Physical Sciences and Mathematics Commons^™

Pattern-Based Model Transformation: A Metamodel-Based Approach To Model Evolution, Sheena Judson Miller

LSU Doctoral Dissertations

Software systems continue to grow in complexity at a rapid pace, creating systems that are complex to build and evolve. The problems that accompany changes in requirements, system upgrades, and error correction produce a desire for software evolution methods that increase the efficiency and effectiveness of adapting complex software to changes. As software systems evolve, design models must be modified to accommodate the required changes. Techniques that control the changes to models in a systematic manner are a key to model evolution. A process that improves the ability to effectively modify a design, thereby enhancing design qualities, supports the need …

Dynamics Of Complex Polymer Solutions: Putting Diffusion To Work And Exploring Rigid Rod Diffusion, Garrett John Doucet

LSU Doctoral Dissertations

This dissertation is concerned with random coil and rodlike polymer diffusion in complex solutions. The development of fluorescence photobleaching recovery, FPR, as a technique to determine polymer molecular weight distributions by measuring the diffusion distribution and converting it to a molecular weight distribution using a calibration curve is first covered. Fluorescently tagged probes were individually dissolved in polymer solutions at negligible amounts and measured with FPR to construct the calibration curve of self-diffusion vs. molecular weight. Once calibration curves were constructed, bimodal distributions were separated using the matrices corresponding to the calibration curves. The diffusion of the probes and separation …

Orbit Structure On The Silov Boundary Of A Tube Domain And The Plancherel Decomposition Of A Causally Compact Symmetric Space, With Emphasis On The Rank One Case, Troels Roussau Johansen

LSU Doctoral Dissertations

We construct a G-equivariant causal embedding of a compactly causal symmetric space G/H as an open dense subset of the Silov boundary S of the unbounded realization of a certain Hermitian symmetric space G₁/K₁ of tube type. Then S is an Euclidean space that is open and dense in the flag manifold G₁/P', where P' denotes a certain parabolic subgroup of G₁. The regular representation of G on L²(G/H) is thus realized on L²(S), and we use abelian harmonic analysis in the study thereof. In particular, …

Mortality Of Pen-Raised White-Tailed Deer (Odocoileus Virginianus) Released On Three Areas In Louisiana, Barret Keith Fortier

LSU Master's Theses

I monitored 60 radio-collared and tagged pen-raised white-tailed deer (Odocoileus virginianus) to ascertain mortality rates on three areas in Louisiana from April 2001 - April 2002. Two of 60 were not used in the analysis because mortality occurred from complications with darting and an affixed radio-collar. Study deer were exposed to legal hunting mortality only if they emigrated from the three study areas. Twenty deer were released to the wild on the Louisiana State University Deer Study Area (LSUDSA) (4,810 ha), where 9 of 20 (45%) suffered mortality. Harvest accounted for 56%, vehicles 22%, and other 22% of the mortality …

Natural Regeneration Of Native Vegetation On Abandoned Agricultural Land In The Fitzgerald Biosphere, Nerilee Boshammer

Theses : Honours

Much of the natural landscape in the south-west of Western Australia has been severely modified as a result of past and current agricultural activity. One of the most conspicuous changes has been the large scale clearing of native vegetation, The evidence of the negative impacts of this vegetation removal on the natural environment is now extensive, particularly in the south-west region of the State. In order to prevent further degradation of the landscape of the south-west and subsequent loss of endemic species, strategic revegetation within the agricultural landscape is required. Native vegetation corridors can be established, linking areas of remnant …

Plant Surrogacy: An Evaluation Of Its Use And Application In The Effort To Conserve Ground Dwelling Invertebrates, Kerry Leigh Ironside

Theses : Honours

A study conducted in the Ridges State Forest, Yanchep was designed to investigate the relationship between plant species richness, vegetation association and ground dwelling invertebrate species richness. Four plant communities were sampled at two scales of measurement. Two treatments were located in woodland and two in heath. Within each vegetation association, plant communities that were representative of both high and low species richness were selected. Three invertebrate orders, Araneae, Coleoptera and Araneae were sorted to morphospecies level. Ordinal richness was also investigated. Two-way ANOVAs indicated that there was no relationship between plant species richness, vegetation association· or the interaction between …

Post Monitoring Of A Cyclodextrin Remediated Chlorinated Solvent Contaminated Aquifer, Rebecca Mary Hinrichs

LSU Master's Theses

Hydroxypropyl-β-cyclodextrin (HPβCD) has been tested successfully in the laboratory and in the field for enhanced flushing of low-polarity contaminants from aquifers. The cyclodextrin molecule forms a toroidal structure, which has a hydrophobic cavity. Within this cavity, organic compounds of appropriate shape and size can form inclusion complexes, which is the basis for the use of cyclodextrin in groundwater remediation. The hydrophilic exterior of the molecule makes cyclodextrin highly water-soluble. The solubility of cyclodextrins can be further enhanced by adding functional groups, such as hydroxypropyl groups, to the cyclodextrin core. The aqueous solubility of HPβCD exceeds 950 g/L. These high solubilities …

Determining Epigenetic Instability In Normal And Diseased Human Vulva, Kirk Hutchinson

LSU Master's Theses

Epigenetics is defined as the study of heritable changes of DNA. One such component of epigenetic regulation is DNA methylation in humans. In neoplastic cells epigenetic controls are often dysregulated, especially in the promoter region of CpG islands. Global hypomethylation along with region specific hypermethylation of CpG islands in the promoter region of tumor suppressor is often indicative of neoplastic cells. In cancer, CpG island cytosine hypermethylation has been observed in more than fifty genes, including known tumor suppressor and DNA repair genes. Squamous cell carcinoma (SCC), lichen sclerosis (LS), and adjacent normal tissues were obtained by radical vulvectomies of …

Attachment Of Oligonucleotide Probes To Polymer Biochips And Its Application For The Detection Of Point Mutations, Yun Wang

LSU Doctoral Dissertations

This dissertation is on the fabrication of polymer-based microfluidic arrays for the detection of genetic mutations. Poly(methyl methacrylate) was chosen as one of the polymer substrate materials due to its low background noise, low adsorption of biomolecules, and low assembly temperature. The surface modification of polymer substrates for covalent attachment of oligonucleotide probes, the construction of fluidic channels/arrays, and hybridization kinetics will be covered. As an example of the application, point mutation detection using immobilized arrays constructed in microfluidic devices will be demonstrated. The PMMA surface was derivatized with N-lithioethylenediamine solution to introduce amine groups, which were utilized for the …

Software Architecture: Styles And Representational Schemes, Somo Subro Banerjee

LSU Master's Theses

Software architecture is being widely used today to describe a very high-level design methodology of large software systems. Software architecture represents the overall structure of a system in an abstract, structured manner. A good architectural representation scheme holds the key to the effectiveness of a software architecture description and usage. In this work we look at architectural styles and architectural representation schemes. We propound the idea that the layered architectural model is a suitable candidate for a generalized architectural style and that it can cater to many different problem domains, other than the message-passing systems it has traditionally been used …

Enhanced Flushing With Cyclodextrin For The Remediation Of Creosote Contaminated Soil, Monalisa Dutta

LSU Master's Theses

Past practices of applying creosote and coal tar preservatives to wood, such as unlined pits and trenches, have resulted in contamination of the surface and ground water at thousand of sites. The low aqueous solubility, volatility and bioavailability of many these constituents limit their degradation by natural attenuation and standard remediation techniques such as ground water flushing, soil vapor extraction, and bioremediation. While research has shown that cyclodextrin solutions have the ability to enhance the solubility of some of the components of creosote, additional work is needed to evaluate its potential as a remedial agent for these sites. Equilibrium batch …

Short-Term Evolution Of A Marsh Island System And The Importance Of Cold Front Forcing, Terrebonne Bay, Louisiana, Dana Ann Watzke

LSU Master's Theses

Short-term, wave induced erosion along bay beaches in the northern Gulf of Mexico has been linked to the postfrontal phase of cold front passages. Not until recently has consideration been given to the importance of wave erosion on marshes fringing large bays during the entire cold front event. Two WAVCIS (Wave-Current-Surge-Information System) stations were established on the north and south flank of a small marsh island in Terrebonne Bay, Louisiana, to measure and elucidate the hydrodynamic response to these events. Data from WAVCIS stations, which includes wind speed and direction, air temperature, significant wave height and water level, were collected …

Quality Assurance Testing Of The Eclox-M In Detecting Terrorism Threats In Louisiana's Public Drinking Water Systems, Jessica Coleman

LSU Master's Theses

A quality assurance testing of the ECLOX-M™, a rapid water quality indicator used in potential terrorist attacks, was evaluated for its adequacy in nine regional Louisiana water systems. The ECLOX-M™ system uses enhanced chemiluminescence to measure toxicity in water by integration of a mixture of luminol (C₈H₇O₃N₃), and an oxidant in the presence of a catalyst enzyme - horseradish peroxidase (HRP). Water samples were tested for chemiluminescence, chlorine content, pH, and arsenic and/or nerve agent/pesticide contamination. In addition, three toxic industrial chemical standards were evaluated (mercury, a volatile liquid mixture, and a …

Electronic Structural Investigations Of Bi- And Polymetallic Complexes Using Quantum Mechanical Methods, Zakiya Sheni Wilson

LSU Doctoral Dissertations

Understanding the dynamics influencing chemical reactivity is essential for properly exploiting matter into more useful purposes. In that manner, computational chemistry is a tool frequently used to study chemical properties at the most intimate level, i.e. the single molecule.

With this work, we probe the chemistry governing a variety of multi-faceted bi- and polymetallic compounds. To date our research consists of four major projects: bimetallic rhodium-catalyzed hydroformylation and aldehyde-water shift hydrocarboxylation catalysis; a novel linear M-H-M interaction in a bridged bis(dialkylphosphino)methane complex of nickel; and CeBe₁₃, a heavy fermion conductor. Computational investigations on these systems allow us to …

Evaluation Of A Desktop Computed Radiography System For Imrt Dosimetry, Ines-Ana Jurkovic

LSU Master's Theses

Different techniques have been developed and used to evaluate dose distribution calculation accuracy and dose delivery reproducibility as a part of patient-specific IMRT QA – e.q. film dosimetry, ionization chambers, and diode arrays. To verify that the calculated dose distribution is delivered accurately during treatment, film dosimetry is usually used. The accuracy and reproducibility of film optical density as an indicator of dose is influenced by several variables, including the chemical processing and scanning conditions. This study investigates the possibility to use a desktop computed radiography (CR) system for patient-specific intensity modulated radiation therapy (IMRT) quality assurance (QA). A study …

Microsatellite Instability In Squamous Cell Carcinoma And Lichen Sclerosus Of The Vulva, Sidney Joseph Marlborough

LSU Master's Theses

The usefulness of detecting genomic instability in the form of microsatellite instability (MSI) has been examined in a number of cancers. Squamous cell carcinoma (SCC) and adjacent normal and lichen sclerosis (LS) samples were taken from patients with radical vulvectomies. Vulvar SCC samples were compared with adjacent normal samples using four oligonucleotide markers (BAT-25, BAT-26, D10S208 and D10S587) found to be informative with other carcinomas. Using polymerase chain reaction techniques, 30 vulvar SCC DNA samples were examined for MSI. BAT-26 displayed the highest level of MSI and was considered to be the most sensitive marker in studying vulvar SCC. There …

Validation Of Pet/Ct Dataset For Radiation Treatment Planning, Rajesh Manoharan

LSU Master's Theses

PET/CT scans are frequently used for radiation treatment planning (RTP). Our work demonstrates a practical approach for validating the PET/CT dataset for RTP. We tested this QA process on a Reveal HD PET/CT scanner. The phantom used is a TGM2 ISIS QA phantom, a 14 cm acrylic cube with a central bore for object inserts. It has four different built-in inserts for electron density verification. 22Na seeds are inserted into the pinholes at the side of the cube. PET/CT images of the phantom with 22Na seeds are acquired and fused in the scanner Syngo fusion software. Registration of the PET/CT …

The Fidelity Of Red Snapper (Lutjanus Campechanus) To Petroleum Platforms And Artificial Reefs In The Northern Gulf Of Mexico, Megan Blythe Peabody

LSU Master's Theses

The habitat value of petroleum platforms for red snapper, Lutjanus campechanus, is poorly understood. However, it is widely recognized by both scientists and fishermen that the presence of platforms in the northern Gulf of Mexico (GOM) has affected the distribution of red snapper by the addition of hard substrate habitat. I evaluated the habitat value of standing and toppled platforms by monitoring the fidelity of red snapper to these structures with acoustic telemetry. In May 2003, 125 red snapper were captured with hook and line at several platforms in a 35-km2 portion of the South Timbalier oil and gas lease …

Synthesis, Separation And Reactivities Of Multidentate Phosphine Ligands And Investigation Into Dirhodium Hydroformylation And Hydrocarboxylation Catalysis, David Aubry

LSU Doctoral Dissertations

A dirhodium homogeneous hydroformylation catalyst based on a tetraphosphine ligand, rac-Et₂PCH₂CH₂P(Ph)CH₂P(Ph)CH₂CH₂PEt₂, rac-et,ph-P4, is under investigation. The ligand synthesis produces a racemic mixture and a facile and efficient method of separation of the racemic and meso diastereomers was achieved through reaction of et,ph-P4 with two equivalents of NiCl₂ in EtOH to yield an almost quantitatively isolable precipitate of meso-Ni₂Cl₄(et,ph-P4) and the soluble rac-Ni₂Cl₄(et,ph-P4). Subsequent cyanolysis of these complexes liberates the et,ph-P4 ligand, and the …

An Evaluation Of Reference Evapotranspiration Models In Louisiana, Royce Landon Fontenot

LSU Master's Theses

Daily and monthly output from seven evapotranspiration models (FAO-24 Radiation, FAO-24 Blaney-Criddle, Hargreaves-Samani, Priestly-Taylor, Makkink, and Turc) have been tested against reference evapotranspiration data computed by the FAO-56 Penman-Monteith model to assess the accuracy of each model in estimating grass-reference evapotranspiration in Louisiana. Models were compared at eight stations of the Louisiana Agriclimate Information System using data from December 2002 to November 2003. Comparisons were also made using three composite regions: statewide, inland, and coastal. A pan evaporation to reference evapotranspiration model (FAO-24 Pan Evaporation) was also tested against daily grass reference evapotranspiration from the FAO-56 Penman-Monteith model using data …

Overlap Zones, Growth Faults, And Sedimentation: Using High Resolution Gravity Data, Livingston Parish, La, Carrie Alison Cazes

LSU Master's Theses

In south Louisiana, parallel to the coast of the Gulf of Mexico, are belts of east-to-west trending, listric-normal faults with associated contemporaneous sedimentation and fault movement. The Tepetate-Baton Rouge Fault system in south-central Louisiana contains individual fault segments which are arcuate and overlap each other in map view, as seen on LiDAR data. Gravity survey data, with a sample spacing of 20 to 50 m, was collected across normal fault scarps. Structural ramps may form in the area between overlapping normal fault segments creating an east-to-west gradient. This gradient change may divert streams and provide areas for coarse-grained sediments to …

A Comparison Of A High-Resolution Survey And A Three-Dimensional Seismic Survey In A Feature-Rich Region Of The Green Canyon Area, Gulf Of Mexico, Bruce Miles Samuel

LSU Master's Theses

Recent advances in Autonomous Underwater Vehicle (AUV) technology have revolutionized the positioning and accuracy of high-resolution deep sea mapping tools. Geologic hazard and engineering surveys by AUV’s are producing high-resolution data sets of a quality that has never before been seen. Three-dimensional (3D) seismic data, though traditionally used for only deep subsurface mapping of large areas, is now being reprocessed at a higher resolution and utilized in well site investigations and geologic hazard assessments. This study makes a comparison between a 3D seismic survey and an AUV high-resolution survey in order to determine the strengths and weaknesses of both of …

20 Years Of Speleothem Paleoluminescence Records Of Environmental Changes: An Overview, Yavor Y. Shopov

International Journal of Speleology

This paper discusses advance of the research on Speleothem Paleoluminescence Records of Environmental Changes after it have been first introduced by the author 20 years ago. It is demonstrated that most of the progress in this field was made in result of the operation of the International Program “Luminescence of Cave Minerals” of the commission on Physical Chemistry and Hydrogeology of Karst of UIS of UNESCO. Potential, resolution and limitations of high resolution luminescence speleothem proxy records of Paleotemperature, Solar Insolation, Solar Luminosity, Glaciations, Sea Level advances, Past Precipitation, Plants Populations, Paleosoils, Past Karst Denudation, Chemical Pollution, Geomagnetic field and …

Influence Of Solar Luminosity Over Geomagnetic And Climatic Cycles As Derived From Speleothems, Y. Shopov, D. Stoykova, L. Tsankov, M. Sanabria, D. Georgieva, D. Ford, L. Georgiev

International Journal of Speleology

We observed cycles presented in a luminescent solar insolation proxy record from a speleothem from Jewel Cave, South Dakota, US. We found cycles of orbital precession with periods of 23 and 19 ka and of obliquity of 41 ka and many others from non-orbital origin in this sample. We determined the Solar origin of the cycles with durations of 11500, 4400, 3950, 2770, 2500, 2090, 1960, 1670, 1460, 1280, 1195, 1145, 1034, 935, 835, 750 and 610 years. It was done by their detection both in proxy records of speleothem luminescence, Δ¹⁴C and the intensity of the geomagnetic …

Activators Of Luminescence In Speleothems As Source Of Major Mistakes In Interpretation Of Luminescent Paleoclimatic Records, Y. Y. Shopov

International Journal of Speleology

This work summarizes the main results of the operation of the International Program “Luminescence of Cave Minerals” of the commission on Physical Chemistry and Hydrogeology of Karst of UIS of UNESCO in the field of activators of speleothem luminescence. It discusses Activators of Luminescence in Speleothems as a source of major mistakes in the interpretation of luminescent paleoclimatic records. It demonstrates the existence of 6 types of luminescence of speleothems and cave minerals in dependence of the type of the luminescence center and its incorporation in the mineral. 24 different activators of photoluminescence of speleothem calcite and 11 of aragonite …

Evolution Of Golpazari-Huyuk Karst System (Bilecik-Turkey): Indications Of Morpho-Tectonic Controls, Mehmet Ekmekci, Lütfü Nazik

International Journal of Speleology

The Golpazari-Huyuk karst system is located in the Central Sakarya Basin whose geomorphologic evolution is mainly controlled by the Post-Miocene epirogenic continental rise. Drastic change in the drainage pattern and dissection of the carbonate platform were the major consequences of this tectonic movement. Rapid incision of the Sakarya river changed the position of the erosion base which consequently distorted the direction of surface and subsurface flow. The Golpazari and Huyuk plains are two topographically distinct, flat bottomed geomorphic features separated by a carbonate rock relief. The difference in elevation between these 10 km distant plains is 350 m. Morphological, geological …

Dissaggregation Modelling Of Spring Discharges, Elena Kirilova Bojilova

International Journal of Speleology

Disaggregation models are basically divided into three main groups: temporal, spatial and temporal-spatial. The focus of this paper is the application of temporal disaggregation models to disaggregate the seasonal flow in some large time intervals to sub-seasonal flows in some shorter time intervals. Two basic models are applied: the original model of Mejia and Rousselle and the corrected extended Lin model one-stage disaggregation. The flow totals from some karstic springs are used. Data for five springs in different areas of Bulgaria for the aims of the study are executed. The synthetic data generation for the chosen spring stations for a …

The Role Of The Environmental Archaeologist In The Study And Reconstruction Of Cave Palaeoclimate, Maria Gkioni

International Journal of Speleology

Man and environment are engaged in a continuous battle to impose themselves on one another. The results are found in environmental modifications or climatic oscillations and, as far as man is concerned, in the different character of cultural remains. Man responds to environmental changes by migrating or evolving technological innovations, both of which leave important remains that the archaeologist is called on to recognise and interpret during and after an excavation. They both also reflect the sociocultural responses to climatic stress. This paper refers to a specific case study, caves, which housed man and his activities from the very early …

Paleocollapse Structures As Geological Record For Reconstruction Of Past Karst Processes During The Upper Miocene Of Mallorca Island, P. A. Robledo Ardila, J. J. Durán, L. Pomar

International Journal of Speleology

Paleocollapse structures and collapse breccias are one of the major features for paleokarst analysis and paleoclimate record. These are affecting the Llucmajor and Santanyí carbonate platforms. These platforms, of southern and eastern Mallorca respectively, are a good example of progradation reef platform in the western Mediterranean. The Santanyí platform is constituted of two sedimentary units, both affected by paleocollapse structures: (1) The Reef Complex attributed to the upper Tortonian-lower Messinian; (2) Santanyí Limestone attributed to the Messinian. There are abundant paleocollapse outcropping in the Reef Complex and Santanyí Limestone units. These structures have been produced by roof collapse of caverns …

Trace Elements In Speleothems. A Short Review Of The State Of The Art, Sophie Verheyden

International Journal of Speleology

A state of the art of the research on trace elements of speleothems is given. First studies focussed on problems such as the colour of speleothems and the aragonite problem. Insitu studies and studies oriented towards a better understanding of vadose hydrology brought new insights in the controls on trace elemental composition of speleothems. Recent studies deal with microscale analyses and annual and intra-annual chemistry changes. Further in-situ studies should be performed to further differentiate influences, such as climate, soil/weathering and local hydrology in order to better constrain possible transfer functions between the surface and a speleothem.