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Full-Text Articles in Materials Chemistry

A Highly Conductive, Flexible, And 3d-Printable Carbon Nanotube-Elastomer Ink For Additive Bio-Manufacturing, Andy Shar, Phillip Glass, Daeha Joung Ph.D. Jan 2022

A Highly Conductive, Flexible, And 3d-Printable Carbon Nanotube-Elastomer Ink For Additive Bio-Manufacturing, Andy Shar, Phillip Glass, Daeha Joung Ph.D.

Undergraduate Research Posters

The synthesis of a highly conductive, flexible, 3D-printable, and biocompatible ink has been of great interest in the field of bio-based additive manufacturing. Various applications include ultra-sensitive, microscale tactile sensors, patient-customizable scaffolds for cardiac and nerve tissue regeneration, and flexible electrocardiogram (ECG) electrodes. Here, a novel elastomeric carbon nanocomposite is presented consisting of amino-functionalized carbon nanotubes (CNT-NH2) homogenously dispersed in a one-part room-temperature vulcanizing (RTV) silicone matrix. The use of acetone as a swelling solvent aids in electrical percolation through the elastomer matrix. CNT-NH2 ratios can be tuned to fit various needs; higher tensile strength is favored …


Metal-Interface-Elastomer (Mine) Structures For Stretchable Electronics, Tricia Carmichael, Akhil Vohra, Kory Schlingman, R. Stephen Carmichael May 2018

Metal-Interface-Elastomer (Mine) Structures For Stretchable Electronics, Tricia Carmichael, Akhil Vohra, Kory Schlingman, R. Stephen Carmichael

Chemistry and Biochemistry Publications

The future of soft, conformable, and robust wearable electronics will require elastomers to provide mechanical stabilization, a soft surface to interact with human wearers, and a crucial physical barrier to protect stretchable devices from the environment. It is a difficult challenge, however, for a single elastomer to fulfill each of these needs. Here, we present a new approach that fuses a membrane of poly(dimethylsiloxane) (PDMS) onto the surface of a transparent butyl rubber (T-IIR) substrate using an organosilane-based molecular glue. The resulting membrane-interface-elastomer (MINE) structures uniquely combine the surface chemistry of PDMS with the intrinsically low gas permeability of T-IIR …


Development Of Magnetorheological Elastomers (Mres) For Strength And Fatigue Resistance, J. Mcintyre, Stephen Jerrams Jan 2017

Development Of Magnetorheological Elastomers (Mres) For Strength And Fatigue Resistance, J. Mcintyre, Stephen Jerrams

Books/Book Chapters

Natural rubber (NR)-based magnetorheological elastomers (MREs) exhibiting a reasonable switching effect were fabricated and tested. They were strong enough for use in automotive applications but still needed protection against ageing. Ethylene–propylene–diene rubber (EPDM) is a cost-effective material that is frequently used in the automotive industry because of its advantageous range of properties. With these applications in mind, it was a logical progression to the development of EPDM-based MREs. Unlike strain-crystallising NR, EPDM requires reinforcement to render its tensile and fatigue strength suitable for use in most applications. While small amounts of carbon black were sufficient for the NR-based MREs, a …


Reinventing Butyl Rubber For Stretchable Electronics, Tricia B. Carmichael, Akhil Vohra, Heather L. Filiatrault, Stanley Amyotte, R. Stephen Carmichael, Natalie D. Suhan, Siegers Conrad, Lorenzo Ferrari, Gregory J E Davidson Jan 2016

Reinventing Butyl Rubber For Stretchable Electronics, Tricia B. Carmichael, Akhil Vohra, Heather L. Filiatrault, Stanley Amyotte, R. Stephen Carmichael, Natalie D. Suhan, Siegers Conrad, Lorenzo Ferrari, Gregory J E Davidson

Chemistry and Biochemistry Publications

The development of stretchable electronic devices that are soft and conformable has relied heavily on a single material – polydimethylsiloxane – as the elastomeric substrate. Although polydimethylsiloxane has a number of advantageous characteristics, its high gas permeability is detrimental to stretchable devices that use materials sensitive to oxygen and water vapor, such as organic semiconductors and oxidizable metals. Failing to protect these materials from atmosphere-induced decomposition leads to premature device failure; therefore, it is imperative to develop elastomers with gas barrier properties that enable stretchable electronics with practical lifetimes. Here, we reinvent butyl rubber – a material with an intrinsically …