Open Access. Powered by Scholars. Published by Universities.®
- Keyword
Articles 1 - 2 of 2
Full-Text Articles in Materials Chemistry
Alkane Adsorption On Mgo(100): Volumetric Isotherm, Inelastic Neutron Scattering, And Computational Studies, Andrew Spencer Hicks
Alkane Adsorption On Mgo(100): Volumetric Isotherm, Inelastic Neutron Scattering, And Computational Studies, Andrew Spencer Hicks
Doctoral Dissertations
Volumetric adsorption isotherms and computational molecular dynamics (MD) simulations were performed for nonane and decane adfilms on MgO(100) nanocubes. From the isotherms, variety of thermodynamic quantities are calculated. These values, along with visual inspection of the isotherms, indicate a layer by layer trend from 2D to 3D behavior. This is attributed to the increasing importance of vertical adsorbate-adsorbate interactions as distance from the surface increases. Additionally, a 2D phase transition is observed for the first adsorbed layer as indicated by the evolution of the widths of the isotherm first derivative peaks. These experimental results are complemented by the MD calculations, …
Carbon Nitride And Conjugated Polymer Composite Materials, Josh Byers
Carbon Nitride And Conjugated Polymer Composite Materials, Josh Byers
Electronic Thesis and Dissertation Repository
The semiconductor and photovoltaic properties of carbon nitride (CNx) thin films prepared using a reactive magnetron sputtering technique were investigated both individually and as composites with the organic conjugated polymers polybithiophene (PBT) and poly(3-hextlthiophene) (P3HT). At low nitrogen content, the film structure was dominated by graphitic sp2 percolation networks, whereas at higher nitrogen contents CNx films started to demonstrate semiconductor properties, as evidenced by the occurrence of photoconductivity and the development of a space charge region. When CNx was deposited onto a PBT substrate, it was found to function as an acceptor material improving the photocurrent generation both in …