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Full-Text Articles in Materials Chemistry

Evaluation Of Low-Temperature Fluoride Routes To Synthesize Actinide Nitrides And Oxide Solid Solutions, Gunanda Waduge Chinthaka Silva May 2009

Evaluation Of Low-Temperature Fluoride Routes To Synthesize Actinide Nitrides And Oxide Solid Solutions, Gunanda Waduge Chinthaka Silva

UNLV Theses, Dissertations, Professional Papers, and Capstones

Actinide mononitrides have been considered as a possible nuclear fuel for the Generation-IV nuclear reactor systems. In the process of evaluating these actinide mononitrides as nuclear fuel, it is important to study different chemical and physical characteristics of these compounds. Synthesis of the materials is thus important. Carbothermic reduction is one of the techniques that have been used to synthesize actinide mononitrides. In this method, a mixture of actinide oxide such as UO 2 and excess carbon is heat treated at temperatures greater than 1700 °C under a nitrogen atmosphere. The technique is however not promising in synthesizing the actinide …


Advanced Radiometry For High Discrimination Explosive Fireball Discrimination, Steven E. Slagle Mar 2009

Advanced Radiometry For High Discrimination Explosive Fireball Discrimination, Steven E. Slagle

Theses and Dissertations

The high explosive fireball phenomenological model for the mid wave infrared spectrum, developed by AFIT, performs classification from spectral signatures was modified to use radiometric intensities. Five bands were sequentially fit to derive the five physical fit parameters describing the fireball's temperature, size, soot absorption coefficient within 16% and emissions from the H2O and CO2 concentrations within 333% of the spectral model. This was improved by changing the model's band sizes, center, and fitting methods where all five fit parameters were matched to within 17% of spectral model. This demonstrated that a combination of radiometric intensities could …


Surface Investigation Of Chitosan Film With Fatty Acid Monolayers, M Misran Jan 2009

Surface Investigation Of Chitosan Film With Fatty Acid Monolayers, M Misran

Misni Misran

The surface pressure-molecular area (pi-A) isotherm curves of two fatty acids of different chain lengths, i.e. stearic (C(18)) and arachidic (C(20)) acids, were obtained by using Langmuir-Blodgett (LB) technique. Results showed clear isotherm plots with limiting mean molecular area around 21 angstrom(2) for both acids. However, the monolayer was found to collapse at higher than 33 mN m(-1) and 21 mN m(-1) for stearic acid and arachidic acid respectively. The effect of Langmuir-Blodgett monolayers of the acids was investigated by atomic force microscopy (AFM). Chitosan film, before and after dipping in water, was also studied by means of AFM so …