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Articles 1 - 18 of 18
Full-Text Articles in Physical Chemistry
Some Features Of The Concentration Oscillations In The Phenylacetylene Oxidative Carbonylation Reaction (In Russian), Sergey N. Gorodsky
Some Features Of The Concentration Oscillations In The Phenylacetylene Oxidative Carbonylation Reaction (In Russian), Sergey N. Gorodsky
Sergey N. Gorodsky
Some modes of concentration oscillations in the homogeneous system KI-PdI2-CO-O2-CH3OH are described in this paper.
Energetyka Niskoemisyjna, Wojciech M. Budzianowski
Energetyka Niskoemisyjna, Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Absolute Ground-State Nitrogen Atom Density In A N2/Ch4 Late Afterglow: Talif Experiments And Modelling Studies, Et. Es-Sebbar, M.-C. Gazeau, Y. Benilan, A. Jolly, C D. Pintassilgo
Absolute Ground-State Nitrogen Atom Density In A N2/Ch4 Late Afterglow: Talif Experiments And Modelling Studies, Et. Es-Sebbar, M.-C. Gazeau, Y. Benilan, A. Jolly, C D. Pintassilgo
Dr. Et-touhami Es-sebbar
Following a first study on a late afterglow in flowing pure nitrogen post discharge, we report new two-photon absorption laser-induced fluorescence (TALIF) measurements of the absolute ground-state atomic nitrogen density N(4S) and investigate the influence of methane introduced downstream from the discharge by varying the CH4 mixing ratio from 0% up to 50%. The N (4S) maximum density is about 2.2 × 1015 cm−3 in pure N2 for a residence time of 22 ms and does not change significantly for methane mixing ratio up to ~15%, while above, a drastic decrease is observed. The influence of the residence time has …
Experimental And Theoretical Studies On Nitrogen Plasma And Methane Photolysis: Implications For Laboratory Simulations Of Titan’S Atmosphere, M-C. Gazeau, Y. Benilan, E. Arzoumanian, Et. Es-Sebbar, A. Jolly
Experimental And Theoretical Studies On Nitrogen Plasma And Methane Photolysis: Implications For Laboratory Simulations Of Titan’S Atmosphere, M-C. Gazeau, Y. Benilan, E. Arzoumanian, Et. Es-Sebbar, A. Jolly
Dr. Et-touhami Es-sebbar
No abstract provided.
Spectroscopic Studies Applied To Uvis Observations Of Titan, Y. Benilan, F. Capalbo, Et. Es-Sebbar, N. Fray, A. Jolly, M-C. Gazeau, J-C. Guillemin, M. Schwell
Spectroscopic Studies Applied To Uvis Observations Of Titan, Y. Benilan, F. Capalbo, Et. Es-Sebbar, N. Fray, A. Jolly, M-C. Gazeau, J-C. Guillemin, M. Schwell
Dr. Et-touhami Es-sebbar
No abstract provided.
Talif Investigation And Modelling Of The Absolute N(4s) Density In A N2-Ch4 Late Afterglow, C.D. Pintassilgo, Et. Es-Sebbar, Y. Benilan, M-C. Gazeau, A. Jolly
Talif Investigation And Modelling Of The Absolute N(4s) Density In A N2-Ch4 Late Afterglow, C.D. Pintassilgo, Et. Es-Sebbar, Y. Benilan, M-C. Gazeau, A. Jolly
Dr. Et-touhami Es-sebbar
The purpose of the present work is the experimental and numerical study of the absolute ground-state nitrogen atoms density N(4S) in the late afterglow of a pure N2 flowing microwave discharge in which different amounts of CH4 have been injected at 25 cm downstream from the nitrogen discharge. The absolute N(4S) concentrations have been measured using Two-photon Absorption Laser-Induced Fluorescence (TALIF), while a detailed kinetic model has been developed to simulate both the discharge and the post-discharge regions. Theoretical predictions are then compared to experimental measurements.
Combined Experimental And Theoretical Studies On Methane Photolysis At 121.6 Nm And 248 Nm- Implications On A Program Of Laboratory Simulations Of Titan’S Atmosphere, C. Romanzin, E. Arzoumanian, Et. Es-Sebbar, A. Jolly, S. Perrier, M.-C. Gazeau, Y. Bénilan
Combined Experimental And Theoretical Studies On Methane Photolysis At 121.6 Nm And 248 Nm- Implications On A Program Of Laboratory Simulations Of Titan’S Atmosphere, C. Romanzin, E. Arzoumanian, Et. Es-Sebbar, A. Jolly, S. Perrier, M.-C. Gazeau, Y. Bénilan
Dr. Et-touhami Es-sebbar
Methane is, together with N2, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C2H2 (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH3, CH2 and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry …
Temperature-Dependent Photoabsorption Cross-Section Of Cyano-Diacetylene In The Vacuum Uv, N. Fray, Y. Bénilan, M.-C. Gazeau, A. Jolly, M. Schwell, E. Arzoumanian, Et. Es-Sebbar, T. Ferradaz, J.- C. Guillemin
Temperature-Dependent Photoabsorption Cross-Section Of Cyano-Diacetylene In The Vacuum Uv, N. Fray, Y. Bénilan, M.-C. Gazeau, A. Jolly, M. Schwell, E. Arzoumanian, Et. Es-Sebbar, T. Ferradaz, J.- C. Guillemin
Dr. Et-touhami Es-sebbar
Using synchrotron radiation as a tunable VUV light source, we have measured, for the first time, the absolute photoabsorption cross sections of HC5N with a spectral resolution of 0.05 nm in the region between 80 and 205 nm from 233 to 298 K. The measured cross sections are used to predict the HC5N photodestruction rate in the solar system and to model a transmission spectrum in Titan's atmosphere. Comparing the latter with that acquired by the Ultraviolet Imaging Spectrograph on board the Cassini spacecraft, we have determined an upper limit of 2.7 × 10−5 on the HC5N abundance at 1100 …
Improvement Of The Stoichiometric Network Analysis For Determination Of Instability Conditions Of Complex Nonlinear Reaction Systems, Zeljko D. Cupic
Improvement Of The Stoichiometric Network Analysis For Determination Of Instability Conditions Of Complex Nonlinear Reaction Systems, Zeljko D. Cupic
Zeljko D Cupic
No abstract provided.
Grafika Inżynierska Ćw., Wojciech M. Budzianowski
Grafika Inżynierska Ćw., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Projektowanie Procesów Biotechnologicznych Proj., Wojciech M. Budzianowski
Projektowanie Procesów Biotechnologicznych Proj., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Projektowanie I Optymalizacja Procesów Proj., Wojciech M. Budzianowski
Projektowanie I Optymalizacja Procesów Proj., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Metody Numeryczne Lab., Wojciech M. Budzianowski
Metody Numeryczne Lab., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Odnawialne Źródła Energii W., Wojciech M. Budzianowski
Odnawialne Źródła Energii W., Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Size Effect Of Ruthenium Nanoparticles In Catalytic Carbon Monoxide Oxidation, Sang Hoon Joo, Jeong Y. Park, J. Russell Renzas, Derek R. Butcher, Wenyu Huang, Gabor A. Somorjai
Size Effect Of Ruthenium Nanoparticles In Catalytic Carbon Monoxide Oxidation, Sang Hoon Joo, Jeong Y. Park, J. Russell Renzas, Derek R. Butcher, Wenyu Huang, Gabor A. Somorjai
Wenyu Huang
Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac)3 precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O2) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm …
Highly Active Heterogeneous Palladium Nanoparticle Catalysts For Homogeneous Electrophilic Reactions In Solution And The Utilization Of A Continuous Flow Reactor, Wenyu Huang, Jack Hung Chang Liu, Pinar Alayoglu, Yimin Li, Cole A. Whitman, Chia-Kuang Tsung, F. Dean Toste, Gabor A/ Somorjai
Highly Active Heterogeneous Palladium Nanoparticle Catalysts For Homogeneous Electrophilic Reactions In Solution And The Utilization Of A Continuous Flow Reactor, Wenyu Huang, Jack Hung Chang Liu, Pinar Alayoglu, Yimin Li, Cole A. Whitman, Chia-Kuang Tsung, F. Dean Toste, Gabor A/ Somorjai
Wenyu Huang
highly active heterogeneous Pd-nanoparticle catalyst for the intramolecular addition of phenols to alkynes was developed and employed in a continuous flow reaction system. Running the reaction in flow mode revealed reaction kinetics, such as the activation energy and catalyst deactivation, and provides many potential practical advantages.
Seedless Polyol Synthesis And Co Oxidation Activity Of Monodisperse (111)- And (100)-Oriented Rhodium Nanocrystals In Sub-10 Nm Sizes, Yawen Zhang, Michael E. Grass, Wenyu Huang, Gabor A. Somoraji
Seedless Polyol Synthesis And Co Oxidation Activity Of Monodisperse (111)- And (100)-Oriented Rhodium Nanocrystals In Sub-10 Nm Sizes, Yawen Zhang, Michael E. Grass, Wenyu Huang, Gabor A. Somoraji
Wenyu Huang
Monodisperse sub-10 nm (6.5 nm) sized Rh nanocrystals with (111) and (100) surface structures were synthesized by a seedless polyol reduction in ethylene glycol, with poly(vinylpyrrolidone) as a capping ligand. When using [Rh(Ac)2]2 as the metal precursor, (111)-oriented Rh nanopolyhedra containing 76% (111)-twinned hexagons (in 2D projection) were obtained; whereas, when employing RhCl3 as the metal precursor in the presence of alkylammonium bromide, such as tetramethylammonium bromide and trimethyl(tetradecyl)ammonium bromide, (100)-oriented Rh nanocubes were obtained with 85% selectivity. The {100} faces of the Rh nanocrystals are stabilized by chemically adsorbed Br− ions from alkylammonium bromides, which led to (100)-oriented nanocubes. …
Furan Hydrogenation Over Pt(111) And Pt(100) Single-Crystal Surfaces And Pt Nanoparticles From 1 To 7 Nm: A Kinetic And Sum Frequency Generation Vibrational Spectroscopy Study, Christopher J. Kliewer, Cesar Aliaga, Marco Bieri, Wenyu Huang, Chia-Kuang Tsung, Jennifer B. Wood, Kyriankos Komvopoulos, Gabor A. Somorjai
Furan Hydrogenation Over Pt(111) And Pt(100) Single-Crystal Surfaces And Pt Nanoparticles From 1 To 7 Nm: A Kinetic And Sum Frequency Generation Vibrational Spectroscopy Study, Christopher J. Kliewer, Cesar Aliaga, Marco Bieri, Wenyu Huang, Chia-Kuang Tsung, Jennifer B. Wood, Kyriankos Komvopoulos, Gabor A. Somorjai
Wenyu Huang
Sum frequency generation surface vibrational spectroscopy and kinetic measurements using gas chromatography have been used to systematically study the adsorption and hydrogenation of furan over Pt(111) and Pt(100) single-crystal surfaces and size-controlled 1.0-nm, 3.5-nm and 7.0-nm Pt nanoparticles at Torr pressures (10 Torr of furan, 100 Torr of H2) to form dihydrofuran, tetrahydrofuran, and the ring-cracking products butanol and propylene. As determined by SFG, the furan ring lies parallel to all Pt surfaces studied under hydrogenation conditions. Upright THF and the oxametallacycle intermediate are observed over the nanoparticle catalysts under reaction conditions. Butoxy increases in surface concentration over Pt(111) with …