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Inorganic Chemistry Commons

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Synthesis

Claremont Colleges

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Synthesis And Characterization Of A Novel Platinum Ligand Complex ((Κ-N,C,N- 2,6-Bis(Diethylaminomethyl)Phenyl)(4- Tert-Butylphenyl) Platinum(Ii)), Carly Roleder Jan 2018

Synthesis And Characterization Of A Novel Platinum Ligand Complex ((Κ-N,C,N- 2,6-Bis(Diethylaminomethyl)Phenyl)(4- Tert-Butylphenyl) Platinum(Ii)), Carly Roleder

CMC Senior Theses

A novel platinum ligand complex (NCN)PtAr, ((κ-N,C,N- 2,6-bis (diethylaminomethyl)phenyl)(4- tert-butylphenyl) platinum(II)), was synthesized. A reaction of 1-Bromo-4-tert-butylbenzene Grignard with (NCN)PtCl, (where NCN = 2,6-bis(diethylaminomethyl)phenyl) yielded the (NCN)PtAr (where Ar = 4-tert­-butylphenyl). The product was then characterized with NMR spectra through 1H NMR, 13C NMR, COSY, HSQC, and HMBC to verify it structure.