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Full-Text Articles in Materials Chemistry

Surface Structure Engineering Of Feni-Based Pre-Catalyst For Oxygen Evolution Reaction: A Mini Review, Jia-Xin Li, Li-Gang Feng Sep 2022

Surface Structure Engineering Of Feni-Based Pre-Catalyst For Oxygen Evolution Reaction: A Mini Review, Jia-Xin Li, Li-Gang Feng

Journal of Electrochemistry

Oxygen evolution reaction (OER) is a significant half-reaction for water splitting reaction, and attention is directed to the high-performance non-precious catalysts. Iron nickel (FeNi)-based material is considered as the most promising pre-catalyst, that will be transferred to the real active phase in the form of high valence state metal species. Even so, the catalytic performance is largely influenced by the structure and morphology of the FeNi pre-catalysts, and lots of work has been done to optimize and tune the structure and chemical environment of the FeNi- based pre-catalysts so as to increase the catalytic performance. Herein, based on our work, …


Rhodium Nanoparticle Shape Dependence In The Reduction Of No By Co, James Russell Renzas, Yawen Zhang, Wenyu Huang, Gabor Somoraji Jan 2009

Rhodium Nanoparticle Shape Dependence In The Reduction Of No By Co, James Russell Renzas, Yawen Zhang, Wenyu Huang, Gabor Somoraji

Wenyu Huang

The shape dependence of the catalytic reduction of nitric oxide by carbon monoxide on rhodium nanopoly- hedra and nanocubes was studied from 230 to 270 ° C. The nanocubes are found to exhibit higher turnover frequency and lower activation energy than the nanopolyhedra. These trends are compared to previous studies on Rh single crystals.