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Physical Chemistry Commons

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Computational Chemistry

Chinese Chemical Society | Xiamen University

1997

Articles 1 - 2 of 2

Full-Text Articles in Physical Chemistry

Calculation Of The Sacrificial Anode Resistance Utilizing Boundary Element Method, Jianhua Wu, Mingxian Sun, Guangzhou Liu, Guangzhang Chen Nov 1997

Calculation Of The Sacrificial Anode Resistance Utilizing Boundary Element Method, Jianhua Wu, Mingxian Sun, Guangzhou Liu, Guangzhang Chen

Journal of Electrochemistry

According to a kind of mathematic model set up for the cathodic protection potential field, the boundary element method (BEM) was used to study the working state of plate sacrificial anodes which were galvanically coupled to mild steel. In situ experiment showed that the current output and resistance of sacrificial anodes could be calculated more accurately using BEM than loiyd formula. On the basis of the calculation, the cathodic protection design would be more accurate. It was also investigated that the effect of the lengthtobreadth ratio (L/B) on current output and resistance of plate zinc anodes. The results demonstrated that …


Corrosion Behaviour Of Copper Covered With Ion Selective Phenolic Coatings By Eis, Zhoucheng Wang, Yingzhou Zhang, Shaomin Zhou Aug 1997

Corrosion Behaviour Of Copper Covered With Ion Selective Phenolic Coatings By Eis, Zhoucheng Wang, Yingzhou Zhang, Shaomin Zhou

Journal of Electrochemistry

Electrochemical impedance spectroscopy(EIS) technique was employed to study the corrosion behaviour of copper painted with the anion selective、 cation selective and bipolar phenolic coatings in 3% NaCl solution. From the impedance spectrum characteristics, the models of equivalent circuit for these different coating systems were established,and the methods for the analysis of experimental impedance diagrams in terms of coating and interface properties were discussed. The research results show that the composition and structure of ion selective coatings have significant influence on corrosion behaviour of copper. The bipolar coating consisting of an anion selective inner layer and a cation selective outer layer …