Chemistry Commons^™

Polarography As A Measure Of Ionic Environment, James Wilburne Larsen

University of the Pacific Theses and Dissertations

The present work is a polarographic study of the alkali metals and selected first row transition metals in DMSO (dimethylsulfoxide) with tetraethylammonium perchlorate as a supporting electrolyte. DMSO was chosen as a solvent because of its interesting solvent and complexing properties. Tetraethylammonium perchlorate was chosen as a supporting electrolyte because of its lack of complex forming tendencies and because of the wide range of voltages available for polarographic investigation before the supporting electrolyte ions react electrochemically.

One of the problems, particularly in nonaqueous polarography, is the low conductivity of the solutions leading to high cell resistance. As current flows through …

Polarography Of Selected Metal Ions In Anhydrous Aliphatic Diamines, Frederick William Foss Jr.

University of the Pacific Theses and Dissertations

A search of the literature revealed that no study has sought to measure and compare the polarographic solvent properties of the anhydrous aliphatic diamines. In fact, there has been no reported instance of the use of anhydrous 1,3-propanediamine or 1,4-butanediamine in any electro- chemical system.

Anomers Of D-Galactosamine Benzoates, Robert Stanley Strong

University of the Pacific Theses and Dissertations

D-Galactosamine has been known as one of the rarer amino sugars, occurring widely distributed in small concentrations in living organisms. The biological importance of D-galactosamine and its derivatives was thought to justify a study of the chemical properties of this group of compounds. As a result of this study the reactions of D-galactosamine have been found to differ more than previously thought from those of D-glucosamine, the more common amino sugar

For this investigation D-galactosamine hydrochloride was isolated from chondroitin sulfate, a polysaccharide obtained from the cartilaginous tissues of animals. This was changed by appropriate reactions to the 1,3,4,6-tetra-0-benzoyl-N-carbobenzoxy-α-β-D-galactosamine (III). …

Some Spectrophotometric Studies Of Molecular Complexes For Phenanthrene, Anthracene, Pyrene, Chrysene, And Benzanthracene With Iodine Monochloride, Joe Boyd Coacher

University of the Pacific Theses and Dissertations

The principal purpose of the present study was to prove the existence of the weak interaction between the halogenoid iodine monochloride and the condensed polycyclic aromatic hydrocarbons, phenanthrene, anthracene pyrene, chrysene, and benzanthracene (see Figure 1).

Studies In The Behavior Of Certain Cyclic Olefins Toward Divalent Platinum And Palladium, Ernest Sam Juljian

University of the Pacific Theses and Dissertations

The initial program of study for consideration was the extension of cyclooctatetraene complexation to other metals of the transition group. Compounds of (COT) with iron, cobalt, chromium, molybdenum, and tungsten which have been reported in the literature involve carbonyl ligands simultaneously as (COT)M(CO)_x with x = 2,3----; only Ag(I) as AgN03 adducts are known. Rhodium (I) is said to form an unstable dimer while ruthenium (I) forms a polymer. (COT)Pt(II) chloride, bromide and iodide have been reported but only the iodide has been studied; only (COT)PdCl₂ has been reported recently. It was further conceived that substituted (COT) would …

The Transition Metal Complexes Of Anthranilic Acid And Its Derivatives, Jesse Smith Decker

University of the Pacific Theses and Dissertations

Part of this investigation was undertaken to determine the effects of functional group substitution on the ring - as well as on the -NH₂ radical - on the formation of metal complexes with the first transition series in the periodic classification of the elements.

The outline of the investigation in this report is as follows: (1) To mind methods for the preparation of the complexes.; (2) To examine the relative ease of formation, and the relative solubility of such chelates in common laboratory reagents.; (3) To determine the relative stabilities by relative molar conductance measurements.; (4) To discover relative …

High Temperature Adsorption Studies On Solid Adsorbents, Julian Joseph Hamerski

University of the Pacific Theses and Dissertations

It has been found that there exist certain crystalline aluminosilicates which provide regular net-works of channels with diameters no bigger than those of molecules. Such crystals can act as sieves (thus the name "molecular sieves" now marketed by the Linde Air Products Company) and bring about a separation of molecular species by occluding small molecules while not adsorbing larger molecules or molecules with shapes that do not "fit."

The aluminosilicates were termed zeolites first by Baron Cronstedt (1) some 200 years ago. He observed that certain mineral crystals, when heated, appeared to melt and to boil at the same time. …

High Frequency Titrations In Liquid Ammonia, Jack Charles Hileman

University of the Pacific Theses and Dissertations

An extensive literature has been established on the use of high frequency conductometric methods in chemical analysis and research. The fact that the instruments respond to chemical changes without having electrodes immersed in the reacting solutions has attracted the attention of many investigators. Until the last few years, practically all of the investigations were concerned with aqueous solutions, with the exception of measurements of dielectric constants.

There seemed no logical reason for not extending the use of the high frequency instruments to the study of Bronsted acid-base reactions, organic syntheses, rates of reaction, and the other commonly studied aspects of …

Determination Of Thallium(Iii) Using The Dead-Stop End Point, Richard Blount Williams

University of the Pacific Theses and Dissertations

An accurate and fairly rapid method of analysis of thallium solutions is desirable in order to facilitate further investigation of the chemistry of thallium. The dead-stop titration method which has been successfully applied to other metals of Group 3b, will not be applied to the quantitative determination of the thallium (III) ion in aqueous solution.

Hydroxy Derivatives Of Benzalthiophenone, John M. Newey

University of the Pacific Theses and Dissertations

It is the purpose of this work to prepare a series of these chalcones containing the thiophene ring.

The compounds were prepared by the condensation of a series of benzaldehydes with acetylthiophene dissolved in dry ethylacetate and saturated with dry HCl. The benzaldehyde compounds were benzaldehyde, m-hydroxybenzaldehyde, o-hydroxybenzaldehyde, O-p-dihydroxybenzaldehyde and vanillin. To prevent the oxidation of the hydroxy groups of the benzaldehydes, the compounds were benzolated with benzoylchloride. The condensed products were debenzoylated with NaOH solution in an atmosphere of nitrogen to prevent oxidation during the debenzoylation process.

A Laboratory-Centered General Chemistry Course For College Freshmen, Alexander Vavoulis

University of the Pacific Theses and Dissertations

In order to give the laboratory-centered course a trial run and to compare it with a lecture-centered course it seemed necessary to the author that both courses should be taught and compared. The latter gave rise to the following hypotheses:

1. Students in a laboratory-centered general chemistry course show more favorable attitudes toward chemistry than do students in a lecture-centered course.
2. Students in a laboratory-centered course show as good a subject-matter mastery as students in a lecture-centered course.

A New Approach To General Chemistry Laboratory In College (With) A Laboratory Manual For General Chemistry, Constantine G. Vlassis

University of the Pacific Theses and Dissertations

Statement of the problem. This study was carried out to determine: (1) what advantages a laboratory-centered general chemistry course might have over the conventional laboratory course, and (2) whether improved understanding of laboratory work leads to better learning of chemistry. The four following questions were raised in connection with the study or this problem:

1. What is the need for a laboratory-centered course?
2. What has been done in the past to meet this need?
3. Can students learn chemistry more effectively in a laboratory-centered course as compared to the conventional course?
4. Is a laboratory-centered course to be preferred over the conventional course …

The Determination Of Ethanol In Aqueous Solution By Gas-Liquid Partition Chromatography, Robert L. Morrison

University of the Pacific Theses and Dissertations

The present chemical and physical methods for the determination of ethyl alcohol are all subject to systematic errors derived from any of a number of interfacing substances usually present in solution with the ethanol. Some of the most popular methods are slow and tedious and require a good deal of skill and technique to perform. The dichromate (2), pycnometer and refractometer methods are three such methods. The interfering substances most often present in industrial and food products are fusel oils and acetaldehyde. These substances interfere in the three methods just mentioned. It is of course possible to analyze for these …

Construction And Calibration Of Equipment For Obtaining Heat Capacity Data At High Temperatures, David Wells Wood

University of the Pacific Theses and Dissertations

This is a study of the heat capacity substances at high temperatures at determined by means of drop-calorimetry. The heat capacity may be defined as the quantity of heat required to raise the temperature of a substance by 1^o C. This can be expressed as [see PDF file for formula]. The concept of heat capacity is used in connection with a certain defined path such as those of constant volume or constant pressure. The following definitions apply: [see PDF file for formula] = heat capacity at constant volume and [see PDF file for formula] = heat capacity at constant …

Condensation Reaction Of Terephthaladehyde And Acetophenone, Lloyd J. Mitchell

University of the Pacific Theses and Dissertations

The plant pigments constitute a fascinating group of compounds whose constitution has only recently been partially clarified. Roughly speaking, there are two main groups of pigment: the plastids, associated with the protoplasmic structure of plants, and the anthocyanins, generally found in solution in the cell sap. The term “anthocyanin” is derived from the Greek, “antho” signifying flower and “cyan” meaning blue, and was introduced by the botanist Marquart in 1835 to designate the blue pigments of flowers. It has since been extended to include all of the pigments of this group, the anthocyanin pigments being responsible for the innumerable shades …

Anhydrous Alcohol And The Vapor Phase Method Of Preparing It, Cleetis Brown

University of the Pacific Theses and Dissertations

Since the almost universal laboratory method of preparing absolute alcohol requires considerable time and trouble, gives a low yield of alcohol and leaves a distilling flask badly clogged with hydrated lime, Professor S.S, Kistler and I undertook the following research in the hope that we might devise a new method that would be both rapid and easy to perform.

Upon reviewing the possibilities, it seemed evident that any method to be rapid would have to involve drying In the vapor phase. Diffusion in a liquid being so slow that when a drying agent is placed in the liquid phase an …

A Study Of The Effect Of Temperature Upon Reactions Between Stannous And Arsenate Ions In Silicic Acid Gels, Ellis Elder

University of the Pacific Theses and Dissertations

Chapter I: Statement of the Problem

The purpose of this investigation was to determine to what extent the reaction between stannous and arsenate ions in silicic acid gels is influenced by temperature.

This was to be done by observing (1) the rate of crystal growth; and (2) the appearance of the crystal growth in sets of gels identical in composition but kept at different temperatures throughout the process of crystal growth.