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Physical Chemistry

Zeljko D Cupic

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Fluctuations In Transient Response Of Adsorption-Based Plasmonic Sensors, Zeljko D. Cupic Dec 2013

Fluctuations In Transient Response Of Adsorption-Based Plasmonic Sensors, Zeljko D. Cupic

Zeljko D Cupic

The basic parameters of a sensor element defining its ultimate performance are sensitivity and intrinsic noise. In plasmonic gas sensors both are determined by refractive index changes due to adsorption and desorption (a–d) of target analyte particles to the sensor active area. In this paper we present a general model that can be simultaneously used to determine sensitivity and intrinsic noise of a plasmonic sensor both during transients and in steady-state and is valid for multi-analyte environments. The model utilizes the conventional probabilistic approach. It is derived without any assumptions about the stochastic nature of the fundamental (a–d) process. It …