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Analytical Chemistry Commons

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University of Tennessee, Knoxville

Optical Sensors

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Full-Text Articles in Analytical Chemistry

Optical Sensors For The Analysis Of Alcohols In Fuels, Kendhl Kate Witt May 2016

Optical Sensors For The Analysis Of Alcohols In Fuels, Kendhl Kate Witt

Masters Theses

This thesis reports the development of optical sensors to analyze alcohols in fuel samples. One optical sensor enables the analysis of phenol in aviation fuels and cellulosic biofuels. It is critical to monitor the concentration of phenols in fuels because they increase the presence of solid oxidative deposits and lower the thermal stability of fuels. Preliminary studies of another optical sensor have been conducted to detect ethanol in E10 gasoline samples. Gasoline containing ethanol is widely available and used, but the exact percentage of ethanol is not specified and varies between samples and regions. Higher concentrations of ethanol in gasoline …


New Electrochemical And Optical Detection Methods For Biological And Environmental Applications, Royce Nicholas Dansby-Sparks Aug 2010

New Electrochemical And Optical Detection Methods For Biological And Environmental Applications, Royce Nicholas Dansby-Sparks

Doctoral Dissertations

Detection of chromium and vanadium is of interest for biomedical and environmental applications. The two metals have narrow limits between being essential and toxic for humans. Ultra-sensitive techniques have been studied to measure Cr and V at low concentrations found in human blood and environmental samples. Bismuth film and mercury-alloy electrodes have been developed as alternatives to traditional Hg-based electrodes for Cr and V detection. While catalytic adsorptive stripping voltammetry (CAdSV) has been used to detect Cr and V, little is known about the process. The mechanisms of CAdSV have been probed to provide a better understanding of its exceptional …