Physical Sciences and Mathematics Commons^™

Survey Of The Performance Of 5 Nm Goldnanoparticles Within An Ssdna-Stabilizedbiosensor For The Detection Of Hg2+, Madalyn J. Zagajowski

ELAIA

The formation of a fluorescent biosensor complex consisting of 5 nm diameter gold nanoparticles (AuNPs) and single-stranded DNA (ssDNA) was conducted using a low-cost, efficient binding method. The analytical potential for the complex to detect mercuric ions (Hg2+) in an aqueous solution was assessed through the collection of UV-vis and fluorescence spectrometry data for the AuNP-ssDNA complex. The researcher aimed to investigate this potential in case the nanoparticles formed utilizing this method were too small to result in detectable fluorescence. To eliminate this possibility, the complex synthesized from this specific method was qualitatively evaluated to determine if it consistently and …

The Impact Of The Use Of Mercury In Mining In Colombia, Johan Martinez

CMC Senior Theses

Artisanal and small-scale gold mining is a practice that is common all around the world, especially in Latin America, Africa, and Asia. It is also one of the leading consumers of mercury and leading sources of emissions. Governments have banned the use of mercury completely, including Colombia, but it continues to be used and emitted into the environment. This issue is exacerbated because there is a lack of standards, a lack of research done regarding mercury use in mining, and a complex socio-political history in Colombia. For this reason, this paper seeks to provide a proposed pathway for research to …

Preliminary Assessment For Critical Minerals In The Terlingua Quicksilver District, Texas And Tres Marias Mine, Chihuahua, Mexico, Eduardo Lee Zuniga

Open Access Theses & Dissertations

The Terlingua Quicksilver district was discovered around the 1880s and was a mercury producing district from 1900 through 1946. The most productive years were during World War one and two. From 1900-1946 the Terlingua Quicksilver District (TQD) produced 150,000 flasks; 80% came from three mines: the Rainbow-Chisos, Mariposa, and Study Butte mines. The structural controls of the Mercury mineralization within these mines are breccia pipes and fractures, often located near igneous intrusions. This study will assess the potential for Critical Minerals and Rare Earth Elements in the Terlingua Quicksilver District. Fifty-five samples have been collected and analyzed for forty-four different …

Revised Final Multi-Pathway Residential Metals Abatement Program Plan, Atlantic Richfield Company, Butte Silver Bow

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Large-Scale Volcanism On The Terrestrial Planets, Keenan Ben Golder

Doctoral Dissertations

Evidence for mafic volcanism has been found on each planet in the inner Solar System. Lava flows on these planets range in size from 10s to 1000s of kilometers in extent. I investigated large-scale lava flows on Mercury, Earth, and Mars throughout the chapters in this dissertation. Each of these lava flows provides an avenue to study the emplacement and evolution of lava on various planets and under differing conditions, the factors that affect their overall extent, and potential source areas.

Chapter One investigates large-scale lava flows in the Cerberus region on Mars, specifically to understand their emplacement history, material …

Survey Of The Performance Of 5 Nm Gold Nanoparticles Within An Ssdna-Stabilized Biosensor For The Detection Of Hg2+, Madalyn Zagajowski

Honors Program Projects

The formation of a fluorescent biosensor complex consisting of 5 nm diameter gold nanoparticles (AuNPs) and single-stranded DNA (ssDNA) was conducted using a low-cost, efficient binding method. The analytical potential for the complex to detect mercuric ions (Hg²⁺) in an aqueous solution was assessed through the collection of UV-vis and fluorescence spectrometry data for the AuNP-ssDNA complex. The researcher aimed to investigate this potential in case the nanoparticles formed utilizing this method were too small to result in detectable fluorescence. To eliminate this possibility, the complex synthesized from this specific method was qualitatively evaluated to determine if it …

Survey Of The Performance Of 5 Nm Gold Nanoparticles Within An Ssdna-Stabilized Biosensor For The Detection Of Hg2+, Madalyn Zagajowski

Scholar Week 2016 - present

The formation of a fluorescent biosensor complex consisting of 5 nm diameter gold nanoparticles (AuNPs) and single-stranded DNA (ssDNA) was conducted using a low-cost, efficient binding method. Furthermore, we assessed the analytical potential for the complex to detect mercury ions (Hg²⁺) in an aqueous solution upon collection of UV-vis and fluorescence spectrometry data for the AuNP-ssDNA complex. We aimed to investigate this potential due to the possibility that the nanoparticles formed utilizing this method would produce nanoparticles of too small a size to result in detectable fluorescence, thus the complex synthesized from this specific method was qualitatively evaluated …

Diagnostic Gold Deportment Studies And Leaching Behaviour Of Small-Scale Gold Mining Tailings From Eastern Region, Ghana, Ishmael Quaicoe, Martin Beyuo, Solomon Quaicoe, Nikao A. Lasidzi

Journal of Sustainable Mining

Artisanal and small-scale gold mining (ASGM) sector employs about 80% of the mining workforce but only contributes about 20-30% of Ghana’s gold production. The low gold production is linked to low recoveries associated with the activities because ofinadequate understanding of the chemical, mineralogical and metallurgical characteristics of the ores. This study examined the metallurgical characteristics of typical small-scale gold mining tailings to understand their grinding characteristics, gold deportment and cyanidation behaviour. The gold deportment results showed that 96.1% of the gold in the samples is free milling (can be leached directly with cyanide and recovered through carbon adsorption), whilst the …

Table1 Erm Rmap Dust 2022 Revision Summary - Final Qualified, Environmental Resource Management (Erm)

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Rmap Interior Schools Project, Liz Stacks

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

2021 2q Btl Chem Dump, Environmental Protection Agency, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Mercury Methylation Potentials In Sediments Of An Ancient Cypress Wetland Using Species-Specific Isotope Dilution Gc-Icp-Ms, Derek D. Bussan, Chris Douvris, James V. Cizdziel

Faculty and Student Publications

Wetlands are of a considerable environmental value as they provide food and habitat for plants and animals. Several important chemical transformations take place in wetland media, including the conversion of inorganic mercury (Hg) to monomethylmercury (MeHg), a toxic compound with a strong tendency for bioconcentration. Considering the fact that wetlands are hotspots for Hg methylation, we investigated, for the first time, Hg methylation and demethylation rates in an old growth cypress wetland at Sky Lake in the Mississippi Delta. The Sky Lake ecosystem undergoes large-scale water level fluctuations causing alternating periods of oxic and anoxic conditions in the sediment. These …

Butte Priority Soils Operable Unit (Bpsou) Revised Final Residential Metals Abatement Program (Rmap) Plan, Mike Mcanulty

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Re: Butte Priority Soils Operable Unit (Bpsou) Revised Final Residential Metals Abatement Program (Rmap) Plan, Mike Mcanulty

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Predicting Contaminant Transfer Following Re-Established Connectivity In The Boardman River, Ross A. Gay

All NMU Master's Theses

Anthropogenic alteration of the environment began as soon as people settled the Great Lakes (GL) region with hydrologic alteration (dams) and discharges of man-made chemicals into the air and water as populations and industry expanded. Consequently, the GL became a reservoir of anthropogenic contaminants such as mercury (Hg), polychlorinated biphenyls (PCBs), dichloro-diphenyl-trichloroethylene (DDT), and organochloride compounds. Migratory fish accumulate and magnify contaminants within their tissues and transport them across ecosystem boundaries. Re-established connectivity in the form of dam removal has the potential to allow contaminant laden migrants access to ecosystems previously inaccessible. Here I assess the contaminant burden of a …

Investigating The Mechanisms Driving Mercury Reduction And Emissions In Soil, Hamil Patel

Student Theses

The water-induced emission of mercury from soil has been studied, but a complete understanding of the mechanisms driving mercury reduction and emission in soil has not been reached. The current understanding is an immediate expulsion of soil gaseous mercury upon water treatment and an upward transport of dissolved soil ionic mercury as the water evaporates. We analyzed emissions from several types of samples using various methods to further our understanding on the mechanisms involved. Light-induced emissions from aqueous samples of humic acid (HA) spiked with mercury (II) chloride (HgCl₂) showed that at higher concentrations of HA, less mercury …

Correlations Between The Rotations And Magnetospheres Of The Terrestrial Planets And The Sun's Formation In Our Solar System, Fred J. Cadieu

Publications and Research

Correlations between the rotations of the terrestrial planets in our solar system and the magnetic field of the Sun have been previously noted. These correlations account for the opposite rotation of Venus as a result of the magnetic field of the Sun being dragged across the conducting core of Venus. Currently the Sun’s magnetic field is not sufficiently strong to account for the proposed correlations. But recently meteorite paleomagnetism measurements have indicated that during the Sun’s formation the magnetic field of the Sun was of sufficient strength to have resulted in the observed correlations. As a part of these correlations …

Cysteine Metallochemistry And Metal Binding: Quantification Of The Thermodynamic Foundations Of Cellular Homeostasis, Matthew R. Mehlenbacher

Dartmouth College Ph.D Dissertations

Metals are required for life. Many metalloproteins contain cysteine in their metal-binding site (MBS) and cysteines are unique in that they are reactive, and strongly bind certain metals, which aid in metal selectivity and specificity. Using isothermal titration calorimetry (ITC), the thermodynamic foundation for metal binding, cellular protection, and transcriptional regulation, which all utilize cysteines in their MBS, are quantified.

In bacteria there are metalloprotein pathways that actively uptake mercury, which are regulated by the metalloregulatory protein MerR. MerR de-represses the transcription of these mer proteins in a metal-dependent manner. Using ITC, the thermodynamic foundation of the negative allosteric coupling …

Residential Metals Abatement Program Quality Assurance Project Plan (Non-Residential Parcels - Indoor Dust), Elsie King, Christopher Berg, Environmental Resource Management (Erm)

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Mercury Concentrations And Mercury Methylation Along The Freshwater To Marine Continuum, Lindsay D. Starr

Browse all Theses and Dissertations

Mercury (Hg) is a neurotoxin that can have detrimental impacts on the human nervous system and on brain development in infants. Methylmercury (MeHg) is the most toxic form of Hg and can concentrate to potentially harmful levels in higher levels of marine food webs. Production of MeHg in oxic water columns is poorly understood due to lack of knowledge of the mechanisms of formation and distribution. Recent work has reported widespread, putative Hg methylation genes in nitrite oxidizers, but any relationship with nitrifiers is unknown. This work focuses on Hg water column distribution, speciation, and methylation. The aims of this …

Mercury Contamination In Selected Edible Plants And Soil From Artisanal And Small-Scale Gold Mining In Sukabumi Regency, Indonesia, Grace Serepina Saragih, Ely Rahmi Tapriziah, Yunesfi Syofyan, Siti Masitoh, Yohana Sari Hotmatua Pandiangan, Andriantoro Andriantoro

Makara Journal of Science

Artisanal and small-scale gold mining (ASGM) activities often pollute soil, water, and air, thereby achieving widespread proliferation, and contaminating the surrounding biota including plants. Mercury contamination on agricultural land around ASGM areas has been widely reported. This study aims to determine the total mercury contamination in plants and soil around active ASGM sites in Sukabumi Regency, Indonesia, namely, Waluran, Lengkong, and Ciemas Districts. Total mercury (Hg) content was measured from 27 plant samples (including cassava [Manihot utilisima], rice [Oryza sativa], and papaya [Carica papaya]), 7 rhizosphere soil samples, and 7 non-rhizosphere soil samples. Data …

Butte-Silver Bow Medical Monitoring Program Plan, Mike Mcanulty, Eric Hassler

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Using Sedimentary Mercury Geochemistry To Evaluate The Niagara-Salina Transition, Silurian Michigan Basin, Usa, Sara Hayes

Masters Theses

The Niagara-Salina boundary in the Michigan Basin is marked by an abrupt transition from carbonates to evaporites. Though the cause is uncertain, previous work suggests the onset of Salina evaporites was driven by basin restriction, but the presence of several global carbon isotope excursions (CIE) suggest a global driver. This study builds on this discussion using two relatively new geochemical proxies - elemental mercury concentrations [Hg] and Hg isotopes.

Mercury concentrations [Hg] were measured in 88 samples from the State Kalkaska #2-15 core from 6604.03 ft to 6797.42 ft. [Hg] ranges from 0.11 to 0.62 mg/kg and [Hg]/TOC from 0.038 …

Response To Comments For 2020 Bpsou Uao Submittal: Revised Final Multi-Pathway Residential Metals Abatement Program Plan (Received January 21, 2021), Mike Mcanulty

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

10587273 Edd, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

10586986 Edd, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Comments For: Draft Residential Metals Abatement Program Quality Assurance Project Plan (Non-Residential Parcels), Atlantic Richfield Company And Butte- Silver Bow County, Dated October 8, 2021, Nikia Greene

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Ligands For Complexation, Extraction, And Sensing Of Mercury(Ii) For Application To High-Level Waste (Hlw) At The Savannah River Site (Srs), Adenike O. Fasiku

FIU Electronic Theses and Dissertations

Mercury (Hg) separation and sensing is of high significance due to Hg^(II) environmental mobility and toxicity. Furthermore, the use of Hg in nuclear applications has resulted in its accumulation in several DOE sites, such as in Oak Ridge and Savannah River reservations. Organic mercury species have been found in low activity waste (LAW) streams resulting from high-level waste (HLW) processing at the Savannah River Site (SRS), therefore posing a threat to humans and the environment. Mercury, being a soft Lewis acid, has a strong affinity for softer Lewis bases, such as S- or N-donor ligands. Therefore, we focus on …

Attachment D To The Dsr; Work Order 10577874, 10584152 Edd, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

10578891 Edd, Pioneer Technical Services, Inc.

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.