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Full-Text Articles in Materials Chemistry
Optimized Electrochemical Performance Of Si@C Prepared By Hydrothermal Reaction And Glucose Carbon Source, Si Chen, Song-Sheng Zheng, Lei-Ming Zheng, Ye-Han Zhang, Zhao-Lin Wang
Optimized Electrochemical Performance Of Si@C Prepared By Hydrothermal Reaction And Glucose Carbon Source, Si Chen, Song-Sheng Zheng, Lei-Ming Zheng, Ye-Han Zhang, Zhao-Lin Wang
Journal of Electrochemistry
Silicon (Si) has been considered as the potential material for the next-generation lithium-ion batteries (LIBs) for its high capacity (4200 mAh·g-1, Li22Si5) and suitable working voltage (about 0.25 V vs. Li/Li+). However, the cycling stability and electrochemical performance of Si anode become significant challenges because of low intrinsic conductivity and huge volume variation (about 400%) during cycling processes. In addition, the repeated formation and destruction of surface solid electrolyte interphase (SEI) film will continuously consume the electrolyte and cause damage to LIBs. Carbon (C) materials, such as graphite, carbon spheres and tubes, have been widely applied …