Inorganic Chemistry Commons^™

Pascoite Minerals And Potential Application Of Nmr Spectroscopy, Craig C. Mclauchlan, Beth Trent-Ringer, Debbie C. Crans

Faculty Publications – Chemistry

The 20 minerals encompassing the pascoite family of decavanadate isopolyanion-containing [V₁₀O₂₈]⁶⁻ minerals include a few minerals, such as rakovanite, that have been described as containing a protonated decavanadate anion. Rakovanite was originally assigned the formula Na₃[H₃V₁₀O₂₈]•15H₂O and now is redefined with an ideal formula (NH₄)₃Na₃[V₁₀O₂₈]•12H₂O. Nuclear magnetic resonance (NMR) and particularly ⁵¹V NMR spectroscopy is an informative method used to describe the protonation state and speciation in both solid and solution states …

Lithological And Geochemical Responses To Abrupt Global And Regional Paleoenvironmental Changes During The Aptian In A Hemipelagic Setting Of The Eastern Iberian Peninsula: A Multi-Proxy Approach, Jander Socorro

FIU Electronic Theses and Dissertations

Intense episodes of environmental perturbations and regionally to globally distributed, oxygen-deprived marine facies characterize the Cretaceous sedimentary record. The Organyà Basin in the Spanish Pyrenees chronicles this period in expanded stratigraphic sequences that enabled high-resolution sampling and detailed analysis of disturbances poorly recorded in more lithologically condensed sections. Here, I present an integrated multi-proxy study aimed at understanding the Basin’s response to changing paleoenvironmental conditions during the early Aptian stage of the Cretaceous.

Results from the El Pui section indicate that large-scale (> 1‰), negative carbon isotope excursions (CIEs) that show no corresponding shifts in local sources of organic matter …

Geochemical Analysis And Heat-Treatment Of Natural Sapphires From Madagascar And Tanzania In Oxidizing And Reducing Conditions, Lukas Karuza, Dr. Michael B. Wolf, Brian Konecke Phd

Geology: Student Scholarship & Creative Works

Natural or synthetic sapphires can be heat-treated to improve the clarity by removing “silk” (inclusions) and to change color by introducing color-inducing elements (i.e., chromophores) into the lattice structure or changing their valency. Due to these reasons, sapphires can be heat-treated to increase their monetary value. Twenty natural blue (C1), 20 green (C2), and 20 clear (C3) sapphires from Madagascar and Tanzania were heat-treated in a muffle furnace in oxidizing and reducing conditions, from 1200 to 1600℃, for 10-hour soak time. In total, 5 experiments were conducted in which soak time remained constant: experiment 1 was performed at 1200℃, exp. …

Phosgene In The Upper Troposphere And Lower Stratosphere: A Marker For Product Gas Injection Due To Chlorine-Containing Very Short Lived Substances, Jeremy J. Harrison, Martyn P. Chipperfield, Ryan Hossaini, Christopher D. Boone, Sandip Dhomse, Wuhu Feng, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

Abstract: Phosgene in the atmosphere is produced via the degradation of carbon tetrachloride, methyl chloroform, and a number of chlorine‐containing very short lived substances (VSLS). These VSLS are not regulated by the Montreal Protocol even though they contribute to stratospheric ozone depletion. While observations of VSLS can quantify direct stratospheric source gas injection, observations of phosgene in the upper troposphere/lower stratosphere can be used as a marker of product gas injection of chlorine‐containing VSLS. In this work we report upper troposphere/lower stratosphere measurements of phosgene made by the ACE‐FTS (Atmospheric Chemistry Experiment Fourier Transform Spectrometer) instrument and compare with results …

Catalyzed Synthesis Of Zinc Clays By Prebiotic Central Metabolites, Marcelo I. Guzman, Ruixin Zhou, Kaustuv Basu, Hyman Hartman, Christopher J. Matocha, S. Kelly Sears, Hajatollah Vali

Chemistry Faculty Publications

How primordial metabolic networks such as the reverse tricarboxylic acid (rTCA) cycle and clay mineral catalysts coevolved remains a mystery in the puzzle to understand the origin of life. While prebiotic reactions from the rTCA cycle were accomplished via photochemistry on semiconductor minerals, the synthesis of clays was demonstrated at low temperature and ambient pressure catalyzed by oxalate. Herein, the crystallization of clay minerals is catalyzed by succinate, an example of a photoproduced intermediate from central metabolism. The experiments connect the synthesis of sauconite, a model for clay minerals, to prebiotic photochemistry. We report the temperature, pH, and concentration dependence …

Hydrogeochemical Modeling Of Saltwater Intrusion And Water Supply Augmentation In South Florida, Yonas T. Habtemichael

FIU Electronic Theses and Dissertations

The Biscayne Aquifer is a primary source of water supply in Southeast Florida. As a coastal aquifer, it is threatened by saltwater intrusion (SWI) when the natural groundwater flow is altered by over-pumping of groundwater. SWI is detrimental to the quality of fresh groundwater sources, making the water unfit for drinking due to mixing and reactions with aquifer minerals. Increasing water demand and complex environmental issues thus force water utilities in South Florida to sustainably manage saltwater intrusion and develop alternative water supplies (e.g., aquifer storage and recovery, ASR).

The objectives of this study were to develop and use calibrated …

Nitrous Oxide In The Atmosphere: First Measurements Of A Lower Thermospheric Source, Patrick E. Sheese, Kaley A. Walker, Chris D. Boone, Peter F. Bernath, Bernd Funke

Chemistry & Biochemistry Faculty Publications

Nitrous oxide (N₂O) is an important anthropogenic greenhouse gas, as well as one of the most significant anthropogenic ozone-depleting substances in the stratosphere. The satellite-based instrument Atmospheric Chemistry Experiment-Fourier Transform Spectrometer has been observing the Earth's limb since 2004 and derives profiles of N₂O volume mixing ratios in the upper troposphere to the lower thermosphere. The resulting climatology shows that N₂O is continuously produced in the lower thermosphere via energetic particle precipitation and enhanced N₂O is present at all latitudes, during all seasons. The results are consistent with an N₂O …

Analysis Of Kyrock For Leaching Of Impurities In Synthetic Rainwater, Santhosh Kumar Kasulavada

Masters Theses & Specialist Projects

Kyrock is a coarse grained sandstone with a complex mixture of organic and inorganic compounds. Mining of Kyrock is for use in road construction and roofing. Kyrock samples were analyzed using scanning electron microscopy to obtain elemental analysis. High levels of carbon indicate the presence of organic compounds. Analysis of an acid digestion of the samples using inductively coupled plasma spectroscopy showed inorganic compounds such as titanium oxide, vanadium oxide along with traces of arsenic. Elemental analysis of samples indicates a percent of carbon, and sulfur with no notable traces of nitrogen. Pyrolysis of the samples was done using gas …

Development Of Procedures To Determine The Fertilizer Requirements Of Annual Pasture Legumes Grown In Cereal Cropping Systems., B. H. Paynter

Experimental Summaries - Plant Research

Trials 88ME67, 88SC17, 90ME1 and 90ME2

Location: Merredin

To determine the phosphate (P) fertilizer requirements of burr medic on marginally acidic, medium textured soils and yellow serradella on acidic, light textured soils.

Trials 89ME52, 89ME55 and 86ME61

Location: Merredin

Determine the response of yellow serradella and burr medic to residual phosphate and freshly applied phosphate.

Trials 89ME50, 89ME54, 88ME67, 88SC17, 89ME60

Location: Merredin.

To measure the influence of different levels of pasture productivity (generated by different levels of P supply) and the different pasture legumes on subsequent wheat crops.

Seed Phosphorus In Wheat And Lupins, B. H. Paynter, K. Adcock, R. W. Bell, Tim Pope

Experimental Summaries - Plant Research

Trial 90NO119

Seed P in wheat.

Location: Greenhills.

Design: 2 applied P x 3 seed P x 4 replicates, sowing wheat (cv. Aroona) seed from 89N33 at 70 kg/ha on May 15, 1990.

Trial 90NO120

Seed P in wheat.

Location: York

Design: 2 applied from P x 3 seed P x 4 replicates, 89N33 at 70 kg/ha on May 25, 1990.

Trial 90NO117

Seed P in lupins

Location: Greenhills.

Design: 2 applied P x 3 seed P x 4 replicates, sowing lupins (cv. Gungurru) from 85BA35 at 100 kg/ha on May 15, 1990.

Trial 90NO118

Seed P in lupins.

Location: …

Depth Of Placement And Rates Of Nitrogen For Lupins On The South Coast., M. Seymour

Experimental Summaries - Plant Research

Trial 90E13

Starter nitrogen for lupins, rates x depth of placement.

To determine if the application of nitrogen at seeding will enable lupins to grow vigorously at the beginning of the season, and have better growth at flowering. Deep placement is used to reduce the effects of high nitrogen fertiliser on plant establishment.

Phosphorus Nutrition., M. D. Bolland, M. J. Baker

Experimental Summaries - Plant Research

Evaluation of soil test for phosphate on sandy soils.

Results presented for this project, commenced in 1988, which started as a joint project between the Department of Agriculture and Soil Science and Plant Nutrition, School of Agriculture, University of Western Australia.

In the field experiments, 10 levels of superphosphate (three replicates) were applied in May 1988, and 10 levels of superphosphate (also three replicates) were applied in May 1989 onto an adjacent area to the 1988 treatments. Colwell P I(soil test values) and yield data are presented for 1988 and 1989 for the 1988 treatments layed out in 1988, and …

Phosphorus And Sulphur Nutrition Of Pastures In High Rainfall Areas., M. D. Bolland, M. F. Clarke

Experimental Summaries - Plant Research

J.S.Yeates and M.F.Clarke started these experiments. In January 1990 M.D.A. Bolland replaced J.S. Yeates (who became Regional Manager of the Northern Agricultural Region) as the Research Officer responsible for the management of the long-term experiments, and to continue the research on the topic.

In the experiments the fertilizers wee applied in autumn (March-April) in the years listed in the tables.

Trial 80AL4

Location: Cuthbert.

A new experiment was started in 1989 to compare two partially acidulated rock phosphate (PARP) fertilizers with ordinary (single) superphosphate (OSP).

Trial 84AL32

Location: Denmark

The fertilizers compared are ordinary (single) superphosphate (OSP). New (pre 1990) …

Rhizoctonia Bare Patch Of Cereals And Lupins. Sterile Red Fungus (Srf) And Control Of Take-All Disease In Wheat., G. C. Macnish

Experimental Summaries - Plant Research

Trial 86E31

Rhizoctonia strains and paddock history.

Location: Esperance Downs Research Station ( Paddock C5)

To determine the effects of pasture, cultivation and cropping on Rhizoctonia root rot, Rhizoctonia patch and distribution of patch and non-patch strains of R. spp

Trial 88E39

Rhizoctonia patch mini-plot establishment area.

Location: Esperance Downs Research Station ( Paddock N1B)

To examine the effects of cultivation and minimum tillage in patches in lupins and to provide sites for mini-plot experiment.

Trial 88KO15

Rhizoctonia bare patch establishment area.

Location: Kojaneerup annex.

To establish an area (with a known history) for future research.

Trial 89E12

Rhizoctonia bare …

Deep Phosphate Banding., R. J. Jarvis

Experimental Summaries - Plant Research

Trial 90A1

Lupins sown 26/4. York gum/jam sandy loam 33 ppm bic. P. Wheat in 1989. Cultivation reduced yield (one pass banding points). Deep banding P overcame this reduction. No additional response to banding compared with TD or D. No response to P. Yield 2.0 t/ha.

Trial 90A2

Wheat sown 8/6. York gum/jam sandy loam 42 ppm bic. P. Lupins in 1989. All treatments had deep cultivation in the one pass. No response to deep band cf. drilled. 23% response to P. Top yield was 1.9 Oa.

88EB12 Wheat sown 5/6. Loamy grey sand/clay 27 ppm bic. P. Lupins in …

Trace Element Nutrition., R. F. Brennan

Experimental Summaries - Plant Research

Trial 66N14

Long Term Copper Residual Trial

Location: Newdegate Research Station.

To determine the residual value of previously applied copper.

Trial 86N27

Residual Value of Zinc with DAP.

Location: Newdegate Research Station.

To determine the decline in effectiveness of zinc on this soil types using DAP.

86LG34

Residual Value of Copper, Zinc and Sulphur with DAP Fertilizer

Location: South Newdegate.

To determine the decline in effectiveness of copper, zinc and sulphur on this soil types using DAP

Trial 67E8

Grain Yields of Wheat Grown on a Residual Copper Trial.

Location: Esperance Downs Research Station.

The trial was originally designed to …

Agronomic Practices To Improve Or Maintain The Protein Content Of High Yielding, Long Season Wheats., Wayne Smith

Experimental Summaries - Plant Research

Trial 90SG8, 90SG9, 90ES9, 90ES11, 90MT8, 90KO2

Wheat variety * Time of sowing

Location: Salmon Gums Research Station, Mt. Ridley, East Gibson, Mt Barker Research Station, Kojaneerup Research Station

The aim is to define the optimum heading/flowering date on the South Coast. This trial also provides information on the performance of the varieties and new cross-breds at various sowing times.

Trial 90E10, 90ES12, 90ES13, 90ES14, 90ES15, 90ES16, 90SG10, 90SG11, 90MT10, 90KO3, 90KO4

Wheat protein on the South Coast

Location: Esperance Downs Research Station, Gibson, Neridup, Mt Ridley, Salmon Gums Research Station, Mt Barker Research Station, Kojaneerup Research Station

The Australian …

Getting The Best Out Of Our Wheats., Brenda Shackley, L. Lambert

Experimental Summaries - Plant Research

Trials: 90KA82 (TOS1), 90KA83 (TOS 2), 90KA84 (TOS 3)
90LG4 (TOS 1), 90LG45 (TOS 2), 90LG46 (TOS 3)
90LG47 (TOS 1), 90LG48 (TOS 2), 90LG49 (TOS 3)
90N42 (TOS 1), 90N43 (TOS 2), 90N44 (TOS 3)

Variety * time of sowing (TOS)

Locations: Wagin, Tarin Rock, Newdegate Research Station and Lake Varley.

Determine the optimum sowing date for maximum yield for a range of released and unreleased wheat cultivars.

Trials: 90KA79, 90LG50, 90LG51, 90N62

Nitrogen application.

Locations: Wagin, Tarin Rock, Newdegate Station and Lake Varley.

Determine the response of released and unreleased wheat cultivars to the application of nitrogen.

Trials: …

Potassium Nutrition Of Lupins On The Sandplain Soils Of Western Australia., N. K. Edwards

Experimental Summaries - Plant Research

Aim: Develop recommendations for optimal potassium fertilizer application strategies for lupin production. Further develop soil and tissue test calibrations for lupin grain production.

Trial 89EC32

Potassium nutrition of lupins on sandplain soils.

Location: East Chapman Research Station.

Fertilizer: At sowing: 50 kg/ha DAP, 50 kg/ha Urea topdressed. 100 kg/ha Urea topdressed 10/7.

Trial 89GE90

Potassium nutrition of lupins on sandplain soils.

Location: Allanooka

Fertilizer: At sowing: 120 kg/ha Agras No. 1. 100 kg/ha Urea topdressed 10/7.

Trial 89MO51

Potassium nutrition of lupins on sandplain soils.

Location: Lancelin.

Fertilizer: At sowing: 110 kg/ha Agras No. 1. 60 kg/ha Urea topdressed 10/7. …

Pasture Deterioration Trial, J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89NA61

Location: Duranillin

In this site we would expect a very large response (40 to 50% ) to phosphorus.

History:

The site was chosen because of the patchy and poor pasture production. The poor areas tend to have more suckling clover than the good areas. The pasture was legume dominant.

Treatments were applied on April 16, 1989.

Pasture Agronomy., C. K. Revell

Experimental Summaries - Plant Research

Trial 89ME82

a. Medic establishment.

Establishing burr medic pastures with cereal cover.
Merredin

Trial 89SC19

b. Serradella - Potash response.

Response of serradella to potash fertilizer.
South Carrabin

Trial 89M44

c. Serradella/Grass competition

Effect of grass competition on production of serradella.
Merredin Research Station.

Trial 89SC HERB

d. Herbicide tolerance of Serradella.

Herbicide tolerance of Madeira serradella.
South Carrabin

Tactical Nitrogen Decisions For Wheat (And N Rates Trials), J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89NO77 (89NO76)

Location: Grass Valley.

History: 1984 Lupins.

1985/86 pasture legumes and about 100 kg super/ha.

1987 Wheat yield of 2.8 t/ha using 45 kg DAP/ha and 60 of urea 2-4 WAS.

1988 Gungurru lupins (27 kg/ha seed) yielding 1.9 t/ha using 80 kg super/ha.

Tactical nitrogen trials - summary of treatments required.

Trial 89NO77

Location: Meckering

Treatments existed of nitrogen and urea. Nitrogen was not applied at seeding. Urea was applied at seeding.

Trial 88No77

Tactical nitrogen trials. - summary of observations.

Location: Grass Valley.

Trial 89NO76

Hand harvest 23/11/1989.
Yield components for copper sufficient plots reps. I …

Nitrogenous Fertilisers For Cereals In Different Rotations. Results From 1989 Trials., I. Rowland, M. G. Mason

Experimental Summaries - Plant Research

Trial 78BA1

Nitrogen fertiliser requirement in alternate crop - pasture rotation.

Location: Badgingarra Research Station.

Trial 88B4

Effect of amount and quality of organic matter residues on response to N.

Location: Badgingarra Research Station.

Trial 86WH36, 86M44

Lupin/wheat rotation.

Location: Wongan Hills Research Station, Carrabin Research Station.

Trail 87N084, 86M39, 86ME64, 87N25, 87KA49

Pea/wheat rotation.

Location: Konnongorring, Merredin Research Station, Narembeen, Newdegate Research Station, Nyabing,

Phosphate Nutrition Of Burr Medic And Yellow Serradella., Blakely Paynter

Experimental Summaries - Plant Research

Trial 89ME50, 89ME51, 89ME53, 88ME55, 89ME56

Location: Mutadgin, Doodlakine, Noongar, Mt Hampton, Nungarin

Compare the response of burr medic to topdressed P with the response of wheat to drilled P.

Trial 89ME52, 89ME54

Location: Noongar, Mt. Hampton.

Compare the response of burr medic to topdressed P with the response of wheat to drilled P.
Measure the response of burr medic pasture to applied potash.

Trial 89ME59

Location: Beacon

Compare the response of yellow serradella to topdressed P with the response of wheat to drilled P.

Trial 89ME60, 89ME61

Location: Muntadgin

Compare the response of yellow serradella to topdressed P with …

Effect Of Seed Origin And Seed Phosphorus On The Growth Of Lupins., M. M. Riley, M. D. Bolland, K. Adcock

Experimental Summaries - Plant Research

Trial: 89BA29

Location: Badgingarra Research Station, Paddock 4A2, old block.

Lupin cv. Gungurru sieved to uniform size and sown without inoculation. No basal fertilizers were applied as the soil had previously been treated with high rates of superphosphate, micro-nutrients and potassium. Muriate of potash topdressed on 18/8/89 at 100 kg/ha.

Influence Of Soil Acidity On Cereals And Acidification Rates., P. J. Dolling

Experimental Summaries - Plant Research

Soil acidity and the availability of nitrogen to cereals.

To determine the extra nitrogen available due to better pasture legume growth after liming.
To determine the extra nitrogen released from soil organic matter after liming.

Trial 89NO81

Location: South Cunderdin.

Trial 89NO82

Location: Cunderdin

Trial 89NO83

Location: Konnongorring.

Trial 89NO84

Location: Jennacubbine.

Trial 88AL35

Location: Woogenellup.

Trial 88TS54

Location: Three Springs.

Trial 88NO76

Location: Goomalling.

Trial 88NO77

Location: Ejanding.

Trace Element Nutrition. Tissue Testing Programme 1989. Residual Value. Manganese Nutrition Of Lupins., R. F. Brennan

Experimental Summaries - Plant Research

Evaluation of existing diagnostic procedures for the recommendation of trace element fertilizers.

To compare the accuracy and reliability of a range of tissue and soil tests being variously promoted for use to farmers for the diagnosis and prognosis of zinc and copper deficiencies in wheat crops on Western Australian farms.

Trial 66N14

Long term copper residual trial at the Newdegate Research Station.

To determine the residual value of previously applied copper.

Location: Newdegate Research Station.

Trial 86N27

Residual value of zinc with high analysis nitrogen and phosphorus fertilizer.

To determine the decline in effectiveness of zinc on this soil types …

Tactical Nitrogen Decisions For Wheat (And Nitrogen Sources Rates And Times On Wheat), J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89MO49

Location: Tenderloin, Brand Highway, Regan's Ford.

History:

1987 Aroona wheat with 70 kg DAP and 3 kg CuSO4 at seeding followed by 60 urea at 3WAS and another 40 urea at 6WAS. Yield was about 1.7 to 1.8 t/ha;
1988 Gungurru lupins with 120 kg super and manganese/ha yielded 1.9 t/ha. 350-400 ml Roundup/ha and one cultivation prior to seeding.

Interaction Of Season With Wheat Response To Nitrogen Fertilizer., J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 89M3

Interaction of season with wheat response to nitrogen fertilizer.

Location: Merredin Research Station.

History: 1988 pasture.

Sown on 30/5/89. Gutha Wheat at 50 kg/ha Madiera Serradella at 15 kg/ha. Basal superphosphate at 200 kg/ha plus Molybdenum drilled with the seed and 100 kg/ha Muriate of Potash topdressed. At seeding (A.S) nitrogen treatments topdressed by hand on 1/6/89 and 4 weeks after (4WAS) treatments applied on 29/6/89. Supplementary water applied.

Trial 89NA61

Pasture deterioration trial.

Location: West Dale

History: Long term pasture dominated by non-productive 'suffocating clover'.

Trial 88NA88

Effect of clover growth on nitrogen for following cereals.

Location: …

Tactical Nitrogen Decisions For Wheat, J. W. Bowden, R. J. Lunt

Experimental Summaries - Plant Research

Trial 88MO41, 88WH40 (2CE), 88WH40 (4W), 89NO77, 89MO47, 89MO47, 89MO49, 89BA33 (1), 89BA33 (2), 89WH70 (1), 89WH70 (2)

Locations: Wannamal, WHRS, Grass Valley, Regan's Ford, Badg. New Block 3CE

In order to test tactical and other fertilizer decision making methods (Table 1), we carried out three trials in 1988 and a further seven trials in 1989 (Table 2).

To date this programme has provided a lot of information which can be used to test and validate current (and future) methods of predicting yield potential and nitrogen status of a crop as the season progresses. However, our inability to predict end …