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New Dion-Jacobson And Ruddlesden- Popper Layered Perovskites Prepared By Topochemical Methods, Dariush Montasserasadi May 2015

New Dion-Jacobson And Ruddlesden- Popper Layered Perovskites Prepared By Topochemical Methods, Dariush Montasserasadi

University of New Orleans Theses and Dissertations

Layered perovskites can be classified in three major groups: Dion-Jacobson AA′n-1BnO3n+1, Ruddlesden-Popper A2A′n-1BnO3n+1,and Aurivillius phase (Bi2O2)A′n-1BnO3n+1. (A: Alkali metal, Alkali-earth metal; A′: Lanthanides and Bi; B: Ti, Nb, Ta; n: thickness of slabs). For more than two decades researchers have shown much interest in this series because of their magnetic and electrical properties. Tuning synthesis parameters such as temperature, time, and host structure can be used to direct such properties. Low temperature synthetic methods (topochemical methods) allow …