Physical Sciences and Mathematics Commons^™

A Study Of How Precursor Key Concepts For Organic Chemistry Success Are Understood By General Chemistry Students, Patrick Gerard Meyer

Dissertations

This study examines college student understanding of key concepts that will support future organic chemistry success as determined by university instructors. During four one-hour individual interviews the sixteen subjects attempted to solve general chemistry problems. A think-aloud protocol was used along with a whiteboard where the students could draw and illustrate their ideas. The protocols for the interviews were adapted from the Covalent Structure and Bonding two-tiered multiple choice diagnostic instrument (Peterson, Treagust, & Garnett, 1989) and augmented by the Geometry and Polarity of Moleculessingle-tiered multiple choice instrument (Furió & Calatayud, 1996). The interviews were videotaped, transcribed, and coded …

Online Support For Multivariate Integration, Shujun Li

Dissertations

In this dissertation, we present an online problem solving environment for multivariate numerical integration. To build an environment for users with various backgrounds, we address issues of Web interface support for end-users, remote application programming interfaces for distributed system programmers, visualization of multivariate integrand functions for problem analysis, and highly efficient integration methods. Compared to previous implementations, our new load balancing schemes increase the scalability of parallel integration and hence are suitable for large scale computations. A parallel integration service, called PI service, was implemented based on Web services technologies to support both remote integration and remote visualization. The multivariate …

Photoexcitation And Photoionization Of The Argon Atom And The Hydrogen Bromide Molecule, Ximao Feng

Dissertations

Interaction between synchrotron radiation with inner-shell electrons is a fundamental method to study the structure and dynamics of atoms and molecules. This thesis, under the guidance of Dr. Nora Berrah, concentrates on the study of the interaction between soft x-ray photons with Ar atoms and HBr moleculeswith time-of-flight (TOF) electron spectrometers and two-dimensional photoelectron spectroscopy (2DPES). Both of the experiments were performed on theAtomic, Molecular and Optical Physics undulator beamline at the Advanced Light Source at Lawrence Berkeley National Laboratory.

The argon study focused on photoelectron recapture when the 2p electrons are ionized just above the thresholds of the two …

An Automata-Based Automatic Verification Environment, Yi Meng

Dissertations

With the continuing growth of computer systems including safety-critical computer control systems, the need for reliable tools to help construct, analyze, and verify such systems also continues to grow. The basic motivation of this work is to build such a formal verification environment for computer-based systems.

An example of such a tool is the Design Oriented Verification and Evaluation (DOVE) created by Australian Defense Science and Technology Organization. One of the advantages of DOVE is that it combines ease of use provided by a graphical user interface for describing specifications in the form of extended state machines with the rigor …

Development Of Micro-Scale And Automated Membrane Extraction Systems For Water Analysis, Xiaoyan Wang

Dissertations

Monitoring of trace level contaminants in water involves the extraction and enrichment of analytes. Over the years several techniques have been developed for this purpose. Currently there is an urgent need for the development of micro-scale extraction techniques that can lead to simple, fast trace analysis. Automated instruments that can be used for continuous, on-line analysis are also important. Membrane extraction can address both these needs, because it can be carried out in a continuous fashion and can also be miniaturized. This research addresses these two aspects of membrane extraction for the next generation of sample preparation.

Micro-Scale Membrane Extraction: …

Effect Of Heavy Metals On Salt March Biota, Kallaya Suntornvongsagul

Dissertations

Environmental restoration of disturbed, degraded and potentially contaminated wetland sites aims for the persistent and sustainable re-establishment of biological communities and important wetland functions. An ecologically informed restoration strategy presupposes some understanding of these system processes, but also of potential impacts on contaminants in the environment for risk assessment, long-term management, and potential cost-effective mitigative measures. In this study, potential effects of moderate heavy metal contamination in sediments of the urban salt marsh Harrier Meadow, NJ, were evaluated on growth performance of the common salt marsh plant S. patens and associated arbuscular mycorrhizal fungi (AMF) colonizing its roots. Growth performance …

Functionalization, Growth And Applications Of Single Wall Carbon Nanotubes, Yubing Wang

Dissertations

Because of their remarkable structural, mechanical and electrical properties, carbon nanotubes, and especially single wall carbon nanotubes (SWNTs), represent one of the most widely investigated materials today in the emerging field of nanotechnology. The development of oriented growth of SWNTs critical for applications, novel approaches for the creation of functional SWNTs, and applications of both as-prepared and chemically functionalized SWNTs for electrochemically-induced hydrogen storage, in-situ formation of new polymer and ceramic nanocomposites with SWNTs, and the fabrication and study for the first time, to the best of our knowledge, of a SWNT-based biofuel cell and self-powered biosensor, are the thrusts …

A Bayesian Approach To Wireless Location Problems, Ivan Zorych

Dissertations

Several approaches for indoor location estimation in wireless networks are proposed. We explore non-hierarchical and hierarchical Bayesian graphical models that use prior knowledge about physics of signal propagation, as well as different modifications of Bayesian bivariate spline models. The hierarchical Bayesian model that incorporates information about locations of access points achieves accuracy that is similar to other published models and algorithms, but by using prior knowledge, this model drastically reduces the requirement for training data when compared to existing approaches. Proposed Bayesian bivariate spline models for location surpass predictive accuracy of existing methods. It has been shown that different versions …

Studies Of Solar White-Light Flares And Small-Scale Magnetic Structures Observed In The Near Infrared, Yan Xu

Dissertations

Using the most advanced infrared imaging technology as developed by NJIT, detailed study of solar white-light flares and small magnetic structures, such as faculae and pores, are presented in this dissertation. The investigations focus on near-infrared observations at 1.56 μm, which are good proxy of the deepest layer of the solar photosphere.

I made fundamental contributions in two areas of near infrared (NIR) solar physics: (1) the first detection and understanding of white-light flares in the NIR and (2) clearly demonstrated non-existence of "dark faculae". Several high-resolution observations have been carried out at BBSO and National Solar Observatory/Sacramento Peak. The …

Supporting Individual Time Management Through The Capture And Display Of Temporal Structures, Dezhi Wu

Dissertations

This thesis work examines the time management strategies of individuals in an academic institution and gathers information on the complex temporal structures they experience and manage. Its focus is on understanding the relationship between the quality of individual time management and an individual's understanding and use of temporal structures. This work consists of an exploratory field study to gather data on how people use temporal structures with electronic tools. It is followed by a survey that is given to a larger group of respondents in the same subject population examined with the field study. The survey examines the hypotheses developed …

Rna Structure Analysis : Algorithms And Applications, Jianghui Liu

Dissertations

In this doctoral thesis, efficient algorithms for aligning RNA secondary structures and mining unknown RNA motifs are presented. As the major contribution, a structure alignment algorithm, which combines both primary and secondary structure information, can find the optimal alignment between two given structures where one of them could be either a pattern structure of a known motif or a real query structure and the other be a subject structure.

Motivated by widely used algorithms for RNA folding, the proposed algorithm decomposes an RNA secondary structure into a set of atomic structural components that can be further organized in a tree …

Electronic Capture And Analysis Of Fraudulent Behavioral Patterns : An Application To Identity Fraud, Benjamin Ngugi

Dissertations

The objective of this research was to find a transparent and secure solution for mitigating identity fraud and to find the critical factors that determine the solution's acceptance. Identity fraud is identified as a key problem with total losses exceeding fifty two billion dollars (Javelin Strategy and Research 2005). A common denominator in most identity-fraud-prone transactions is the use of a keypad; hence this research focuses on keypad data entry and proposes a biometric solution. Three studies develop, evaluate and investigate the feasibility of this solution.

The first study was done in three stages. Stage one investigated the technical feasibility …

Influence Of Uncorrelated Defects On The Vortex Phase Diagram In Yba2Cu3O7-6 Superconducting System, Lucian M. Undreiu

Dissertations

The goal of our work is to gain more insight into the vortex dynamics in YBa₂Cu₃0_7-8 single crystals with point defects induced by 9MeV proton irradiation. The position of the critical points from the first order melting transition line can be shifted in a controlled manner with the induced disorder. In order to accomplish a comparative study, different crystals and irradiation doses were used. The results were correlated using both electrical transport and ac specific heat measurements. Special attention was given to investigating the nature of the vortex state below the lower critical point o …

Single-Electron Capture Processes In Slow Collisions Of He^2+ Ions With Molecular Targets, Osama Abu-Haija

Dissertations

Translational energy-gain spectroscopy (TES) has been used to investigate state-selective dissociative and non-dissociative single-electron capture processes in low-energy collisions of He²⁺ ions with O₂ , H₂ O, CO₂ , N₂ , and NH3 at impact energies between 100 eV and 1600 eV. The measured energy spectra for theHe²⁺ -O₂ and H₂ O collision systems show that the dominant exit channel is due to dissociative transfer ionization (DTI), single-electron captureaccompanied by ionization of the molecular target-ion, at the lowest collision energies. As the impact energy is increased non-dissociative single-electron capture (SEC) into the …

Synthesis And Spectroscopic Characterization Of Manganese Doped Zinc Sulfide Quantum Dot Nanocrystals, Pedro A. Gonzalez Beerman

Dissertations

Zinc sulphide quantum dots were synthesized in aqueous media using sodium polyphosphate as the stabilizer. The nanoparticles were 2.5 ± 0.5 nm and 5.0 ± 0.5 nm diameter depending on the synthetic procedure employed and the amount of Mn doped varied from 0.003 to 0.32% (w/w). The nanoparticles were characterized by UV-Vis absorption, luminescence, EPR, near edge x-ray absorption fine structure (NEXAFS), and x-ray photoelectron spectroscopy (XPS), and x-ray diffraction (XRD), and transmission electron microscopy (TEM). These quantum dots show a strong emission at 590 nm due to the ⁴T₁ -⁶A₁ transition characteristic of Mn …

Acylpyrazolones: Synthesis, Self-Assembly And Lanthanide Metal Ion Separation, Jun Yang

Dissertations

The central hypothesis that nanoscale self-assemblies can provide excellent metal ion recognition has been substantiated by employing acylpyrazolones and trivalent lanthanide metal ions as model systems. Several novel acylpyrazolones and their amphiphilic analogs have been designed, synthesized, and characterized. Their lanthanide metal ion recognition efficacies have been demonstrated through baseline separations of a mixture of light, middle, and heavy lanthanide metal ions by employing them in the aqueous mobile phase of high performance liquid chromatography (HPLC) with octadecylsilanized silica (ODS) as the stationary phase. The complex separation mechanism is influenced by the structures of acylpyrazolone and amphiphilic moieties, and spontaneous …

Rank-Based Methods For Repeated Measures Data Under Exchangeable Errors, John Kloke

Dissertations

Rank-based estimation methods provide alternatives to least squares. Estimators derived via least squares are generally not robust to aberrant observations.Rank-based methods for linear models generalize traditional Wilcoxon procedures in the simple location models and are robust.

In the usual linear model it is assumed that the errors are independent. In the case of repeated measures data several observations are taken on each experimental unit. In the case of longitudinal data the measures are taken on the same subject over time. As such an independence assumption does not seem valid. A common solution to this is to make an assumption on …

Modeling Of Flexible Drug-Like Molecules : Qsar Of Gbr 12909 Analog Dat/Sert Selectivity, Kathleen Mary Gilbert

Dissertations

The dopamine reuptake inhibitor GBR 12909 and related dialkyl piperazine and piperidine analogs have been studied as agonist substitution therapies acting on the dopamine transporter (DAT) to treat cocaine addiction. Undesirable binding to the serotonin transporter (SERT) can vary greatly depending on the specific substituents on the molecule. This study uses Comparative Molecular Field Analysis (CoMFA) and Comparative Molecular Similarity Indices (CoMSIA) techniques to determine a stable and predictive model for DAT/SERT selectivity for a set of flexible GBR 12909 analogs.

Families of analogs were constructed from six pairs of naphthyl-substituted piperazine and piperidine templates identified by hierarchical clustering as …

Influences Of Surfactant On The Breakup Of A Fluid Jet In Viscous Surrounding, Muhammad Irfan Hameed

Dissertations

The effect of insoluble surfactant on the breakup of a fluid jet surrounded by another viscous fluid at low Reynolds number is studied both theoretically and experimentally. Equations governing the evolution of the interface and surfactant concentration are derived using a long wavelength approximation for the case of an inviscid jet and a slightly viscous jet surrounded by a more viscous fluid. These one dimensional partial differential equations governing the evolution of the slender jet are solved numerically for given initial interfacial perturbations and surfactant concentration. It is found that the presence of insoluble surfactant at the interface retards the …

Dynamics Of Filaments, Flares And Coronal Mass Ejections (Cmes), Ju Jing

Dissertations

The objective of this dissertation is to investigate the connection between the dynamics of solar surface phenomena such as filament eruptions, flares, the coronal mass ejections (CMEs), the core of so-called solar activity, and the properties of the associated magnetic field for the development of forecasts of solar activity and space weather. Both statistical and case studies have been carried out.

The topics covered in this dissertation are: the statistical relationship among phenomena of solar activity, in particular, filament eruptions, flares and coronal mass ejections (CMEs); the correlation between magnetic reconnection rate and flux rope acceleration of two-ribbon flares; the …

The Effects Of Digital Audio On Social Presence, Motivation And Perceived Learning In Asynchronous Learning Networks, Eunhee Kim

Dissertations

This study explores the possibilities of applying digital audio to the ALN environment, so that students can speak and listen rather than type and read. Two sets of 1x2 field experiments (text vs. digital audio) were conducted with two formats of digital audio -recorded voice messages and narrated Microsoft PowerPoint presentation - used in several NJIT courses conducted via ALN. The perceptions of communication media were measured from two different user perspectives: active use when the subjects created their assignments using prescribed communication media (audio or text) and passive use when the subjects viewed/listened to other students' work.

The perceptions …

Some Topics On Deterministic Scheduling Problems, Yumei Huo

Dissertations

Sequencing and scheduling problems are motivated by allocation of limited resources over time. The goal is to find an optimal allocation where optimality is defined by some problem specific objectives.

This dissertation considers the scheduling of a set of ri tasks, with precedence constraints, on m >= 1 identical and parallel processors so as to minimize the makespan. Specifically, it considers the situation where tasks, along with their precedence constraints, are released at different times, and the scheduler has to make scheduling decisions without knowledge of future releases. Both preemptive and nonpreemptive schedules are considered. This dissertation shows that optimal …

Evaluating Rhizodegradation Of Petroleum Hydrocarbons And Polycyclic Aromatic Hydrocarbons In Wetland Sediments Containing Spartina Patens, Robert J. Lippencott

Dissertations

Biodegradation of petroleum hydrocarbons (PHC) and 16 polycyclic aromatic hydrocarbon (PAH) compounds was evaluated in sediments from a stormwater basin that was a former salt marsh at an active oil refinery. Spartina patens were grown in basin sediments during a field study and a greenhouse study over three consecutive growing seasons. Ninety percent (90%) survival was observed in field study plots containing sediments with <12% PHC. In the greenhouse study, planted and bulk sediments were monitored for PHC, PAH, microbial density, nutrients, pH, redox and root biomass at 2.5 and 7.5 cm in sediments with <12% PHC. The sediments contained on average 6.5% to 9.5% PHC and 56 to 124 parts per million (ppm) total PAH. The plants exhibited a 95% survival rate and added from 1% to 2% root biomass to the sediment. Microbial densities in planted sediments were significantly higher than in bulk sediments (p<0.05). Oxidizing conditions were prevalent in all treatments at both depths; however, reducing conditions developed in the planted sediments at 7.5 cm. PHC was 35% to 37% lower in the planted sediments vs. bulk sediment at the end of the study. Planted sediment PAH concentrations were generally lower than in bulk sediments. Low MW PAHs (2 and 3-Rings) were either absent or at relatively low concentrations in all treatments. Phenanthrene concentrations in bulk sediments did not change, but were reduced by 95% in planted sediments (p<0.01), with half-life estimates of 141 to 165 days at 2.5 cm. Temporal changes in high MW PAHs ( 4-Rings) were not observed over the greenhouse study period. Differences in PAH concentrations between planted and bulk sediments exhibited a decreasing trend with PAH molecular weight. Evaluation of differences in planted and bulk sediment PAH concentrations suggests that lower MW PAHs degrade better under oxidizing conditions, and higher MW PAHs under reducing conditions in the planted sediments. Comparison of planted and bulk sediment PAH concentrations links depth and redox conditions to decreases in PAH as a function of PAH MW. Therefore, it was concluded that spatio-temporal variations and cycling of redox conditions should be considered to properly evaluate biodegradation of PAH.

Theory And Algorithms For Swept Manifold Intersections, Yuriy Mileyko

Dissertations

Recent developments in such fields as computer aided geometric design, geometric modeling, and computational topology have generated a spate of interest towards geometric objects called swept volumes. Besides their great applicability in various practical areas, the mere geometry and topology of these entities make them a perfect testbed for novel approaches aimed at analyzing and representing geometric objects. The structure of swept volumes reveals that it is also important to focus on a little simpler, although a very similar type of objects - swept manifolds. In particular, effective computability of swept manifold intersections is of major concern.

The main goal …

Scheduling Policies For Disks And Disk Arrays, Chang Liu

Dissertations

Recent rapid advances of magnetic recording technology have enabled substantial increases in disk capacity. There has been less than 10% improvement annually in the random access time to small data blocks on the disk. Such accesses are very common in OLTP applications, which tend to have stringent response time requirements. Scheduling of disk requests is intended to improve their response time, reduce disk service time, and increase disk access bandwidth with respect to the default FCFS scheduling policy.

Shortest Access Time First policy has been shown to outperform other classical disk scheduling policies in numerous studies. Before verifying this conclusion, …

Image Watermarking, Steganography, And Morphological Processing, Yi-Ta Wu

Dissertations

With the fast development of computer technology, research in the fields of multimedia security, image processing, and robot vision have recently become popular. Image watermarking, steganogrphic system, morphological processing and shortest path planning are important subjects among them. In this dissertation, the fundamental techniques are reviewed first followed by the presentation of novel algorithms and theorems for these three subjects.

The research on multimedia security consists of two parts, image watermarking and steganographic system. In image watermarking, several algorithms are developed to achieve different goals as shown below. In order to embed more watermarks and to minimize distortion of watermarked …

Collaborative Examinations In Asyncronous Learning Networks : Field Experiments On Collaborative Learning Through Online Assessments, Jia Shen

Dissertations

With the proliferation of computer networks and the emergence of virtual teams, learning and knowledge sharing in the online environment has become an increasingly important topic. Applying constructivism and collaborative learning theories to assessment, the collaborative online exam is designed featuring students' active participation in various phases of the exam process through small group activities online. A participatory online exam process is designed featuring similar procedures except that students' involvement in each phase of the exam is individual. The collaborative online exam and the participatory online exam are investigated regarding student exam study strategies, group process, exam outcomes, faculty satisfaction, …

Electromagnetic And Acoustic Propagation In Strip Lines And Porous Media, Lin Zhou

Dissertations

Wave propagation in two physical structures is described and analyzed in this dissertation. In the first problem, the propagation of a normally incident plane acoustic wave through a three dimensional rigid slab with periodically placed holes is modeled and analyzed. The spacing of the holes A and B, the wavelength λ and the thickness of the slab L are order one parameters compared to the characteristic size D of the holes, which is a small quantity. Scattering matrix techniques are used to derive expressions for the transmission and reflection coefficients of the lowest mode. These expressions depend only on the …

Algorithms And Complexity Analyses For Some Combinational Optimization Problems, Hairong Zhao

Dissertations

The main focus of this dissertation is on classical combinatorial optimization problems in two important areas: scheduling and network design.

In the area of scheduling, the main interest is in problems in the master-slave model. In this model, each machine is either a master machine or a slave machine. Each job is associated with a preprocessing task, a slave task and a postprocessing task that must be executed in this order. Each slave task has a dedicated slave machine. All the preprocessing and postprocessing tasks share a single master machine or the same set of master machines. A job may …

Just-In-Time Hypermedia, Li Zhang

Dissertations

Many analytical applications, especially legacy systems, create documents and display screens in response to user queries "dynamically" or in real time . These documents and displays do not exist in advance, and thus hypermedia must be generated 'just in time" -automatically and dynamically.

This dissertation details the idea of 'just-in-time" hypermedia and discusses challenges encountered in this research area. A fully detailed literature review about the research issues and related research work is given. A framework for the 'just-in-time" hypermedia compares virtual documents with static documents, as well as dynamic with static hypermedia functionality. Conceptual 'just-in-time" hypermedia architecture is proposed …