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Full-Text Articles in Analytical Chemistry
Improved Sample Utilization In Thermal Ionization Mass Spectrometry Isotope Ratio Measurements: Refined Development Of Porous Ion Emitters For Nuclear Forensic Applications, Matthew Louis Baruzzini
Improved Sample Utilization In Thermal Ionization Mass Spectrometry Isotope Ratio Measurements: Refined Development Of Porous Ion Emitters For Nuclear Forensic Applications, Matthew Louis Baruzzini
Doctoral Dissertations
The precise and accurate determination of isotopic composition in nuclear forensic samples is vital for assessing origin, intended use and process history. Thermal ionization mass spectrometry (TIMS) is widely accepted as the gold standard for high performance isotopic measurements and has long served as the workhorse in the isotopic ratio determination of nuclear materials. Nuclear forensic and safeguard specialists have relied heavily on such methods for both routine and atypical efforts. Despite widespread use, TIMS methods for the assay of actinide systems continue to be hindered by poor ionization efficiency, often less than tenths of a percent; the majority of …
Rapid Dissolution For Destructive Assay Of Nuclear Melt Glass, Jonathan Allen Gill
Rapid Dissolution For Destructive Assay Of Nuclear Melt Glass, Jonathan Allen Gill
Masters Theses
This study evaluates four methods for dissolving complex glassy debris resulting from nuclear detonations. The samples of interest simulate the glassy debris generated from a nuclear detonation’s fireball coming in contact with solid masses. Each method attempts to achieve dissolution through different approaches involving either acid digestion, alkaline digestion, or molten salt fusion. Two of the four methods were modified to retain all elements of the debris or surrogate debris. This retention is critical to the proportional relationships used in identifying fuel types and designs of nuclear weapons. Analysis is conducted with an inductively coupled time of flight mass spectrometer …