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Full-Text Articles in Chemistry

Rational Design Of Multifunctional Nanocatalysts For Environmental Remediation And Energy Conversion Technologies, Md Ariful Ahsan Dec 2021

Rational Design Of Multifunctional Nanocatalysts For Environmental Remediation And Energy Conversion Technologies, Md Ariful Ahsan

Open Access Theses & Dissertations

The discovery of efficient and sustainable carbon-based nanotechnologies to solve both the scarcity of drinking water and global energy crisis has become a paramount task in the last decades. Owed to the fast population growth and industrialization of the modern society, access to potable water and clean energy technologies is becoming very hard around the globe. Water pollutants have become a serious threat to the environment and ecology because of their toxic nature. Parallelly, the current hydrocarbon-based fuel industries are generating high levels of contamination across the planet, making imperative the development of cleaner energy technologies. In this regard, the …


Synthesis, Characterization, And Catalytic Activity Of Functionalized Metal Bis(Thiosemicarbazones)., Caleb Aaron Calvary Aug 2021

Synthesis, Characterization, And Catalytic Activity Of Functionalized Metal Bis(Thiosemicarbazones)., Caleb Aaron Calvary

Electronic Theses and Dissertations

Bis-(thiosemicarbazones) are a class of ligands that have found a wide range of uses from electrocatalysts to medicinal and diagnostic reagents. These ligands contain a diimine backbone, N2S2 chelating core, and pendent amines. In order to further explore this class of ligands, the previously underreported transamination reaction, which exchanges one pendent amine group for another, was utilized to create several derivatives using aliphatic and aromatic amines. The transamination reaction is appealing alternative to making the desired thiosemicarbazide. Further appeals come from the fact that it is a one-pot reaction that gives highly pure products in good yields. …