Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 2 of 2
Full-Text Articles in Chemistry
Characterization And Co Oxidation Activity Studies Of Co-Based Catalysts, Fi̇li̇z Balikçi, Çi̇ğdem Güldür
Characterization And Co Oxidation Activity Studies Of Co-Based Catalysts, Fi̇li̇z Balikçi, Çi̇ğdem Güldür
Turkish Journal of Chemistry
Cobalt oxide based catalysts were developed for carbon monoxide oxidation at low temperature. The catalysts were prepared by co-precipitation and calcined at 200 °C. Several techniques were used to characterize the catalysts, such as X-ray diffractometer system, N_2 physisorption measurements, scanning electron microscope (SEM), and X-ray photoelectron spectroscopy. Carbon monoxide oxidation studies were carried out to investigate the relation between the characteristic properties of the catalysts and the catalytic activity. Catalytic activity measurements were studied from room temperature to 200 °C, using a feed composition of 1% CO, 21% O_2, and remaining He. X-ray studies showed that the catalysts have …
Kinetic Study Of Selective Co Oxidation Over Pt-Co-Ce/Al_2o_3 Catalyst In Hydrogen-Rich Streams, Göktuğ Nezi̇hi̇ Özyönüm, Ayşe Ni̇lgün Akin, Ramazan Yildirim
Kinetic Study Of Selective Co Oxidation Over Pt-Co-Ce/Al_2o_3 Catalyst In Hydrogen-Rich Streams, Göktuğ Nezi̇hi̇ Özyönüm, Ayşe Ni̇lgün Akin, Ramazan Yildirim
Turkish Journal of Chemistry
The kinetics of the selective CO oxidation was studied in a fixed-bed microreactor at atmospheric pressure over Pt-Co-Ce/Al_2O_3 catalyst, which was prepared using the incipient to wetness co-impregnation technique. Intrinsic kinetic data were obtained in the initial rate region using 8 different sets of CO and O_2 concentrations, each at 2 space times, i.e. 2 catalyst loadings, at 110 °C. The kinetic models based on elementary reaction steps were constructed and tested using nonlinear regression analysis with Levenberg-Marquardt algorithm. The alternative models proposed for the similar catalytic systems in the literature were also tested. It was found that Pt-Co-Ce/Al_2O_3 acts …