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Inorganic Chemistry Commons

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Full-Text Articles in Inorganic Chemistry

Seasonal Transport Of Dissolved Inorganic Carbon And Total Alkalinity Across The Louisiana Shelf, Michelle M. Anderson Jun 2020

Seasonal Transport Of Dissolved Inorganic Carbon And Total Alkalinity Across The Louisiana Shelf, Michelle M. Anderson

LSU Master's Theses

Rivers and wetlands are a major source of terrestrial derived carbon for coastal ocean margins. Unfortunately, Louisiana’s wetlands are threatened by ongoing high rates of erosion, deterioration, and unprecedented rates of river water discharge that changes seasonally, leading to a net loss of terrestrial carbon into the northern Gulf of Mexico (nGOM). There exists a current lack of understanding about the distribution of dissolved inorganic carbon (DIC) and total alkalinity (TAlk) within the shallowest regions of the Louisiana shelf. Even less is known about how the transport of DIC alters seasonally with changes in river outflow and shelf currents. Quantifying …


Lithological And Geochemical Responses To Abrupt Global And Regional Paleoenvironmental Changes During The Aptian In A Hemipelagic Setting Of The Eastern Iberian Peninsula: A Multi-Proxy Approach, Jander Socorro Mar 2020

Lithological And Geochemical Responses To Abrupt Global And Regional Paleoenvironmental Changes During The Aptian In A Hemipelagic Setting Of The Eastern Iberian Peninsula: A Multi-Proxy Approach, Jander Socorro

FIU Electronic Theses and Dissertations

Intense episodes of environmental perturbations and regionally to globally distributed, oxygen-deprived marine facies characterize the Cretaceous sedimentary record. The Organyà Basin in the Spanish Pyrenees chronicles this period in expanded stratigraphic sequences that enabled high-resolution sampling and detailed analysis of disturbances poorly recorded in more lithologically condensed sections. Here, I present an integrated multi-proxy study aimed at understanding the Basin’s response to changing paleoenvironmental conditions during the early Aptian stage of the Cretaceous.

Results from the El Pui section indicate that large-scale (> 1‰), negative carbon isotope excursions (CIEs) that show no corresponding shifts in local sources of organic matter …


Geochemical Analysis And Heat-Treatment Of Natural Sapphires From Madagascar And Tanzania In Oxidizing And Reducing Conditions, Lukas Karuza, Dr. Michael B. Wolf, Brian Konecke Phd Jan 2020

Geochemical Analysis And Heat-Treatment Of Natural Sapphires From Madagascar And Tanzania In Oxidizing And Reducing Conditions, Lukas Karuza, Dr. Michael B. Wolf, Brian Konecke Phd

Geology: Student Scholarship & Creative Works

Natural or synthetic sapphires can be heat-treated to improve the clarity by removing “silk” (inclusions) and to change color by introducing color-inducing elements (i.e., chromophores) into the lattice structure or changing their valency. Due to these reasons, sapphires can be heat-treated to increase their monetary value. Twenty natural blue (C1), 20 green (C2), and 20 clear (C3) sapphires from Madagascar and Tanzania were heat-treated in a muffle furnace in oxidizing and reducing conditions, from 1200 to 1600℃, for 10-hour soak time. In total, 5 experiments were conducted in which soak time remained constant: experiment 1 was performed at 1200℃, exp. …