Physical Sciences and Mathematics Commons^™

Aquifers Of Nebraska Ii: The Niobrara Aquifer, Dana Divine, Robert Matthew Joeckel, Sue Olafsen Lackey

Conservation and Survey Division

The marine shale, chalk, marl, and chalky limestone of the Niobrara Formation directly underlie Quaternary sediments in 23 counties from south-central to northeastern Nebraska. Nevertheless, the formation serves as an aquifer only in and around Cedar, Madison, and Nuckolls counties. Niobrara aquifer wells mostly supply irrigation, domestic, and livestock needs. Two hundred of the approximately 230 active registered wells in Nebraska that are screened entirely in the Niobrara aquifer are in Cedar County and environs. About another 200 wells in this area are screened in both the Niobrara aquifer and overlying Quaternary sediments. Wells screened entirely in the Niobrara aquifer …

Shower Atomization, Chirag Ayappa Ravishankar,

Masters Theses & Specialist Projects

The research will help to design a shower for Dr. Chelson’s shelter, which can control the water flow, pressure and duration of the shower, which optimizes the utilization of water. The showers could be used in drought-hit areas where water is very scarce, as daily sanitation needs are necessary to keep a person safe and healthy without wasting water. The report from, World Health Organization shows that showers consume the most water. A timed shower could help resolve this issue through eliminating the wastage. Eco-friendly environmentalists may also be attracted to the showers, as their main purposes are to save …

Characterization Of Γ-Butyrolactone Rings: A Computational And Toxicological Study, Donald C. Kidd

Masters Theses

Given the declining state of the natural environment, identifying green methodologies in synthetic chemistry is becoming paramount. An under explored area of green chemistry, is the use of catalytic systems in green solvents. One interesting concept in green chemistry is the use of N-Heterocyclic Carbenes (NHCs) as organocatalysts.

Thiamine or vitamin B1 was one of the first NHCs recognized. Thiamine is required for carbohydrate metabolism and helps the cell produce adenosine triphosphate (ATP). Over the last 20 years NHCs have been found to be efficient catalysts in carbon-carbon bond forming reactions.

But to date, little research has been done exploring …

Water-Energy Sector Collaboration In The United States: Benefits, Barriers, And Climate-Change Implications, Cassandra J. Osterhoudt

International Development, Community and Environment (IDCE)

The purpose of this report is to examine the impact of the water-energy nexus in the United States, and identify opportunities for increased collaboration between water and energy utilities. Through reviewing the regulatory history of both sectors, I explore how regulations on utilities align with the Porter Hypothesis, and the impacts the water-energy nexus will have moving forward, including under climate-change scenarios. The extent of collaboration between sectors has been relatively limited to states with progressive energy and water efficiency policies. This report identifies existing barriers and benefits to collaboration, and utilizes two case studies; California and Massachusetts. Results are …

Operationalizing Resilience In The Face Of Water Conflict: Linking Social And Ecological Systems, Stephen Andrew Mcguire

Theses and Dissertations

This dissertation investigates the possibility of linked surface-groundwater governance through the application of a social-ecological systems lens to the Lake Beulah Conflict over a high capacity well in Walworth County, Wisconsin. Potential adverse impacts the loss of Ca2+ rich groundwater would have on Lake Beulah’s water quality was modeled through an ex-ante assessment method using the U.S. Army Corps of Engineers lake and reservoir model BATHTUB, the U.S. Geological Survey geochemical model PHREEQC and a Ca2+ mass balance equation. The utility of this information in a management setting was also analyzed. Reduction of Ca2+ through groundwater withdrawal revealed a eutrophication …

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Volatiles In Subglacially Erupted Basaltic Glasses And Their Use In Reconstructing Paleo-Ice Thicknesses, Carver Lee

Masters Theses

Volatile concentrations in basaltic tuyas, edifices that form during a subglacial eruption and remain once the ice sheet has retreated, have been used to calculate the thickness of the overlying ice sheet at the onset of the eruption (Tuffen, 2010). However, subglacial eruptions are complex events and this technique does not always provide a clear answer (Schopka et al., 2006; Edwards et al., 2009). The purpose of this research is to evaluate this technique and investigate constraints on the quality of data collected by attempting to calculate the minimum ice thickness under which Hlöðufell, a tuya in south-central Iceland, erupted. …

Results Of Test-Hole Drilling For Observation Well Planning In The Upper Loup Natural Resources District, Fall 2016, Douglas Hallum, Sue Olafsen Lackey

Conservation and Survey Division

The High Plains Aquifer underlies much of Nebraska (Figure 1). It is the primary source of groundwater within the Upper Loup Natural Resources District (ULNRD) of central Nebraska (Figure 2). Water derived from the aquifer is an important natural resource for the area and supplies water for recreation, wildlife and agriculture, as well as domestic, municipal, and industrial uses. A general lack of water level observations in the region (Figure 3), recently developed groundwater irrigated acres along the upper Calamus River (Figure 4), falling spring water levels measured in existing irrigation wells (Figure 5), and a stable to falling stream …

Fy 2017 Umass Amherst Water & Steam Data By Building, Ezra Small

Campus Data

Each year, UMass Amherst Utilities publishes this spreadsheet which has the monthly and annual building water and steam consumption of each metered building on campus.

Aquacrop-Os: An Open Source Version Of Fao’S Crop Water Productivity Model, T. Foster, N. Brozovic, A. P. Butler, C. M. U. Neale, D. Raes, P. Steduto, E. Fereres, T. C. Hsiao

Daugherty Water for Food Global Institute: Faculty Publications

Crop simulation models are valuable tools for quantifying crop yield response to water, and for devising strategies to improve agricultural water management. However, applicability of the majority of crop models is limited greatly by a failure to provide open-access to model source code. In this study, we present an open-source version of the FAO AquaCrop model, which simulates efficiently water-limited crop production across diverse environmental and agronomic conditions. Our model, called AquaCrop-OpenSource (AquaCrop-OS), can be run in multiple programming languages and operating systems. Support for parallel execution reduces significantly simulation times when applying the model in large geospatial frameworks, for …

A Demonstration Study Of Drainage Water Management In Eastern South Dakota, Ashik Sahani

Electronic Theses and Dissertations

Subsurface drainage is a common water management practice for improving crop production in poorly drained soils; however, the practice is associated with several environmental concerns such as nutrient losses to downstream surface waters. These environmental concerns from subsurface drainage have prompted interest in drainage water management strategies such as controlled drainage. This study assessed the agronomic and environmental impacts of drainage water management in eastern South Dakota by using two demonstration plots for controlled and conventional drainage. Drain flow, nitrate and dissolved phosphorous concentration in drain water, shallow groundwater, crop yield, residual soil nitrate, soil moisture and temperature, soil penetration …

Hyperspectral Signatures And Worldview-3 Imagery Of Indian River Lagoon And Banana River Estuarine Water And Bottom Types, Charles R. Bostater Jr., Taylor S. Oney, Tyler Rotkiske, Samin Aziz, Charles Morrisette, Kelby Callahan, Devin Mcallister

Ocean Engineering and Marine Sciences Faculty Publications

Hyperspectral signatures and imagery collected during the spring and summer of 2017 and 2016 are presented. Ground sampling distances (GSD) and pixel sizes were sampled from just over a meter to less than 4.0 mm. A pushbroom hyperspectral imager was used to calculate bidirectional reflectance factor (BRF) signatures. Hyperspectral signatures of different water types and bottom habitats such as submerged seagrasses, drift algae and algal bloom waters were scanned using a high spectral and digital resolution solid state spectrograph. WorldView-3 satellite imagery with minimal water wave sun glint effects was used to demonstrate the ability to detect bottom features using …

Effect Of Storage Environment On Hydrogen Generation By The Reaction Of Al With Water, Yin-Qiang Wang, Wei-Zhuo Gai, Xia-Yu Zhang, Hong-Yi Pan, Zhenxiang Cheng, Pingguang Xu, Zhen-Yan Deng

Australian Institute for Innovative Materials - Papers

Al powder was stored in saturated water vapor, oxygen, nitrogen and drying air separately for a time period of up to six months, the degradation behavior of Al activity was characterized by the reaction of Al with water. It was found that water vapor decreased the induction time for the beginning of Al-water reaction and reduced the total hydrogen generation per unit weight of Al, while oxygen increased the induction time and retarded the Al-water reaction. In contrast, the effect of nitrogen and drying air on Al activity was weak. The mechanism analyses indicated that water vapor promoted the hydration …

The Water-Electricity Nexus In California: Drought-Induced Risk To Thermal Electricity Generation, Timothy S. Hyles

Cal Poly Humboldt theses and projects

Investigating the possibility that drought might limit the water supply needed for thermal electricity generation in California, power plant water consumption data was compared to urban and agricultural consumptive demands to identify areas where power plants might contribute to regional water stress. To identify areas where power plants might be impacted by water stress, regional power plant, urban, and agricultural water demands were also compared to the available water supply. A list of power plants that would contribute most to regional water scarcity (individually and in aggregate) was highlighted, based on the plant’s water consumption volume, water-intensity, and water source. …

Climate Change Adaptation For Southern California Groundwater Managers: A Case Study Of The Six Basins Aquifer, Frank Lyles

Pomona Senior Theses

Groundwater has been very important to the economic development of Southern California, and will continue to be a crucial resource in the 21st century. However, Climate Change threatens to disrupt many of the physical and economic processes that control the flow of water in and out of aquifers. One groundwater manager, the Six Basins Watermaster in eastern Los Angeles and western San Bernardino Counties, has developed a long-term planning document called the Strategic Plan that mostly fails to address the implications of Climate Change, especially for local water supplies. This thesis presents an in-depth analysis of the Six Basin Watermaster’s …

Spectrophotometric Detection Of Rhodamine B In Tap Water, Lipstick, Rouge, And Nail Polish Samples After Supramolecular Solvent Microextraction, Nebi̇ye Özkantar, Mustafa Soylak, Mustafa Tüzen

Turkish Journal of Chemistry

A simple and sensitive supramolecular solvent-based dispersive liquid--liquid microextraction method was described for the separation/preconcentration and spectrophotometric detection of rhodamine B. The microextraction method, which was realized at ambient temperature for the detection of rhodamine B, was carried out by using supramolecular solvents such as tetrahydrofuran and decanoic acid. The method was based on analyses of rhodamine B by using UV-Vis spectrophotometry at 558 nm. The influences of some parameters such as pH, sample volume, eluent solutions, centrifugation time, and ultrasonic bath time were optimized. The effects of various matrix ions were also investigated. Moreover, the limit of detection and …

The Potential For Phosphorus Release From Floodplain Soils: Temporal Variability And Management Strategies, Megan Amanda Reavis

Graduate Theses and Dissertations

Soils may contain large amounts of legacy phosphorus (P) due to past application of excess fertilizers, releasing P during runoff and flood events. As the level of P in soils increases, the release of P from the soils increases, but the temporal fluctuations of this release are not well known. Experiments were conducted to examine 1) the variability of soluble reactive P (SRP) release from the soil throughout a year and 2) the effect of repeated flooding and drying cycles on release rates. Soil cores were collected 7 times throughout a year from 2 sites within the Watershed Research and …

Antimicrobial Activity Of Fractionated Borohydride-Capped And Electrochemical Colloidal Silver, Marjorie M. Markopoulos

Browse all Theses and Dissertations

Silver nanoparticles (AgNPs) and ionic silver (Ag+) are known to be broad-spectrum antimicrobial agents. Recent studies show these agents may be an alternative to the most widely used drinking water disinfectant, chlorine. Chlorine is a toxic industrial chemical with a lethal concentration of 430 ppm after 30 minutes. Additionally, chlorine can react with naturally occurring materials to produce a number of disinfection byproducts such as chloroform and trihalomethanes. Some of these byproducts pose cancer risks in addition to other negative impacts to human health. These would be eliminated with the use of Ag+ or AgNPs. The main goal of this …