Physical Sciences and Mathematics Commons^™

Improving Robustness Of Deep Learning Models And Privacy-Preserving Image Denoising, Hadi Zanddizari

USF Tampa Graduate Theses and Dissertations

Applications of deep learning models and convolutional neural networks have been rapidly increased. Although state-of-the-art CNNs provide high accuracy in many applications, recent investigations show that such networks are highly vulnerable to adversarial attacks. The black-box adversarial attack is one type of attack that the attacker does not have any knowledge about the model or the training dataset, but it has some input data set and theirlabels.

In this chapter, we propose a novel approach to generate a black-box attack in a sparse domain, whereas the most critical information of an image can be observed. Our investigation shows that large …

First-Principles-Based Modeling Of Energy Converting Properties Of Conventional And Emerging Ferroelectrics, Maggie Kingsland

USF Tampa Graduate Theses and Dissertations

Ferroelectric materials are a type of multifunctional material that exhibit spontaneous polarization reversable by the application of an electric field. They are used in many technologies such as ferroelectric RAM (FeRAM), piezoelectric devices, RFID chips, and capacitors. However, the most commonly used ferroelectrics are often made with rare, expensive elements and are not environmentally friendly. For example, many prototypical ferroelectrics contain elements such as lead, zirconium, and titanium. As technology grows more advanced, there is a need to discover or manufacture cheaper ferroelectrics and to make them less impactful on human health and the earth as a whole. We set …

Study On New Reactivity Of Vinyl Gold And Its Sequential Transformations, Teng Yuan

USF Tampa Graduate Theses and Dissertations

This dissertation mainly contains three parts: 1) the study of new reactivity of vinyl gold(I) and synergistic gold-iron catalyzed regioselective crossed aldol reaction. 2) synergistic gold-iron catalyzed amide crossed aldol reaction by using ynamides as ‘masked’ amides. 3) alkyne trifunctionalization via divergent gold catalysis: combining three modes of gold catalysis: π activation, nucleophilic addition of vinyl gold and gold redox catalysis. This novel method affords access to constructing C-N, C-O and C-C bond in one step at mild condition.

In the first part, a new reaction mode in gold catalysis will be introduced. Due to the protodeauration of vinyl gold …

Exploring Magneto-Excitons In Bulk And Mono-Layer Semiconductors Using Non-Linear Spectroscopy Techniques, Varun Mapara

USF Tampa Graduate Theses and Dissertations

The research in two-dimensional (2D) materials has evolved from ``traditional" quantum wells based on group III-V and II-VI semiconductors to atomically thin sheets of van der Waals materials such as 2D semiconducting Transition Metal Dichalcogenides (TMDs). These 2D materials remain a stimulating field that continues to introduce new challenges. From both a fundamental physics and technological perspective, magneto-optical spectroscopy has been an essential tool in this research field. TMDs, for example, pose the challenge of characterizing their spin-valley-resolved physics and deriving implications in quantum computation and information research. With the discovery of valley Zeeman effects, the spin-valley physics of TMDs …

Watershed Management For Nutrient Control In Taylor Creek And Nubbins Slough, Florida, Rachael Z. Cooper

USF Tampa Graduate Theses and Dissertations

Despite efforts to improve water quality within the watershed since the 1970s, harmful algal blooms (HABs) still occur within Lake Okeechobee (LO). HABs are harmful to the people, the ecosystem, and the economy dependent on the lake. Taylor Creek Nubbins Slough (TCNS) is a subwatershed of the lake, contributing to a large percentage of the nutrient loading. Due to the size and complexity of LO’s watershed, two smaller basins within the TCNS subwatershed were selected to evaluate the following research questions: (1) How do water quality trends contrast between two basins? (2) How do nutrient load and treatment within the …

Analyzing Decision-Making In Robot Soccer For Attacking Behaviors, Justin Rodney

USF Tampa Graduate Theses and Dissertations

In robotics soccer, decision-making is critical to the performance of a team’s SoftwareSystem. The University of South Florida’s (USF) RoboBulls team implements behavior for the robots by using traditional methods such as analytical geometry to path plan and determine whether an action should be taken. In recent works, Machine Learning (ML) and Reinforcement Learning (RL) techniques have been used to calculate the probability of success for a pass or goal, and even train models for performing low-level skills such as traveling towards a ball and shooting it towards the goal[1, 2]. Open-source frameworks have been created for training Reinforcement Learning …

Predicting The Number Of Objects In A Robotic Grasp, Utkarsh Tamrakar

USF Tampa Graduate Theses and Dissertations

Picking up the desired number of objects at once from a pile is still very difficult to dofor a robot. The main challenge is predicting the number of objects in the grasp. This thesis describes several deep-learning-based prediction models that predict the number of objects in the grasp of a Barrett hand using the tactile sensors on its fingers and palm and its joint angles and torque (strain gauge) readings. The deep learning models include various architectures using autoencoders and vision transformers. We evaluated the models with a dataset of grasping 0, 1, 2, 3, and 4 spheres. Then, we …

Using Fine-Scale Aquatic Habitat Data To Construct Dreissenid Sdms In The Laurentian Great Lakes, Grace C. Henderson

USF Tampa Graduate Theses and Dissertations

The invasion of the Laurentian Great Lakes by aquatic invasive species (AIS) has been the subject of investigation for decades, due to their dramatic alterations to the ecosystem and high economic costs. Two AIS with the largest impacts are dreissenid zebra and quagga mussels, and though these species have been studied extensively, questions remain about what factors control their distributions, and whether lake warming will alter these distributions. Species distribution models (SDMs) offer a powerful tool to examine the relationship between species presences and environmental variables, which are typically bioclimactic data. The creation of the Aquatic Habitat (AqHab) dataset containing …

Measurements Of Generalizability And Adjustment For Bias In Clinical Trials, Yuanyuan Lu

USF Tampa Graduate Theses and Dissertations

While randomized controlled trials (RCTs) are widely used as a gold standard in clinical research and public health, they are criticized because of a potential lack of generalizability, as the trial patients may be unrepresentative of the target patient population. Few research addresses how to assess and evaluate the generalizability of RCTs. As we know, patients are rarely selected on a random basis from a well-defined patient population of interest into a clinical trial. Generalizing findings from the RCT samples to the patient population has begun to receive increasing attention. We simulate a patient population with treatment effect size of …

Developing Efficient Transition Metal Catalyzed C-C & C-X Bond Construction, Chiyu Wei

USF Tampa Graduate Theses and Dissertations

This dissertation mainly contains three parts: 1) The synergistic Pd/enamine catalysis for asymmetric hydrocarbon functionalization of unactivated alkenes with ketones; 2) Gold redox catalysis with a selenium cation as mild oxidant; 3) HFIP promoted disulfidation and diselenation of alkyne, alkene, and allene.

Palladium-catalyzed alkene activation has its intrinsic limitation: 1) the requirement of a pre-functionalized alkene to form a Pd π-allyl complex; 2) problematic reversible β-H elimination. It always leads to limited reaction scope and losing of the stereochemical control. Synergistic palladium and enamine catalysis was conducted to promote ketone addition to unactivated olefins. A secondary amine-based organocatalyst was identified …

Assessing Changes In Actual Air Quality And Public Perceptions Of Air Quality In Kathmandu Valley Nepal Pre And Post Covid-19 Lockdown, Robin Margherita Rives

USF Tampa Graduate Theses and Dissertations

Air pollution is a global concern. Cities around the world fail to meet air quality standards set by the World Health Organization Air Quality Guidelines, which has a significant impact on public health. As the capital city and largest metropolitan region of Nepal, Kathmandu is a hotspot for urban pollution in South Asia. Nepal faces emissions from both internal and external sources. External sources include emissions from Nepal’s neighboring countries of India and China and emissions resulting from tourism. Internal sources of pollution in the country include brick and cement factories, consumption of energy from traditional sources such as biomass, …

Pad Beyond The Classroom: Integrating Pad In The Scrum Workplace, Jade S. Weiss

USF Tampa Graduate Theses and Dissertations

Purpose: The “story” format used in Scrum ticket writing is confusing to developers and leadsto insufficient ticket content, which lends to miscommunication between team members and administrators, and disrupts workflow from the bottom up. A burgeoning methodology in Technical Writing, Purpose, Audience, Design (PAD) is an alternative ticket format that is easier to teach developers and improves the aforementioned conditions than the existing “story” format. The goal of this paper is to lay out why and how PAD can benefit developers on smaller Scrum teams who are tasked with writing their own tickets. This paper does not offer solutions for …

Quantitative Assessment Of The Trophic Ecology Of The Oceanic Ctenophore, Bolinopsis Infundibulum, In Monterey Bay, California, Victoria C. Scriven

USF Tampa Graduate Theses and Dissertations

Bolinopsis infundibulum is a wide-ranging, ubiquitous ctenophore whose fragile nature makes the collection of specimens and quantification of key predator-prey activities in controlled laboratory experiments, challenging. Thus, in situ methods often represent the best means for data collection. However, while present in surface waters, these animals can also be abundant at depths well beyond those attainable by divers. As a result, very little empirical data exist over the depth range of their natural habitats which limits our ability to assess key predator-prey interactions needed to assess their ecological role in midwater food webs. Working in Monterey Bay, California, remotely operated …

Symbolic Computation Of Lump Solutions To A Combined (2+1)-Dimensional Nonlinear Evolution Equation, Jingwei He

USF Tampa Graduate Theses and Dissertations

This thesis aims to consider a (2+1)-dimensional nonlinear evolution equation and its lump solutions. Byusing symbolic computation, two classes of lump solutions are presented. And for two specific chosen examples, we will show three-dimensional plots and density plots to exhibit dynamical features of the lump solution, which are made by Maple plot tools.

Factors Controlling Longshore Variations Of Beach Changes Induced By Hurricane Hermine Along Pinellas County Beaches, West-Central Florida, Wenhan Zhai

USF Tampa Graduate Theses and Dissertations

Hurricane Hermine, 2016, impacted the coast of west-central Florida and generated high waves superimposed on elevated wave levels which caused significant beach erosion. A total of 122 profiles, spaced about 300 m apart, were surveyed 2 weeks before and one week after the storm to examine the beach changes along three barrier islands along the coast of west-central Florida. including Sand Key, Treasure Island and Long Key. In order to investigates the longshore variations of beach/nearshore changes induced by storm, several parameters were defined and calculated including beach volume changes, berm height, beach width, foreshore slope, as well as sandbar …

Uncertainty Quantification In Deep And Statistical Learning With Applications In Bio-Medical Image Analysis, K. Ruwani M. Fernando

USF Tampa Graduate Theses and Dissertations

Deep Learning (DL) has achieved the state-of-the-art performance across a broad spectrum oftasks. From a statistical standpoint, deep neural networks can be construed as universal function approximators. Although statistical modeling and deep learning methods are well-established as independent areas of research, hybridization of the two paradigms via probabilistic deep networks is an emerging trend. Through development of novel analytical methods under the statistical and deep-learning framework, we address some of the major challenges encountered in the design of intelligent systems which include class imbalance learning, probability calibration, uncertainty quantification and high dimensionality. When modeling rare events, existing methodologies require re-sampling …

Novel Approach To Integrate Can Based Vehicle Sensors With Gps Using Adaptive Filters To Improve Localization Precision In Connected Vehicles From A Systems Engineering Perspective, Abhijit Vasili

USF Tampa Graduate Theses and Dissertations

Research and development in Connected Vehicles (CV) Technologies has increased exponentially, with the allocation of 75 MHz radio spectrum in the 5.9 GHz band by the Federal Communication Commission (FCC) dedicated to Intelligent Transportation Systems (ITS) in 1999 and 30 MHz in the 5.9 GHz by the European Telecommunication Standards Institution (ETSI). Many applications have been tested and deployed in pilot programs across many cities all over the world.

CV pilot programs have played a vital role in evaluating the effectiveness and impact of the technology and understanding the effects of the applications over the safety of road users. The …

Managing Incomplete Data In The Patient Discharge Summary To Support Correct Hospital Reimbursements, Fadi Naser Eddin

USF Tampa Graduate Theses and Dissertations

The patient discharge summary is a document that conveys the patient's story to other healthcare practitioners, external users, and, most importantly from a financial perspective, health insurers. A defect or incompleteness in the patient's discharge summary will result in delays in the collection process through denial of the entire or partial reimbursement claim or, in the best-case scenario, delay until the discharge summary issue is resolved. The purpose of this project is to address the issue of the incompleteness of discharge summary from the perspective of healthcare providers, with the goal of understanding, diagnosing, and intervening in the research problem. …

Soil Accretion And Mass Accumulation In A Scrub And Fringe Mangrove Forest In Biscayne Bay, Florida, Jessica A. Jacobs

USF Tampa Graduate Theses and Dissertations

This study estimated soil accretion and mass (organic carbon (OC), total nitrogen (TN), and total soil) accumulation in a scrub and fringe mangrove forest in Biscayne Bay, FL, to assess how forests of different morphologies (scrub vs. fringe) have kept pace with recently accelerating rates of sea-level rise. Accretion rates (AR) were estimated using the Constant Initial Concentration (CIC) model of lead-210 deposition and it was determined that the scrub forest has accreted at 1.3 ± 0.2 mm yr-1 over 75 years and the fringe forest at 2.8 ± 0.4 mm yr-1 over 92 years. The fringe forest estimate met …

Revisiting Darwin’S Little Pond As A Method To Liberate Phosphorus From Apatite Under Prebiotic Hadean Earth Conditions, Jennifer Lago

USF Tampa Graduate Theses and Dissertations

Phosphorus is an essential element for life as we know it. Phosphorus, mainly in the form of phosphate, is key to biologic functions such as genetic material, energy production, and cellular framework. As phosphorus is key to so many important biological functions it is of no wonder the question of how phosphorus was incorporated into life initially is a fundamental question in how life began.

During this time a prebiotic phosphorus source would need to have originated in rock, as phosphorus has not volatile source on Earth. The most prevalent mineral source on a prebiotic Earth would likely have been …

Fighting Mass Diffusion Of Fake News On Social Media, Abdallah Musmar

USF Tampa Graduate Theses and Dissertations

Fake news has been considered one of the most challenging problems in the last few years. The effects of spreading fake news over social media platforms are widely observed across the globe as the depth and velocity of fake news reach far more than real news (Vosoughi et al., 2018). The plan for the following dissertation is to investigate the mass spread of fake news across social media and propose a framework to fight the spread of fake news by mixing preventive methods that could hinder the overall percentage of fake news sharing. We plan to create a study on …

Efficient Management Of Nitrogen And Phosphorus At Centralized Water Reclamation Facilities, Helene Kassouf

USF Tampa Graduate Theses and Dissertations

A variety of process configurations are employed at municipal water reclamation facilities (WRFs), such as 5-stage Bardenpho, oxidation ditch, modified Ludzack-Ettinger (MLE) process, and sidestream recycle. However, all of these configurations face certain challenges in achieving optimum treatment of nitrogen and phosphorus. In this dissertation, the driving objectives were to: (1) quantitatively assess the fate of nitrogen and phosphorus (mass fluxes) at a treatment facility that employs biological nutrient removal, aerobic digestion, and sidestream recycle, (2) evaluate the performance of a microbial fuel cell (MFC) as a technology to remove nitrogen from sidestreams at a treatment plant that employs that …

Pressure Retarded Osmosis: A Potential Technology For Seawater Desalination Energy Recovery And Concentrate Management, Joshua Benjamin

USF Tampa Graduate Theses and Dissertations

Currently, a significant challenge with reverse osmosis-based desalination is reducing the energy consumption and environmental impacts of the process. This project analyzed the viability of using pressure-retarded osmosis (PRO) for energy recovery in seawater desalination facilities using brine concentrate (the draw solution) and other water sources (the feed solution) such as wastewater effluent. The primary goal of this project is to decrease the cost and overall energy consumption of seawater desalination through PRO-based energy recovery. Process modeling, statistical and sensitivity analysis, energy and cost analysis, geospatial and GIS analysis, laboratory-scale testing, water quality analysis, SEM-EDS microscopy, computational fluid dynamics (CFD), …

Resolution Of Lava Tubes With Ground Penetrating Radar, Sanaz Esmaeili

USF Tampa Graduate Theses and Dissertations

Finding habitable places to keep astronauts safe from surface radiation, magnetic storms, and temperature fluctuations will be an important component of future planetary exploration missions. Remote sensing surveys on other planets indicate the presence of lava tubes. Ground Penetrating Radar (GPR) has shown great potential for detection of tunnels in terrestrial environments. In this research, the capabilities of this near surface rapid exploratory tool for detection of lava tubes are investigated. This dissertation describes terrestrial examples of how GPR can be utilized to explore tubes and addresses the capabilities of GPR for resolving tube-related features such as the floor, fractures, …

The Photophysical Studies Of Transition Metal Polyimines Encapsulated In Metal Organic Frameworks (Mof’S), Jacob M. Mayers

USF Tampa Graduate Theses and Dissertations

Light harvesting systems provide a platform that converts solar energy into other forms of energy. One of the most common examples of photon capturing and conversion into chemical energy is observed in photosynthetic organisms in both Eurkaroyic and Prokaryotic domains. Nature provides a model for successful light harvesting platforms which includes the compartmentalization of antenna complexes that contain separated donor and acceptor pairs that participate in efficient electron transfer processes. In order to mimic such systems, crystalline porous materials that exhibits regular cavities and pore dimensions provides an excellent starting place. Metal organic frameworks (MOFs) are a class of porous …

Crystal Structure Prediction Of Materials At Extreme Conditions, Ashley S. Williams

USF Tampa Graduate Theses and Dissertations

The prediction of the structure of a crystal given only the constituent elements is one of the greatest challenges in both materials science and computational science alike. If one were to try to predict a novel crystal by brute force, meaning by arranging the atoms in every possible position of the unit cell and optimizing the geometry to find the energy minima of the potential energy surface, the amount of computer resources required to complete the calculation on the timescale of a few years would vastly exceed the currently installed computational capacity of the entire world. Fortunately, several methods have …

A System Architecture For Water Distribution Networks, Noha Abdel-Mottaleb

USF Tampa Graduate Theses and Dissertations

This dissertation examines structure-function relationships of water distribution networks (WDNs), with focus on improving the decision-making process for water utilities. WDNs are lifeline infrastructure systems, necessary for the functioning of cities. Yet water utilities around the world struggle with emerging challenges that include but are not limited to aging infrastructure components, limited budgets, increased interdependencies between infrastructure systems, increased rates of urbanization, and increasing extreme weather conditions. This is why enhancing the performance of WDNs is a priority for water utilities around the world. This research begins to delineate a system architecture for WDNs and evaluates the use of various …

Examining The Effects Of Hydrology And Reclaimed Water Application On Nutrient Retention In Wetlaculture Mesocosms In Southwest Florida, Andrew Wilson

USF Tampa Graduate Theses and Dissertations

The substantial increase among agricultural and urban land use over the past century is widely regarded as the leading cause in a variety of negative environmental impacts, particularly regarding eutrophication of both salt and fresh surface waters. Usage of both synthetic and natural fertilizers on agricultural fields and residential lawns has increased significantly in order to achieve maximum crop yield and green lawns. The nitrogen and phosphorus in these fertilizers inevitably run off the landscape and into downstream surface waters. The geographic scale of this issue makes it a challenge to overcome, as targeting specific sources/polluters is nearly impossible. Landscape-scale …

Zeros Of Harmonic Polynomials And Related Applications, Azizah Alrajhi

USF Tampa Graduate Theses and Dissertations

In this thesis, we study topics related to harmonic functions, where we are interested in the maximum number of solutions of a harmonic polynomial equation and how it is related to gravitational lensing. In Chapter 2, we study the conditions that we should have on the real or complex coefficients of a polynomial p to get the maximum number of distinct solutions for the equation p(z) − z¯ 2 = 0, where deg p = 2. In Chapter 3, we discuss the lens equation when the lens is an ellipse, a limac¸on, or a Neumann Oval. Also, we give a …

Differential Privacy For Regression Modeling In Health: An Evaluation Of Algorithms, Joseph Ficek

USF Tampa Graduate Theses and Dissertations

Background: There is a need for rigorous and standardized methods of privacy protection for shared data in the health sciences. Differential privacy is one such method that has gained much popularity due to its versatility and robustness. This study evaluates differential privacy for explanatory regression modeling in the context of health research.

Methods: Surveyed and newly proposed algorithms were evaluated with respect to the accuracy (bias and RMSE) of coefficient estimates, the empirical coverage probability of confidence intervals, and the power and type I error rates of hypothesis tests. Evaluations took place in both simulated and real data from a …