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Full-Text Articles in Physical Sciences and Mathematics

Atomistic Assessment Of Drug-Phospholipid Interactions Consequent To Cancer Treatment: A Study Of Anthracycline Cardiotoxicity, Yara Elsayed Ahmed Jun 2023

Atomistic Assessment Of Drug-Phospholipid Interactions Consequent To Cancer Treatment: A Study Of Anthracycline Cardiotoxicity, Yara Elsayed Ahmed

Theses and Dissertations

Despite being one of the most effective chemotherapeutic agents developed to date, Anthracyclines are notorious for their cardiotoxicity. Their clinical use is frequently limited both in dosage and in prescription due to the severe cardiac damage they cause. The mechanism of anthracycline-induced cardiotoxicity is not yet fully understood. However, it is hypothesized that interactions with the myocardial membrane play an important role in imparting cardiotoxicity. In this study, we use molecular dynamics simulations and density functional theory calculations to study the anthracycline drug molecules and the interactions that they have with the myocardial membrane. We construct a myocardial membrane model …


Beyond Hcahps: Analysis Of Patients’ Comments Provides An Expanded View Of Their Hospital Experiences, Andrew S. Gallan, Rakesh Niraj, Awanindra Singh Apr 2022

Beyond Hcahps: Analysis Of Patients’ Comments Provides An Expanded View Of Their Hospital Experiences, Andrew S. Gallan, Rakesh Niraj, Awanindra Singh

Patient Experience Journal

An important concern for health care professionals is that standardized patient surveys may not fully capture all the topics that are important to patients. As a result, health care professionals may not have a complete picture of what their patients experience. The purpose of this research is to utilize a state-of-the-art Natural Language Processing technique to make sense of patients’ solicited, unstructured comments to gain a deeper and broader understanding of their experiences in the hospital. We analyzed a large dataset of inpatient survey responses (48,592 patients generating 65,998 comments) by a patient experience survey vendor for an eleven-hospital health …


Beam-Recoil Transferred Polarization In K+Y Electroproduction In The Nucleon Resonance Region With Clas12, D. S. Carman, A. D'Angelo, L. Lanza, V. I. Mokeev, K. P. Adhikari, M. J. Amaryan, W. R. Armstrong, H. Atac, H. Avakian, C. Ayerbe Gayoso, N. A. Baltzell, L. Barion, M. Battaglieri, I. Bedlinskiy, B. Benkel, A. Bianconi, A. S. Biselli, M. Bondi, S. Boiarinov, V. Ziegler Jan 2022

Beam-Recoil Transferred Polarization In K+Y Electroproduction In The Nucleon Resonance Region With Clas12, D. S. Carman, A. D'Angelo, L. Lanza, V. I. Mokeev, K. P. Adhikari, M. J. Amaryan, W. R. Armstrong, H. Atac, H. Avakian, C. Ayerbe Gayoso, N. A. Baltzell, L. Barion, M. Battaglieri, I. Bedlinskiy, B. Benkel, A. Bianconi, A. S. Biselli, M. Bondi, S. Boiarinov, V. Ziegler

Physics Faculty Publications

Beam-recoil transferred polarizations for the exclusive electroproduction of K + Λ and K + Σ0 final states from an unpolarized proton target have been measured using the CLAS12 spectrometer at Jefferson Laboratory. The measurements at beam energies of 6.535 and 7.546 GeV span the range of four-momentum transfer Q2 from 0.3 to 4.5 GeV2 and invariant energy W from 1.6 to 2.4 GeV, while covering the full center-of-mass angular range of the K+. These new data extend the existing hyperon polarization data from CLAS in a similar kinematic range but from a significantly larger dataset. …


Law Library Blog (December 2021): Legal Beagle's Blog Archive, Roger Williams University School Of Law Dec 2021

Law Library Blog (December 2021): Legal Beagle's Blog Archive, Roger Williams University School Of Law

Law Library Newsletters/Blog

No abstract provided.


Investigation Of Interactions Between 1,3 Dialkyl Imidazolium Ionic Liquids And Lignocellulosic Polymers, Aparna Annamraju May 2021

Investigation Of Interactions Between 1,3 Dialkyl Imidazolium Ionic Liquids And Lignocellulosic Polymers, Aparna Annamraju

Doctoral Dissertations

Lignocellulosic biomass is a potential energy source for fuels, chemicals and materials production in a sustainable manner. A network of covalent and non-covalent bonds between the three main polymers of biomass, i.e., cellulose, hemicellulose and lignin, results in a compact structure that is resistant to chemical and biological attacks and therefore challenging for the efficient utilization of lignocellulosic biomass. Ionic liquids (ILs) have been reported to disrupt the bonds between these polymers and dissolve biomass at temperatures below 100 ˚C. Research through the years has shown that biomass pretreatment with IL brings out the selective dissolution of biomass polymers and …


Bundles And Hotspots Of Multiple Ecosystem Services For Optimized Land Management In Kentucky, United States, Yang Bai, Thomas O. Ochuodho, Jian Yang, Domena A. Agyeman Jan 2021

Bundles And Hotspots Of Multiple Ecosystem Services For Optimized Land Management In Kentucky, United States, Yang Bai, Thomas O. Ochuodho, Jian Yang, Domena A. Agyeman

Forestry and Natural Resources Faculty Publications

Ecosystem services are benefits that the natural environment provides to support human well-being. A thorough understanding and assessment of these services are critical to maintain ecosystem services flow through sustainable land management to optimize bundles of ecosystem services provision. Maximizing one particular ecosystem service may lead to reduction in another. Therefore, identifying ecosystem services tradeoffs and synergies is key in addressing this challenge. However, the identification of multiple ecosystem services tradeoffs and synergies is still limited. A previous study failed to effectively capture the spatial interaction among ecosystem services as it was limited by “space-to-time” substitution method used because of …


Formation Pathways In Brightest Cluster Galaxies: Measuring The Distribution Of Ages, Metallicities, And Hydrodynamics Of Stellar Populations, Priscilla E. Holguin West May 2020

Formation Pathways In Brightest Cluster Galaxies: Measuring The Distribution Of Ages, Metallicities, And Hydrodynamics Of Stellar Populations, Priscilla E. Holguin West

Physics

Brightest Cluster Galaxies (BCGs) are the most massive galaxies in the local universe and have had the full age of the universe to build. This makes their formation and evolution history particularly interesting as they offer a glimpse at potential evolutionary pathways for younger systems. We present the radial profile of ages, metallicities, and preliminary classification of companions to 23 BCGs observed using the SparsePak instrument on WIYN by running the STARLIGHT stellar population synthesis models. This analysis of the BCGs’ stellar populations is done by separating each BCG into different regions, and preliminary results of the stellar populations for …


Regression When There Are Two Covariates: Some Practical Reasons For Considering Quantile Grids, Rand Wilcox Feb 2020

Regression When There Are Two Covariates: Some Practical Reasons For Considering Quantile Grids, Rand Wilcox

Journal of Modern Applied Statistical Methods

When dealing with the association between some random variable and two covariates, extensive experience with smoothers indicates that often a linear model poorly reflects the nature of the association. A simple approach via quantile grids that reflects the nature of the association is given. The two main goals are to illustrate this approach can make a practical difference, and to describe R functions for applying it. Included are comments on dealing with more than two covariates.


Pantropical Climate Interactions, Wenju Cai, Lixin Wu, Matthieu Lengaigne, Tim Li, Shayne Mcgregor, Jong-Seong Kug, Jin-Yi Yu, Malte F. Stuecker, Agus Santoso, Xichen Li, Yoo-Geun Ham, Yoshimitsu Chikamoto, Benjamin Ng, Michael J. Mcphaden, Yan Du, Et Al. Mar 2019

Pantropical Climate Interactions, Wenju Cai, Lixin Wu, Matthieu Lengaigne, Tim Li, Shayne Mcgregor, Jong-Seong Kug, Jin-Yi Yu, Malte F. Stuecker, Agus Santoso, Xichen Li, Yoo-Geun Ham, Yoshimitsu Chikamoto, Benjamin Ng, Michael J. Mcphaden, Yan Du, Et Al.

Plants, Soils, and Climate Faculty Publications

The El Niño–Southern Oscillation (ENSO), which originates in the Pacific, is the strongest and most well-known mode of tropical climate variability. Its reach is global, and it can force climate variations of the tropical Atlantic and Indian Oceans by perturbing the global atmospheric circulation. Less appreciated is how the tropical Atlantic and Indian Oceans affect the Pacific. Especially noteworthy is the multidecadal Atlantic warming that began in the late 1990s, because recent research suggests that it has influenced Indo-Pacific climate, the character of the ENSO cycle, and the hiatus in global surface warming. Discovery of these pantropical interactions provides a …


Development Of Rules Of Attraction For Intercalated Guest Molecules Inside Of A Hydrogen Bonded Framework, Matthew Fischer Apr 2018

Development Of Rules Of Attraction For Intercalated Guest Molecules Inside Of A Hydrogen Bonded Framework, Matthew Fischer

Dissertations

Supramolecular chemistry has synthesized large and small molecules which host guest molecules for several decades. What started as a way to mimic of enzymes in nature, has exploded into a sea of materials such as porous coordination polymers, low-density metal-organic frameworks, inclusion compounds, and hydrogen bonded frameworks. We previously designed a layered framework consisting of a metal complex with coordinate covalent ligands. These ligands have peripheral carboxylic acid groups which hydrogen bond to organic pillars containing terminal amines. The layered structure is separated by these pillars, which are closed-packed, creating 1-dimensional channels able to co-crystallize molecules. There is interest in …


Harnessing Remote Sensing To Address Critical Science Questions On Ocean-Atmosphere Interactions, Griet Neukermans, Tristan Harmel, Martí Galí, Natalia Rudorff, Jacek Chowdhary, Oleg Dubovik, Chris Hostetler, Yongxiang Hu, Cédric Jamet, Kirk Knobelspiesse, Yoav Lehahn, Pavel Litvinov, Andrew M. Sayer, Brian Ward, Emmanuel Boss, Ilan Koren, Lisa A. Miller Jan 2018

Harnessing Remote Sensing To Address Critical Science Questions On Ocean-Atmosphere Interactions, Griet Neukermans, Tristan Harmel, Martí Galí, Natalia Rudorff, Jacek Chowdhary, Oleg Dubovik, Chris Hostetler, Yongxiang Hu, Cédric Jamet, Kirk Knobelspiesse, Yoav Lehahn, Pavel Litvinov, Andrew M. Sayer, Brian Ward, Emmanuel Boss, Ilan Koren, Lisa A. Miller

Marine Sciences Faculty Scholarship

Earth observing systems have proven to be a unique source of long-term synoptic information on numerous physical, chemical and biological parameters on a global scale. Merging this information for integrated studies that peruse key questions about the ocean-atmosphere interface is, however, very challenging. Such studies require interdisciplinary frameworks and novel insights into ways to address the problem. We present here a perspective review on how current and emerging remote sensing technologies could help address two scientific questions within the Surface Ocean-Lower Atmosphere Study (SOLAS) science plan: (1) to what extent does upper-ocean biology affect the composition and radiative properties of …


Cahost Facilitating The Johnson-Neyman Technique For Two-Way Interactions In Multiple Regression, Stephen W. Carden, Nicholas Holtzman, Michael Strube Jul 2017

Cahost Facilitating The Johnson-Neyman Technique For Two-Way Interactions In Multiple Regression, Stephen W. Carden, Nicholas Holtzman, Michael Strube

Department of Mathematical Sciences Faculty Publications

When using multiple regression, researchers frequently wish to explore how the relationship between two variables is moderated by another variable; this is termed an interaction. Historically, two approaches have been used to probe interactions: the pick-a-point approach and the Johnson-Neyman (JN) technique. The pick-a-point approach has limitations that can be avoided using the JN technique. Currently, the software available for implementing the JN technique and creating corresponding figures lacks several desirable features–most notably, ease of use and figure quality. To fill this gap in the literature, we offer a free Microsoft Excel 2013 workbook, CAHOST (a concatenation of the first …


Novel Spectroscopic Tools To Differentiate Drug-Dna Binding Interactions, Fadwa Dhafer Hamad Jun 2017

Novel Spectroscopic Tools To Differentiate Drug-Dna Binding Interactions, Fadwa Dhafer Hamad

Masters Theses

DNA-drug interactions play a major role in therapeutics, diagnostics, forensics and imaging. Drugs bind to DNA in several ways based on the mode of interaction and they alter protein-DNA interactions or breaks/cleaves DNA that can lead to the cure of the disease. The major goal of the research carried out in this thesis is to develop novel optical spectroscopic tools that can differentiate Drug-DNA binding interactions mode whether its intercalation or minor-groove binding. To achieve this goal, we developed two-photon absorption (2PA) cross-section based technique to differentiate between Drug-DNA binding modes. The investigations were carried out on two drug molecules, …


Spatially Offset Active Galactic Nuclei. Ii. Triggering In Galaxy Mergers, R Scott Barrows, Julia M. Comerford, Jenny E. Greene, David Pooley Apr 2017

Spatially Offset Active Galactic Nuclei. Ii. Triggering In Galaxy Mergers, R Scott Barrows, Julia M. Comerford, Jenny E. Greene, David Pooley

Physics and Astronomy Faculty Research

Galaxy mergers are likely to play a role in triggering active galactic nuclei (AGNs), but the conditions under which this process occurs are poorly understood. In Paper I, we constructed a sample of spatially offset X-ray AGNs that represent galaxy mergers hosting a single AGN. In this paper, we use our offset AGN sample to constrain the parameters that affect AGN observability in galaxy mergers. We also construct dual-AGN samples with similar selection properties for comparison. We find that the offset AGN fraction shows no evidence for a dependence on AGN luminosity, while the dual-AGN fractions show stronger evidence for …


Transcriptional And Antagonistic Responses Of Biocontrol Strain Lysobacter Enzymogenes Oh11 To The Plant Pathogenic Oomycete Pythium Aphanidermatum, Yangyang Zhao, Guoliang Qian, Yuan Chen, Liangcheng Du, Fengquan Liu Jan 2017

Transcriptional And Antagonistic Responses Of Biocontrol Strain Lysobacter Enzymogenes Oh11 To The Plant Pathogenic Oomycete Pythium Aphanidermatum, Yangyang Zhao, Guoliang Qian, Yuan Chen, Liangcheng Du, Fengquan Liu

Chemistry Department: Faculty Publications

Lysobacter enzymogenes is a ubiquitous, beneficial, plant-associated bacterium emerging as a novel biological control agent. It has the potential to become a new source of antimicrobial secondary metabolites such as the Heat-Stable Antifungal Factor (HSAF), which is a broad-spectrum antimycotic with a novel mode of action. However, very little information about how L. enzymogenes detects and responds to fungi or oomycetes has been reported. An in vitro confrontation bioassay between the pathogenic oomycete Pythium aphanidermatum and the biocontrol bacterial strain L. enzymogenes OH11 was used to analyze the transcriptional changes in the bacteria that were induced by the oomycetes. Analysis …


Determination Of The Polarization Observables Cx, Cz, And Py For Final-State Interactions In The Reaction −!D ! K+−!N, Tongtong Cao Jun 2016

Determination Of The Polarization Observables Cx, Cz, And Py For Final-State Interactions In The Reaction −!D ! K+−!N, Tongtong Cao

Theses and Dissertations

The hyperon-nucleon (YN) interaction plays a key role in hypernuclei and strange nuclear matter and is an important part of the baryon-baryon interaction. While considerable progress has been made in the understanding of the nucleon-nucleon (NN) interaction, the YN interaction is less known. Some parameters of the YN potential can be obtained from the NN potential by using SU(3) symmetry. However, due to broken SU(3) there are parameters, which must be obtained from fits to experimental data. High-statistics data on exclusive photoproduction off the deuteron initiated with highly-polarized photons offer a unique opportunity to extract a large sample of polarization …


A Comparison Of X-Ray And Optical Emission In Cassiopeia A, Daniel J. Patnaude, Robert A. Fesen Mar 2014

A Comparison Of X-Ray And Optical Emission In Cassiopeia A, Daniel J. Patnaude, Robert A. Fesen

Dartmouth Scholarship

Broadband optical and narrowband Si XIII X-ray images of the young Galactic supernova remnant Cassiopeia A (Cas A) obtained over several decades are used to investigate spatial and temporal emission correlations on both large and small angular scales. The data examined consist of optical and near infrared ground-based and Hubble Space Telescope images taken between 1951 and 2011, and X-ray images from Einstein, ROSAT, and Chandra taken between 1979 and 2013. We find weak spatial correlations between the remnant’s X-ray and optical emission features on large scales, but several cases of good optical/X-ray correlations on small scales for features which …


Optical Switching Of Protein Interactions On Photosensitive-Electroactive Polymers Measured By Atomic Force Microscopy, Amy Gelmi, Michele Zanoni, Michael J. Higgins, Sanjeev Gambhir, David L. Officer, Dermot Diamond, Gordon G. Wallace Mar 2014

Optical Switching Of Protein Interactions On Photosensitive-Electroactive Polymers Measured By Atomic Force Microscopy, Amy Gelmi, Michele Zanoni, Michael J. Higgins, Sanjeev Gambhir, David L. Officer, Dermot Diamond, Gordon G. Wallace

Gordon Wallace

The ability to switch the physico-chemical properties of conducting polymers opens up new possibilities for a range of applications. Appropriately functionalised materials can provide routes to multi-modal switching, for example, in response to light and/or electrochemical stimuli. This capability is important in the field of bionics wherein remote and temporal control of the properties of materials is becoming attractive. The ability to actuate a film via photonic stimuli is particularly interesting as it facilitates the modulation of interactions between host binding sites and potential guest molecules. In this work, we studied two different poly-terthiophenes: one was functionalised with a spiropyran …


Strengthening Interactions Between Statisticians And Collaborators: Objectives And Sample Sizes, Emily Van Meter, Richard Charnigo Feb 2014

Strengthening Interactions Between Statisticians And Collaborators: Objectives And Sample Sizes, Emily Van Meter, Richard Charnigo

Biostatistics Faculty Publications

No abstract provided.


Parental Environments And Interactions With Conspecifics Alter Salinity Tolerance Of Offspring In The Annual Medicago Truncatula, Brenna M. Castro, Ken S. Moriuchi, Maren L. Friesen, Mounawer Badri, Sergey V. Nuzhdin, Sharon Y. Strauss, Douglas R. Cook, Eric Von Wettberg Sep 2013

Parental Environments And Interactions With Conspecifics Alter Salinity Tolerance Of Offspring In The Annual Medicago Truncatula, Brenna M. Castro, Ken S. Moriuchi, Maren L. Friesen, Mounawer Badri, Sergey V. Nuzhdin, Sharon Y. Strauss, Douglas R. Cook, Eric Von Wettberg

College of Agriculture and Life Sciences Faculty Publications

Summary: Based on expectations of the stress-gradient hypothesis for conspecific interactions, stress-sensitive genotypes may be able to persist in stressful environments when positive interactions between individuals occur under stressful environments. Additionally, we test how parental environmental effects alter responses to stress and outcomes of conspecific interactions in stress. While the stress-gradient hypothesis focuses on plant growth, earlier flowering may provide stress avoidance in short-lived organisms. We studied responses to soil salinity and conspecific neighbour using genotypes of Medicago truncatula (Fabaceae) originating from saline or non-saline environments, utilizing seeds from parental plants grown in saline or non-saline environments. During the early …


Chemical Reactivity Worksheet, Noaa, Jeffrey H. Glans Jul 2013

Chemical Reactivity Worksheet, Noaa, Jeffrey H. Glans

Jeffrey H. Glans

Website overview by Jeffrey H. Glans. NOAA. Office of Response and Restoration. "Chemical Reactivity Worksheet, NOAA." http://response.restoration.noaa.gov/crw


Characterising The Interactions Between Unicast And Broadcast In Ieee 802.11 Ad Hoc Networks, Jerry Chun-Ping Wang, D. Franklin, Mehran Abolhasan, Farzad Safaei Jun 2013

Characterising The Interactions Between Unicast And Broadcast In Ieee 802.11 Ad Hoc Networks, Jerry Chun-Ping Wang, D. Franklin, Mehran Abolhasan, Farzad Safaei

Professor Farzad Safaei

This paper investigates the relative performance of unicast and broadcast traffic traversing a one-hop ad hoc network utilising the 802.11 DCF. An extended Markov model has been developed and validated through computer simulation, which successfully predicts the respective performance of unicast and broadcast in a variety of mixed traffic scenarios. Under heavy network traffic conditions, a significant divergence is seen to develop between the performance of the two traffic classes - in particular, when network becomes saturated, unicast traffic is effectively given higher precedence over broadcast. As a result, the network becomes dominated by unicast frames, leading to poor rates …


Late Quaternary Aeolian And Fluvial Interactions On The Cooper Creek Fan And The Association Between Linear And Source-Bordering Dunes, Strzelecki Desert, Australia, Timothy Cohen, Gerald Nanson, Joshua Larsen, B. Jones, David Price, Maria Coleman, Tim Pietsch Jun 2013

Late Quaternary Aeolian And Fluvial Interactions On The Cooper Creek Fan And The Association Between Linear And Source-Bordering Dunes, Strzelecki Desert, Australia, Timothy Cohen, Gerald Nanson, Joshua Larsen, B. Jones, David Price, Maria Coleman, Tim Pietsch

B. G. Jones

The Innamincka Dome and associated low-gradient fan in the Strzelecki Desert is the product of Cenozoic crustal warping that has aided formation of an extensive array of palaeochannels, source-bordering transverse dunes and superimposed linear dunes. These dunes have impeded the course of Cooper Creek and provided a repository of evidence for Quaternary climate change as well as the interactive processes between transverse and linear dune formation. At Turra, Gidgealpa and sites nearby are extensive fluvial and aeolian sand bodies that date from marine isotope stages (MIS) 8-3 and the Last Glacial Maximum (LGM) and are now surrounded or buried by …


Varying Index Coefficient Models, Shujie Ma, Peter Xuekun Song May 2013

Varying Index Coefficient Models, Shujie Ma, Peter Xuekun Song

The University of Michigan Department of Biostatistics Working Paper Series

It has been a long history of utilizing interactions in regression analysis to investigate interactive effects of covariates on response variables. In this paper we aim to address two kinds of new challenges resulted from the inclusion of such high-order effects in the regression model for complex data. The first kind arises from a situation where interaction effects of individual covariates are weak but those of combined covariates are strong, and the other kind pertains to the presence of nonlinear interactive effects. Generalizing the single index coefficient regression model (Xia and Li, 1999), we propose a new class of semiparametric …


Interactions Between The Chloride Anion And Aromatic Molecules: Infrared Spectra Of The Cl-_C6h5ch3, Cl-_C6h5nh2 And Cl-_C6h5oh Complexes, Corinna Emmeluth, Berwyck L. J Poad, Christopher D. Thompson, Evan J. Bieske May 2013

Interactions Between The Chloride Anion And Aromatic Molecules: Infrared Spectra Of The Cl-_C6h5ch3, Cl-_C6h5nh2 And Cl-_C6h5oh Complexes, Corinna Emmeluth, Berwyck L. J Poad, Christopher D. Thompson, Evan J. Bieske

Berwyck L. J. Poad

The Cl-−C6H5CH3·Ar, Cl-−C6H5NH2·Ar, and Cl-−C6H5OH·Ar anion complexes are investigated using infrared photodissociation spectroscopy and ab initio calculations at the MP2/aug-cc-pVDZ level. The results indicate that for Cl-−C6H5NH2 and Cl-−C6H5OH, the Cl- anion is attached to the substituent group by a single near-linear hydrogen bond. For Cl-−C6H5CH3, the Cl- is attached to an ortho-hydrogen atom on the aromatic ring and to a hydrogen atom on the methyl group by a weaker hydrogen bond. The principal spectroscopic consequence of the hydrogen-bonding interaction in the three complexes is a red-shift and intensity increase for the CH, NH, and OH stretching modes. Complexities in …


Single-Grain Osl Chronologies For Middle Palaeolithic Deposits At El Mnasra And El Harhoura 2, Morocco: Implications For Late Pleistocene Human-Environment Interactions Along The Atlantic Coast Of Northwest Africa, Zenobia Jacobs, Richard Roberts, Roland Nespoulet, M El Hajraoui, Andre Debenath Mar 2013

Single-Grain Osl Chronologies For Middle Palaeolithic Deposits At El Mnasra And El Harhoura 2, Morocco: Implications For Late Pleistocene Human-Environment Interactions Along The Atlantic Coast Of Northwest Africa, Zenobia Jacobs, Richard Roberts, Roland Nespoulet, M El Hajraoui, Andre Debenath

Richard G Roberts

Optically stimulated luminescence (OSL) measurements were made on individual, sand-sized grains of quartz from Middle Palaeolithic deposits at two cave sites (El Harhoura 2 and El Mnasra) on the Atlantic coast of Morocco. We were able to calculate OSL ages for 32 of the 33 samples collected from the Middle Palaeolithic deposits, including the earliest and latest Aterian levels at both sites. These ages reveal periods of occupation between about 110 and 95 ka (thousands of years ago), and at ~75 ka. A late Middle Palaeolithic occupation of El Harhoura 2 is also recorded at ~55 ka. Our single-grain OSL …


Electric Multipole Interactions In An Extended Beg Model, Teresa Burns, Jr Dennison Mar 2013

Electric Multipole Interactions In An Extended Beg Model, Teresa Burns, Jr Dennison

Posters

General 2D dielectric phase diagrams and phase transitions for multipolar molecules adsorbed to a square ionic crystal are presented. The adsorbed molecules are modeled using a dilute spin-one Ising model in the Blume-Emery-Griffiths formalism, using a mean-field approximation. Physical constants such as the electricmultipole moments and binding energies are used to uniquely determine the interaction parameters over the full range of physically-relevant values. We find that temperature- and coverage-dependent antiferroelectric to ferroelectric, coverage-dependent ferroelectric up to ferroelectric down, reentrant ferroelectric to ferrielectric, and order-disorder dipole phase transitions can occur. The results are presented as a quasi-continuous set of phase diagrams. …


Electronic Interactions Within Composites Of Polyanilines Formed Under Acidic And Alkaline Conditions. Conductivity, Esr, Raman, Uv-Vis And Fluorescence Studies, L Dennany, P C. Innis, S T. Mcgovern, Gordon G. Wallace, Robert J. Forster Mar 2013

Electronic Interactions Within Composites Of Polyanilines Formed Under Acidic And Alkaline Conditions. Conductivity, Esr, Raman, Uv-Vis And Fluorescence Studies, L Dennany, P C. Innis, S T. Mcgovern, Gordon G. Wallace, Robert J. Forster

Gordon Wallace

The properties of two forms of polyaniline (PAni) synthesised under acidic and basic conditions have been investigated both individually and as combined complexes. The PAni polymerised within alkaline media was redox inactive and non-conducting while the PAni emeraldine salt (ES) was electroactive and conducting. Raman, electron spin resonance, UV-Vis and fluorescence spectroscopies were used to monitor the changes in electronic properties of these conducting polymer composites. Solution cast films of alkaline synthesised (A-PAni) with the PAni ES resulted in an increase in the high spin polaron population suggesting that it acts as a pseudodopant. The ability of the A-PAni to …


The Properties Of Post-Starburst Quasars Based On Optical Spectroscopy, Sabrina L. Cales, Michael S. Brotherton, Zhaohui Shang, Jessie C. Runnoe, Michael A. Dipompeo, Vardha Nicola Bennert, Gabriela Canalizo, Kyle D. Hiner, R. Stoll, Rajib Ganguly, Aleksandar Diamond-Stanic Jan 2013

The Properties Of Post-Starburst Quasars Based On Optical Spectroscopy, Sabrina L. Cales, Michael S. Brotherton, Zhaohui Shang, Jessie C. Runnoe, Michael A. Dipompeo, Vardha Nicola Bennert, Gabriela Canalizo, Kyle D. Hiner, R. Stoll, Rajib Ganguly, Aleksandar Diamond-Stanic

Physics

We present optical spectroscopy of a sample of 38 post-starburst quasars (PSQs) at z ~ 0.3, 29 of which have morphological classifications based on Hubble Space Telescope imaging. These broad-lined active galactic nuclei (AGNs) possess the spectral signatures of massive intermediate-aged stellar populations, making them potentially useful for studying connections between nuclear activity and host galaxy evolution. We model the spectra in order to determine the ages and masses of the host stellar populations, and the black hole masses and Eddington fractions of the AGNs. Our model components include an instantaneous starburst, a power law, and emission lines. We find …


Optical Switching Of Protein Interactions On Photosensitive-Electroactive Polymers Measured By Atomic Force Microscopy, Amy Gelmi, Michele Zanoni, Michael J. Higgins, Sanjeev Gambhir, David L. Officer, Dermot Diamond, Gordon G. Wallace Jan 2013

Optical Switching Of Protein Interactions On Photosensitive-Electroactive Polymers Measured By Atomic Force Microscopy, Amy Gelmi, Michele Zanoni, Michael J. Higgins, Sanjeev Gambhir, David L. Officer, Dermot Diamond, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

The ability to switch the physico-chemical properties of conducting polymers opens up new possibilities for a range of applications. Appropriately functionalised materials can provide routes to multi-modal switching, for example, in response to light and/or electrochemical stimuli. This capability is important in the field of bionics wherein remote and temporal control of the properties of materials is becoming attractive. The ability to actuate a film via photonic stimuli is particularly interesting as it facilitates the modulation of interactions between host binding sites and potential guest molecules. In this work, we studied two different poly-terthiophenes: one was functionalised with a spiropyran …