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Materials Chemistry Commons

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Condensed Matter Physics

Posters-at-the-Capitol

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Full-Text Articles in Materials Chemistry

Graphene Quantum Dots Electrochemistry And Development Of Sensitive Electrochemical Biosensor [Hybrid Poster 1-B], Tyler Smith, Alexander Banaszak Nov 2016

Graphene Quantum Dots Electrochemistry And Development Of Sensitive Electrochemical Biosensor [Hybrid Poster 1-B], Tyler Smith, Alexander Banaszak

Posters-at-the-Capitol

Graphene quantum dots (GQDs) are zero-dimensional material derived from graphene derivatives with characteristics from the structure of graphene with quantum confinement and edge effects possessing unique properties. Intense research activity in GQDs is attributed to their novel physical-chemical phenomena arising from the sp2-bonded carbon core surrounded with edge functional moieties. In this work, GQDs of optimal 5-7 nm size are investigated for their fundamental electrochemical properties and use in electrochemical sensing including enzyme-based glucose biosensor. Glucose oxidase (GOx) was immobilized on GQDs modified glassy carbon (GC) and the UV-Vis absorption and fluorescence spectroscopy, electron microscopy, cyclic …


Molecular Sensitivity And Selectivity Of Metal Nanoparticles Decorated Graphene As ‘Smart’ Surface-Enhanced Raman Scattering (Sers) Platforms [Hybrid Poster 1-A], Alexander Banaszak, Tyler Smith Nov 2016

Molecular Sensitivity And Selectivity Of Metal Nanoparticles Decorated Graphene As ‘Smart’ Surface-Enhanced Raman Scattering (Sers) Platforms [Hybrid Poster 1-A], Alexander Banaszak, Tyler Smith

Posters-at-the-Capitol

Raman scattering signal enhancement that uses graphene as support, graphene-enhanced Raman scattering (GERS), is a recent phenomenon. It can produce clean and reproducible Raman signals of chemical molecules with significantly enhanced signal intensity in contrast to traditional surface- (SERS) and tip- enhanced Raman scattering (TERS) techniques. While enhancement in SERS and TERS arise due to the electromagnetic mechanism, GERS also relies on a chemical mechanism and therefore shows unique molecular sensitivity and selectivity. In this work, we developed graphene materials decorated with noble metal (silver and gold) nanoparticles for detection of different chemical molecules e.g. methylene blue (MB) and rhodamine …