Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Inorganic Chemistry
Low-Valent Synthons Of Titanium : Investigations On Structure-Reactivity Relationships, Rolando Aguilar
Low-Valent Synthons Of Titanium : Investigations On Structure-Reactivity Relationships, Rolando Aguilar
Open Access Theses & Dissertations
Strategies for the functionalization of abundant, small molecules into products with added value provide a powerful approach to address environmental sustainability issues. Dinitrogen (N2), and carbon oxides (CO, CO2), are examples of the ample, yet, underutilized atmospheric feedstock of nitrogen and carbon building blocks to produce a variety of chemicals. Although, potentially valuable, small molecules are inert under most conditions, and as such, their industrial activation often requires heterogeneous catalysts operated under high pressures (200 atm) and temperatures (450-600 ºC).
To this end, great efforts in synthetic inorganic chemistry have been devoted to the generation of well-defined and highly reactive …
Metal Catalyzed Activation Of E-H Bonds, E = Si, Ge, Sn, Renzo Nelson Arias Ugarte
Metal Catalyzed Activation Of E-H Bonds, E = Si, Ge, Sn, Renzo Nelson Arias Ugarte
Open Access Theses & Dissertations
The present project covers the use of complexes of the type: (C5H5)M(CO)nLMe, (M = Fe, n = 1; L = CO, Ph3P; M = Mo, n = 2; L = CO, Ph3P); M(CO)6, (M = Cr, Mo, W) and M(CO)5NMe3 as catalysts for the activation of E-H bonds (E = Si, Ge and Sn). The work is divided in three sections; the first two involves dehydrogenation and the last one amide reduction.