text Articles in Physical Chemistry
The Investigation Of Epr Paramagnetic Probe Line Width And Shape Temperature Dependence In High-Temperature Superconductors Of Bi–Pb–Sr–Ca–Cu–O System, J. G. Chigvinadze, Juana Vivó Acrivos, I. G. Akhvlediani, M. I. Chubabria, T. L. Kalabegishvili, T. I. Sanadze
The Investigation Of Epr Paramagnetic Probe Line Width And Shape Temperature Dependence In High-Temperature Superconductors Of Bi–Pb–Sr–Ca–Cu–O System, J. G. Chigvinadze, Juana Vivó Acrivos, I. G. Akhvlediani, M. I. Chubabria, T. L. Kalabegishvili, T. I. Sanadze
Faculty Publications, Chemistry
The work is related with the finding out of magnetic phases in strongly anisotropic high-temperature superconductor Bi1,7Pb0,3Sr2Ca2Cu3O10-δ in the temperature region where the superconductor is in the normal state. It was studied the temperature dependence of the paramagnetic probe EPR line width. In the normal state at T>Tc near 175 K it was revealed a pick in the temperature dependence of line width. In this region it was observed the time increase of the line width with the characteristic time ~ 17 min. This shows the possibility of magnetic phase formation in this material.
The Investigation Of Epr Paramagnetic Probe Line Width And Shape Temperature Dependence In High-Temperature Superconductors Of Bi–Pb–Sr–Ca–Cu–O System, J. G. Chigvinadze, Juana Vivó Acrivos, I. G. Akhvlediani, M. I. Chubabria, T. L. Kalabegishvili, T. I. Sanadze
The Investigation Of Epr Paramagnetic Probe Line Width And Shape Temperature Dependence In High-Temperature Superconductors Of Bi–Pb–Sr–Ca–Cu–O System, J. G. Chigvinadze, Juana Vivó Acrivos, I. G. Akhvlediani, M. I. Chubabria, T. L. Kalabegishvili, T. I. Sanadze
Juana Vivó Acrivos
The work is related with the finding out of magnetic phases in strongly anisotropic high-temperature superconductor Bi1,7Pb0,3Sr2Ca2Cu3O10-δ in the temperature region where the superconductor is in the normal state. It was studied the temperature dependence of the paramagnetic probe EPR line width. In the normal state at T>Tc near 175 K it was revealed a pick in the temperature dependence of line width. In this region it was observed the time increase of the line width with the characteristic time ~ 17 min. This shows the possibility of magnetic phase formation in this material.
Analysis Of The A3(X3)3 Nuclear Spin System And -Electron Coupled Hyperfine Splitting Constants In Aromatic Hydrocarbons, Juana Acrivos
Analysis Of The A3(X3)3 Nuclear Spin System And -Electron Coupled Hyperfine Splitting Constants In Aromatic Hydrocarbons, Juana Acrivos
Faculty Publications, Chemistry
The nuclear spin functions for the A3(X3)3 system have been developed and used to analyse the NMR spectra of (CH3)3C6H3 and (CF3)3C6H3. The π-electron coupled hyperfine splitting constants, obtained from the Ramsey theory with simple Hückel M.O.'s for benzene and without the assumption of an average energy of excitation for the virtual processes which give rise to the coupling, are in agreement with the hyperfine constants observed between the methyl groups and the ring protons in the above compounds.