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Articles 1 - 30 of 108
Full-Text Articles in Environmental Chemistry
Enabling More Efficient Solar Thermal Energy Production And Storage, Allan Wilson
Enabling More Efficient Solar Thermal Energy Production And Storage, Allan Wilson
Poster Presentations
Concentrated Solar Power (CSP) stores & transfers energy using a Thermal Energy Storage Fluid (EIA AEO 2022)
The Impact Of Glacial Proximity On The Elemental Composition Of Leachate Derived From Sediment Weathering, Karoline Ford
The Impact Of Glacial Proximity On The Elemental Composition Of Leachate Derived From Sediment Weathering, Karoline Ford
Theses/Capstones/Creative Projects
This study assesses chemical weathering trends as they relate to glacial retreat. The chemical environment of surfaces exposed to the atmosphere differs significantly from beneath a glacier. As a glacier melts, changes to the biogeochemical processes generate environmental gradients. This study analyzed chemical weathering signals at different distances from a glacial front by comparing the elemental composition of leachate derived from sediments in southeastern Greenland. Samples from proglacial, nonglacial, and moraine locations were weathered in a laboratory setting, and ion chromatography was used to determine the elemental composition of the products. Divergent trends in leachate composition were observed as distance …
Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen
Molecular Insights Into The Redox Of Atmospheric Mercury Through Laser Spectroscopy, Rongrong Wu Cohen
Theses and Dissertations
The widespread pollution of mercury motivates research into its atmospheric chemistry and transport. Gaseous elemental mercury (Hg(0)) dominates mercury emission to the atmosphere, but the rate of its oxidation to mercury compound (Hg(II)) plays a significant role in controlling where and when mercury deposits to ecosystems. Atomic bromine is regarded as the main oxidant for Hg(0) oxidation, known to initiate the oxidation via a two-step process in the atmosphere – formation of BrHg (R1) and subsequent reactions of BrHg with abundant free radicals Y, i.e., NO2, HOO, etc. (R2), where the reaction of BrHg +Y could also lead to the …
Wastewater-Informed Public Health Intervention Playbook
Wastewater-Informed Public Health Intervention Playbook
Sustain Magazine
As the SARS-CoV-2 pandemic quickly spread from country to country and continent to continent in 2020, governments and scientists needed a way to track COVID-19 through populations in order to position public health interventions in the most impactful locations. Having a decision-based risk framework may help to guide policy creation that could minimize or prevent possible outbreaks and surges of infection within communities. The University of Louisville in partnership with Louisville’s Department of Public Health and Wellness tested this strategy in 2021 and 2022. This Wastewater-Informed Public Health Intervention Playbook describes the decisions and actions of that academic and public …
The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin
The Interaction Of Different Primary Producers And Physical And Chemical Dynamics Of An Urban Shallow Lake, Majid Sahin
Dissertations, Theses, and Capstone Projects
An artificial urban shallow lake, Prospect Park Lake (PPL), is situated on a terminal moraine in Brooklyn New York, and supplied with municipal water treated with ortho-phosphates. The constant input of the phosphate nutrient is the primary source of eutrophication in the lake. The numerous pools along the water course houses various aquatic phototrophs, which influence the water quality and the state of the system, driving conditions into favoring the survival of their species. In the first half of the dissertation, the focus of the project is on analyzing how the different primary producers in different regions of PPL affect …
Investigating The Mechanisms Driving Mercury Reduction And Emissions In Soil, Hamil Patel
Investigating The Mechanisms Driving Mercury Reduction And Emissions In Soil, Hamil Patel
Student Theses
The water-induced emission of mercury from soil has been studied, but a complete understanding of the mechanisms driving mercury reduction and emission in soil has not been reached. The current understanding is an immediate expulsion of soil gaseous mercury upon water treatment and an upward transport of dissolved soil ionic mercury as the water evaporates. We analyzed emissions from several types of samples using various methods to further our understanding on the mechanisms involved. Light-induced emissions from aqueous samples of humic acid (HA) spiked with mercury (II) chloride (HgCl2) showed that at higher concentrations of HA, less mercury …
Spatial Geochemical Changes In Central And East Texas Soils Over Time Resulting From Human Decomposition, Isabela Marisol Overturf
Spatial Geochemical Changes In Central And East Texas Soils Over Time Resulting From Human Decomposition, Isabela Marisol Overturf
CMC Senior Theses
Human decomposition is studied to aid forensic investigations and better understand the impact of cemeteries on urban resources like soil and groundwater. The purpose of this study was to identify changes in soil geochemistry at and around a human grave to search for lateral nutrient movement and possibly identify new patterns in elemental concentrations that could be used in estimating post-mortem intervals (PMIs). At the Forensic Anthropology Research Facility (FARF) at Texas State San Marcos, soil samples were collected from a shallow grave over the course of 54 days to conduct analysis for organic matter content, texture, pH, and bulk …
Corrosion Prevention On Aluminum Alloy, Andrea Brenner
Corrosion Prevention On Aluminum Alloy, Andrea Brenner
Symposium of Student Scholars
Aluminum alloy (Al-alloy) is a widely used metal in construction, aerospace, aviation, and other necessary fields due to its lightweight and tweakable properties. However, corrosion is inevitable on metals and alloys, and that causes millions of dollars of revenue loss every year. Therefore, we propose to research fabricating coating to prevent corrosion on Al-alloy. This study uses an iron-based metal-organic framework (MOF) and polyurethane (PU) based composite coating to prevent corrosion on the Al-alloy. The makeup of the composite material is changed by varying the percentage of MOF. In addition, a binder is also used to enhance the homogenization between …
To Know The Land With Hands And Minds: Negotiating Agricultural Knowledge In Late-Nineteenth-Century New England And Westphalia, Justus Hillebrand
To Know The Land With Hands And Minds: Negotiating Agricultural Knowledge In Late-Nineteenth-Century New England And Westphalia, Justus Hillebrand
Electronic Theses and Dissertations
Ever since the eighteenth century, experts have tried to tell farmers how to farm. The agricultural enlightenment in Europe marked the beginning of a long arc of new experts aiming to change agricultural knowledge and practice. This dissertation analyzes the pivotal period in the late nineteenth and early twentieth century in Germany and the United States when scientists, improvers, and market agents began to develop comprehensive ways to communicate agricultural innovation to farmers. In a functional approach to analyzing the negotiation of agricultural knowledge through its communication in things, words, and practices, this dissertation argues that the process of change …
Desorption Of Non-Exchangeable Radiocesium In Soil From Fukushima Prefecture, Japan, Grayson Phillips
Desorption Of Non-Exchangeable Radiocesium In Soil From Fukushima Prefecture, Japan, Grayson Phillips
Master of Science in Chemical Sciences Theses
The Fukushima Daiichi Nuclear Powerplant was struck by an earthquake and a tsunami resulting in the meltdown of four of the six reactor cores operating at the plant. As a result, nuclear waste was released from the plant, contaminating the soil in the region. Most of the contamination was sequestered within the few inches of the soil but unluckily the contamination, radiocesium formed a non-exchangeable bond. The Japanese government bagged this soil and has stored it in fields surrounding the exclusion zone. Long-term storage facilities have not been determined. This is a study of the available resources to determine if, …
Competitive Reductive Removal Of Chromate And Pertechnetate Via Zero-Valent Iron, Jonathan Williams Ramirez
Competitive Reductive Removal Of Chromate And Pertechnetate Via Zero-Valent Iron, Jonathan Williams Ramirez
FIU Electronic Theses and Dissertations
Treatment to immobilize radioactive waste is of concern for long-term storage, avoiding future environmental exposure. Most production of Technetium-99 (99Tc) occurred as a byproduct of development of legacy nuclear weapons research. Zero-valent iron (ZVI) is a promising reductant of Tc(VII) to a less mobile 99Tc(IV). However, more redox-sensitive contaminants can compete in the reductive process. Therefore, it is important to examine the effects of competitive contaminants and quantify the effects on the reductive removal rates of 99Tc. Chromate, Cr(VI), is a redox-sensitive contaminant that is expected to be present in legacy waste present in the Hanford …
Coastal Watershed Monitoring And Management: Geomorphology, Geochemistry, And Hydrologic Modeling Of Los Peñasquitos Creek, Ca, Ravleen Khalsa-Basra
Coastal Watershed Monitoring And Management: Geomorphology, Geochemistry, And Hydrologic Modeling Of Los Peñasquitos Creek, Ca, Ravleen Khalsa-Basra
Theses
Rivers in semi-arid climates are directly influenced by local geographic and hydrologic conditions and impacted by modifications to hydrology via urbanization. Changes can influence erosion, morphology, habitat sustainability, and watershed health. In highly urbanized southern California coastal regions, these rare open spaces provide vital ecosystem services. Los Peñasquitos Creek in San Diego County is one such watershed. Using stream surveying and laboratory methods we quantified channel characteristics, grain size distribution, total metal concentration [M], organic carbon (%OC), and phosphate to longitudinally characterize the creek for improved management. Results identified three distinct reaches in the watershed (upper, middle, lower). Downstream, depth …
Artisanal Mining Impacts In Urbanized Semi-Arid Environments: Lessons From Historic Arsenic Mining Near San Diego, California, James A. Wright
Artisanal Mining Impacts In Urbanized Semi-Arid Environments: Lessons From Historic Arsenic Mining Near San Diego, California, James A. Wright
Theses
Anomalously elevated arsenic concentrations occur at an abandoned artisanal mine site in an open space recreational park in urban San Diego County, California. Although mining at the site ceased 100 years ago little to no remediation efforts took place leaving shafts, adits, waste piles and derelict infrastructure accessible by inquisitive hikers and adventurers frequenting Black Mountain Open Space Park. This study evaluates the geochemical mechanisms of As transport downgradient from the mine and examines the contribution of both climate and urbanization on the restriction of As mobility. Sediment As concentrations reach 2,320 mg/kg (483 times background crustal concentrations; n=73) along …
Corn And Soybean Response To Wastewater-Recycled Phosphorus Fertilizers, Shane Ylagan
Corn And Soybean Response To Wastewater-Recycled Phosphorus Fertilizers, Shane Ylagan
Crop, Soil and Environmental Sciences Undergraduate Honors Theses
The ability to recycle phosphorus (P) from wastewaters could provide a sustainable, continuous source of P that might also help protect surface water quality from P enrichment. The mineral struvite (MgNH4PO4·6H2O) is an understudied material that can be created from Pcontaining wastewater and has been shown to have agricultural fertilizer value. The objective of this study was to evaluate the effects of electrochemically precipitated struvite (ECST), chemically precipitated struvite (Crystal Green; CG), diammonium phosphate (DAP), monoammonium phosphate (MAP), rock phosphate (RP), and triple super phosphate (TSP) on corn (Zea mays) and soybean (Glycine max) response in a 79-day greenhouse pot …
Algal Biomarkers As A Proxy For Pco2: Constraints From Late Quaternary Sapropels In The Eastern Mediterranean, Caitlyn R. Witkowski, Marcel T.J. Van Der Meer, Brian Blais, Jaap S. Sinninghe Damsté, Stefan Schouten
Algal Biomarkers As A Proxy For Pco2: Constraints From Late Quaternary Sapropels In The Eastern Mediterranean, Caitlyn R. Witkowski, Marcel T.J. Van Der Meer, Brian Blais, Jaap S. Sinninghe Damsté, Stefan Schouten
Science and Technology Department Faculty Journal Articles
Records of carbon dioxide concentrations (partial pressure expressed as pCO2) over Earth’s history provide trends that are critical to understand our changing world. To better constrain pCO2 estimations, here we test organic pCO2 proxies against the direct measurements of pCO2 recorded in ice cores. Based on the concept of stable carbon isotopic fractionation due to photosynthetic CO2 fixation (Ɛp), we use the stable carbon isotopic composition (δ13C) of the recently proposed biomarker phytol (from all photoautotrophs), as well as the conventionally used alkenone biomarkers (from specific species) for comparison, to reconstruct pCO2 over several Quaternary …
The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan
The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan
MSU Graduate Theses
The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …
Massive Peatland Carbon Banks Vulnerable To Rising Temperatures, A. M. Hopple, R. M. Wilson, M. Kolton, Cassandra A. Zalman, J. P. Chanton, J. Kostka, P. J. Hanson, Jason K. Keller, S. D. Bridgham
Massive Peatland Carbon Banks Vulnerable To Rising Temperatures, A. M. Hopple, R. M. Wilson, M. Kolton, Cassandra A. Zalman, J. P. Chanton, J. Kostka, P. J. Hanson, Jason K. Keller, S. D. Bridgham
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research
Peatlands contain one-third of the world’s soil carbon (C). If destabilized, decomposition of this vast C bank could accelerate climate warming; however, the likelihood of this outcome remains unknown. Here, we examine peatland C stability through five years of whole-ecosystem warming and two years of elevated atmospheric carbon dioxide concentrations (eCO2). Warming exponentially increased methane (CH4) emissions and enhanced CH4 production rates throughout the entire soil profile; although surface CH4 production rates remain much greater than those at depth. Additionally, older deeper C sources played a larger role in decomposition following prolonged warming. Most …
Synergistic Use Of Remote Sensing And Modeling For Estimating Net Primary Productivity In The Red Sea With Vgpm, Eppley-Vgpm, And Cbpm Models Intercomparison, Wenzhao Li, Surya Prakash Tiwari, Hesham El-Askary, Mohamed Ali Qurban, Vassilis Amiridis, K. P. Manikandan, Michael J. Garay, Olga V. Kalashnikova, Thomas C. Piechota, Daniele C. Struppa
Synergistic Use Of Remote Sensing And Modeling For Estimating Net Primary Productivity In The Red Sea With Vgpm, Eppley-Vgpm, And Cbpm Models Intercomparison, Wenzhao Li, Surya Prakash Tiwari, Hesham El-Askary, Mohamed Ali Qurban, Vassilis Amiridis, K. P. Manikandan, Michael J. Garay, Olga V. Kalashnikova, Thomas C. Piechota, Daniele C. Struppa
Mathematics, Physics, and Computer Science Faculty Articles and Research
Primary productivity (PP) has been recently investigated using remote sensing-based models over quite limited geographical areas of the Red Sea. This work sheds light on how phytoplankton and primary production would react to the effects of global warming in the extreme environment of the Red Sea and, hence, illuminates how similar regions may behave in the context of climate variability. study focuses on using satellite observations to conduct an intercomparison of three net primary production (NPP) models--the vertically generalized production model (VGPM), the Eppley-VGPM, and the carbon-based production model (CbPM)--produced over the Red Sea domain for the 1998-2018 time period. …
Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber
Reconstructing Hydrologic Conditions And Metals Supplied By The Peace River To The Peace-Athabasca Delta, Jelle André Faber
Theses and Dissertations (Comprehensive)
The Peace-Athabasca Delta (PAD) in northern Alberta, Canada, is recognized internationally for its ecological, historical, and cultural significance. The delta is mostly within Wood Buffalo National Park, a UNESCO World Heritage Site, and is a Ramsar Wetland of International Importance. The construction of the WAC Bennett Dam (1967) and the Site C Dam (ongoing, 2024) on the Peace River, and expansion of the Alberta Oil Sands industry along the Athabasca River have raised concerns over water quantity and quality in the delta. When industry operations began, effective monitoring had not been implemented. Consequently, pre-industrial reference conditions are unknown and can …
Sustainable Solutions, Fall/Winter 2020, Issue 41
Sustainable Solutions, Fall/Winter 2020, Issue 41
Sustain Magazine
No abstract provided.
Environmentally Responsible Land Use, Spring/Summer 2010, Issue 22
Environmentally Responsible Land Use, Spring/Summer 2010, Issue 22
Sustain Magazine
No abstract provided.
Sustainable Communities, Fall/Winter 2010, Issue 21
Sustainable Communities, Fall/Winter 2010, Issue 21
Sustain Magazine
No abstract provided.
Sustainable Building, Spring/Summer 2009, Issue 20
Sustainable Building, Spring/Summer 2009, Issue 20
Sustain Magazine
No abstract provided.
Environmental History, Fall/Winter 2009, Issue 19
Environmental History, Fall/Winter 2009, Issue 19
Sustain Magazine
No abstract provided.
Student Research, Spring/Summer 2008, Issue 18
Evolving Pollution Prevention, Fall/Winter 2008, Issue 17
Evolving Pollution Prevention, Fall/Winter 2008, Issue 17
Sustain Magazine
No abstract provided.
Climate Change, Spring/Summer 2007, Issue 16
Our Energy Future, Fall/Winter 2007, Issue 15
Land Conservation, Spring/Summer 2006, Issue 14
Land Conservation, Spring/Summer 2006, Issue 14
Sustain Magazine
No abstract provided.
Pollution And Heart Disease, Fall/Winter 2006, Issue 13
Pollution And Heart Disease, Fall/Winter 2006, Issue 13
Sustain Magazine
No abstract provided.