Physical Sciences and Mathematics Commons^™

Manganese Oxide Mineral Phases Produced At Room Temperature Under Acidic Conditions Investigated With Xrd, Tem, Sem, Eds, And Bet, Nancy R. Birkner

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis concerns characterization of synthetic manganese oxides belonging to mineral phases known as Birnessite and Cryptomelane. Presented here are the results of an experiment designed to examine the influence of sodium, potassium, chloride, and sulfate ions on the reduction of potassium permanganate under acidic conditions at room temperature to produce Birnessite and Cryptomelane. The experiments used KMnO4 as the source of Mn and the resulting Birnessite and Cryptomelane precipitates were washed with 18 Mn/cm NANOpure water at the end of syntheses. Several state-of-the-art solid state techniques were used to characterize the Mn-based oxide mineral phases. Based on the literature …

Democracy And The Environment In Latin America, Javier Albert Escamilla

UNLV Theses, Dissertations, Professional Papers, and Capstones

This study examines the ability of democratic and non-democratic states alike to protect the environment. Democracy has long been an important concept in the study of politics and environmental protection is an increasingly important issue in world politics. Advocates of democracy claim democratic states are better able to protect the environment than non-democracies. In contrast there are those that argue democracy's emphasis on individual rights leads to excessive resource consumption. This thesis employs a mixed methods approach to determine if democratic countries protect the environment more than their non-democratic counterparts. In short democracies do protect the environment better than non-democracies …

Going Green In The Hospitality Industry, Christina Wilson Micioni

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this research is to examine whether a hotel’s greening efforts are a reason why everyday guests or hospitality professionals choose a hotel. Do meeting planners and business travelers expect certain things while staying at a hotel? Do the personal greening activities of a guest affect their hotel stay? This will also include the housekeeping needs of the guests and why they choose the hotel. The objective of the research will be to discover whether there is guest data to support the need for hotels to become green establishments.

A Study Of Relevance Feedback In Vector Space Model, Deepthi Katta

UNLV Theses, Dissertations, Professional Papers, and Capstones

Information Retrieval is the science of searching for information or documents based on information need from a huge set of documents. It has been an active field of research since early 19^th century and different models of retrieval came in to existence to cater the information need.

This thesis starts with understanding some of the basic information retrieval models, followed by implementation of one of the most popular statistical retrieval model known as Vector Space Model. This model ranks the documents in the collection based on the similarity measure calculated between the query and the respective document. The user …

Evaluation Of Low-Temperature Fluoride Routes To Synthesize Actinide Nitrides And Oxide Solid Solutions, Gunanda Waduge Chinthaka Silva

UNLV Theses, Dissertations, Professional Papers, and Capstones

Actinide mononitrides have been considered as a possible nuclear fuel for the Generation-IV nuclear reactor systems. In the process of evaluating these actinide mononitrides as nuclear fuel, it is important to study different chemical and physical characteristics of these compounds. Synthesis of the materials is thus important. Carbothermic reduction is one of the techniques that have been used to synthesize actinide mononitrides. In this method, a mixture of actinide oxide such as UO ₂ and excess carbon is heat treated at temperatures greater than 1700 °C under a nitrogen atmosphere. The technique is however not promising in synthesizing the actinide …

The Synthesis And Systematic Evaluation Of Modified Polymeric Foams And Electrically Conductive Polyimide/Carbon/Metal Films, John Macharia Kinyanjui

UNLV Theses, Dissertations, Professional Papers, and Capstones

Thermally processed PU foams are examined as a function of processing temperatures (25, 45, 65, and 85°C) at the side, middle, and center of a simple cylindrical mold. The PU foams show both chemical and morphological differences as a function of the processing temperature and radial position within the mold. Thermal degradation of uretoneimine structures, the emergence of carbodiimide structures, and extent of reaction of isocyanate groups are measured using photoacoustic FTIR spectroscopy. Chemical gradients and morphology differences between the side, middle, and center of the molded foam are observed for all processing temperatures. The data indicate that thermal activation …

Magnetic Sensors For Biodetection, Pranjali Vineet Sneha Deshpande

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objective of thesis is to design magnetic sensor for detection of nanoparticles. Recently integrating the standard laboratory techniques into integrated system on chip is growing attention. Recent development is to combine magnetic markers and magnetoresistive sensors together in magnetic chip. In this thesis two magnetoresistive sensors were studied and designed.

By applying magnetic fields, magnetic nanoparticles can be manipulated on-chip, which can be utilized to pull the molecules to specific binding sites or to test the binding strength and distinguish between specifically and non-specifically bound molecules

Magnetoresistive sensors are compatible with the semiconductor industry which provides electronic signal directly …

The Sheep Pass Formation, A Record Of Late Cretaceous And Paleogene Extension Within The Sevier Hinterland, East-Central Nevada, Peter Alexander Druschke

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Sevier hinterland of western North America is considered by many to be an ancient proxy for the modern Andean Puna-Altiplano or Tibetan Plateau. However, controversies exist as tectonic setting and overall paleogeography of the Sevier hinterland during the Late Cretaceous and Paleogene. The Sheep Pass Formation type section within the southern Egan Range of east-central Nevada comprises a > 1 km thick sedimentary succession spanning the latest Cretaceous to Eocene, and provides a rare opportunity to test prevailing tectonic and paleogeographic models for the Sevier hinterland. New 1:12,000 scale field mapping inthe southern Egan Range indicates that up to three …

Uncertainty, Sensitivity And Geostatistical Studies Of Flow And Contaminant Transport In Heterogeneous Unsaturated Zone, Feng Pan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The objectives of this study are: (1) to develop a methodology of estimating probability density functions (PDFs) of unsaturated hydraulic parameters when field samples are sparse, (2) to evaluate the predictive uncertainties in flow and contaminant transport due to parameter uncertainties in the layer- and local-scale heterogeneities of hydraulic parameters in unsaturated zone (UZ), (3) to investigate the contributions of the parameter uncertainties to the flow and transport uncertainties, and (4) to estimate the spatial correlation structures of hydraulic parameters by incorporating prior information and site measurements.

At layer scale, the uncertainty assessment of flow and contaminant transport in UZ …

Substrate Monitoring, Contaminant Monitoring, And Educational Outreach On Quagga Mussels (Dreissena Bugensis) In Lake Mead, Nevada, Sara Ann Mueting

UNLV Theses, Dissertations, Professional Papers, and Capstones

The invasive species, the quagga mussel, Dreissena bugensis, was found in Lake Mead, Nevada-Arizona, USA on January 6, 2007. Since then, researchers have been attempting to quantify the amount of damage these mussels will cause to the lower Colorado River basin. Three projects were implemented in this thesis to research the quagga mussel in Lake Mead. First, a study to determine which types of substrates quagga mussels will grow on preferentially was conducted. Six different substrates, Acrylonitrile Butadiene Styrene (ABS) plastic, High Density Polyethylene (HDPE) plastic, Concrete Underlayment Board (CUB), aluminum, stainless steel and fiberglass, were placed in the Boulder …

The Influence Of Carbon Source Types And Nitrate On The Performance Of The Enhanced Biological Phosphorus Removal Systems, Shamim Ara Begum

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research focuses on two issues in enhanced biological phosphorus removal (EBPR). The first issue encompasses the effect of the type of carbon sources (i.e. volatile fatty acids and non volatile fatty acids) on the microbiology of EBPR. The second issue deals with the influence of denitrification on EBPR. Few studies have been performed to investigate these two issues. The recent findings on these areas are summarized below to establish the knowledge gaps this dissertation attempted to address. Details on the specific findings can be found in the literature review portion of this proposal.

A Survey Of Monge Properties, Swetha Sethumadhavan

UNLV Theses, Dissertations, Professional Papers, and Capstones

Monge properties play an important role in theoretical computer science. Many greedy algorithms are based on such properties, as is speedup in dynamic programming. Monge properties are simple monotonicity properties which are observed and used in various settings such as resource optimization, computational geometry, statistical sampling, computational biology and coding.

Turn Constrained Path Planning Problems, Victor M. Roman

UNLV Theses, Dissertations, Professional Papers, and Capstones

We consider the problem of constructing multiple disjoint paths connecting a source point s to a target point t in a geometric graph. We require that the paths do not have any sharp turn angles. We present a review of turn constrained path planning algorithms and also algorithms for constructing disjoint paths. We then combine these techniques and present an O(nlogn) time algorithm for constructing a pair of edge disjoint turn constrained paths connecting two nodes in a planar geometric graph. We also consider the development of a turn constrained shortest path map in the presence of …

Flowing Toward Sustainability: Two Stream Adjudications Analyzed Under The Iad Framework, Nancye Lou Bethurem

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the most significant problems impacting the western United States today is the lack of naturally occurring water resources, especially during this period of drought and explosive population growth. This has led to intense competition over water use and ownership in the arid and semi-arid regions of the United States. During this period of water resource scarcity, it is extremely important to determine the ownership of water rights in order to implement optimal management systems. Most western states use a system of "general stream adjudications" to make water rights ownership determinations.

General stream adjudications are legal proceedings used to …

Case Study: Feasibility Analysis Of Renewable Energy Supply Systems In A Small Grid Connected Resort, Jody Robins

UNLV Theses, Dissertations, Professional Papers, and Capstones

This paper presents a case study on the feasibility of a small grid connected resort in the marine west coast climate of Canada to implement a renewable energy supply system. The current industry conditions of three renewable energy systems are explored including small and large wind energy conversion systems, solar photovoltaic cell systems, and energy cell systems. Furthermore, these three systems are evaluated using the power load, wind, and solar radiation information from a specific resort. The renewable energy source assessment and optimization software HOMER (National Renewable Energy Laboratory, US) is used to evaluate the costs and benefits of each …

Water Quality Changes In A Constructed Wetland At The Springs Preserve In Las Vegas, Nevada, Aaron Mathis Miller

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Springs Preserve near downtown Las Vegas, Nevada contains a seven-acre constructed wetland. Springs Preserve managers are planning to use water from the constructed wetland to irrigate creeks immediately north of the wetland. These creeks will be used by a variety ofaquatic wildlife, including endangered amphibians sensitive to harmful metalloids, such as selenium, lead, and arsenic.

In an attempt to answer toxicological questions about contaminant concentrations in the constructed wetland, three metals and metalloids (selenium, arsenic, and lead), two nutrients (nitrogen and phosphorus), and the major ionic species were analyzed at four sampling locations for aqueous concentrations, in two separate …

Identifying Biomarkers For Resistance To Novel Cisplatin Analogues In Human Lung, Breast And Prostate Cancers, Becky Michelle Hess

UNLV Theses, Dissertations, Professional Papers, and Capstones

Cisplatin is a common therapeutic agent used in cancer treatment. Unfortunately, resistance to cisplatin in addition to severe side effects limits its use in cancer treatment. Two novel cisplatin analogues, 4DB and 4TB were shown to have varying cytotoxicity in lung, breast and prostate cancer cells. The hypothesis for this study states that the differences in 4DB and 4TB cytotoxicity among different tissue types is due to the type and efficiency of DNA repair mechanisms involved in response to these drugs.

To test the hypothesis, proteins involved in the rate limiting step of nucleotide excision repair (NER) and mismatch repair …

Trophic Interactions Associated With Indroduction Of The Invasive Quagga Mussel In Lake Mead, Nevada, Eric Michael Loomis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The ecology of Lake Mead is experiencing an uncertain future since the documented arrival of the invasive quagga mussel. Interactions among constituents of the food web will undoubtedly be altered over time, adversely affecting the popular sport fishery. This study is the first in Lake Mead to present historic trends in lower trophic interactions among threadfin shad and zooplankton before, and shortly after, the arrival of quagga mussels. Shad stomach content analysis revealed cladocerans and copepods were the dominant identifiable food items in Las Vegas Bay and Overton Arm of Lake Mead. Baseline energetics data through the use of stable …

Efficient Clustering Techniques For Managing Large Datasets, Vasanth Nemala

UNLV Theses, Dissertations, Professional Papers, and Capstones

The result set produced by a search engine in response to the user query is very large. It is typically the responsibility of the user to browse the result set to identify relevant documents. Many tools have been developed to assist the user to identify the most relevant documents. One such a tool is clustering technique. In this method, the closely related documents are grouped based on their contents. Hence if a document turns out to be relevant, so are the rest of the documents in the cluster. So it would be easy for a user to sift through the …

Effects Of Plant Uptake And Micro-Topography On Chloride Transport In Arid Soils, Wenming Nie

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chloride concentration profiles to depths of 1 m were evaluated on a young alluvial fan in Eldorado Valley, NV. It was found that chloride beneath plant canopies were 11 to 222 times higher than adjacent (1 - 2 m away) bare soil locations. Two-dimensional numerical simulations using HYDRUS 2D/3D model were used to further explore the impact of plants on chloride transport. The simulation results indicated that lateral flow driven by root uptake concentrated chloride toward root zones, leading to the accumulation of chloride under plant canopies. Results also suggest that locally micro-topography can have a substantial impact on chloride …

Experimental And Numerical Study Of A Proton Exchange Membrane Electrolyzer For Hydrogen Production, Sachin S. Deshmukh

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrogen as a fuel source has received attention from researchers globally due to its potential to replace fossil based fuels for energy production. Research is being performed on hydrogen production, storage and utilization methods to make its use economically feasible relative to current energy sources. The PEM electrolyzer is used to produce hydrogen and oxygen using water and electricity. Focus of our study is to provide a benchmark experiment and numerical model of a single cell electrolyzer that can assist in improving the current state of understanding of this system. Parametric analysis of an experimental cell was performed to understand …

Provenance Of The Miocene-Pliocene Muddy Creek Formation Near Mesquite, Nevada, Steven Wayne Forrester

UNLV Theses, Dissertations, Professional Papers, and Capstones

The provenance, stratigraphy, and depositional history of the Miocene-Pliocene Muddy Creek Formation (MCF) in southern Nevada are poorly studied and poorly constrained. Previous studies of the MCF have concluded that the formation consists of lacustrine, eolian, and fluvial deposits. Currently the age of deposition is loosely constrained between 8.5 and 4.1 Ma. This study documents the evolution of one portion of the eastern extent of the MCF and determines its provenance and depositional history at Flat Top and Mormon Mesas in Nevada; and near Beaver Dam and Littlefield, Arizona.

This study intended to determine whether the MCF was deposited by …

Examining The Influence Of Restaurant Green Practices On Customer Return Intention, Audrey L. Szuchnicki

UNLV Theses, Dissertations, Professional Papers, and Capstones

In recent years there has been an increased awareness of how the actions of the foodservice industry are effecting the environment. With this awareness we have begun to see a change in priorities for both new and existing businesses. At the forefront of this change in the "green" direction is the GRA who certifies how eco-friendly an establishment is based on its' environmental guidelines. This study will examine the correlation between customer return intention and the institution of green practices within a restaurant setting. The expected outcome would be that a restaurant that is certified green or, implementing measures to …

Optimization Of The Microprecipitation Procedure For Nuclear Forensics Applications, Lyndsey Renee Kelly

UNLV Theses, Dissertations, Professional Papers, and Capstones

Microprecipitation has become one of the most widely used sample preparation techniques for alpha spectroscopy. Many factors during the precipitation process can affect the yield and energy resolution by adding unwanted mass to the sample. Current applications in nuclear forensics call for an optimization of energy resolution and yield in order to improve identification and quantify specific radionuclides. The purpose of this research is to determine the optimal parameters used for microprecipitation. The optimal solution temperature, precipitation time, carrier amount, and hydrofluoric acid amount are used to investigate the influence of varying the type of carrier, as well as, the …

Substituent Effect On The Electronic And Assembling Properties Of Asymmetric Phenazine Derivatives, Bin Cao

UNLV Theses, Dissertations, Professional Papers, and Capstones

Currently, one-dimensional (1-D) nanostructures have drawn much interest because of their potential applications for nanoscale optoelectronic devices. Self-assembly (SA) based on π-conjugated systems through various intermolecular interactions has been widely used to produce 1-D nanostructure. Morphology of the assembled structures can be modified by incorporating substituents, which provide additional secondary interactions. Meanwhile, those substituents also influence the electronic properties of the molecules. Previous studies have made little effort to systematically study subsistent effects on both electronic and SA properties.

The primary objective of this research is to generate controllable 1-D structures through SA, and to provide a fundamental understanding of …

Water Use And Natural Limits In The Las Vegas Valley: A History Of The Southern Nevada Water Authority, Christian Harrison

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis examines the history of the Southern Nevada Water Authority (SNWA) and how it has helped transform various aspects of southern Nevada's economy and environment. Prior to the establishment of the SNWA in 1991 the Las Vegas Metropolitan Area (LVMA) possessed several competing water providers whose opposition to one another adversely affected the management of water in the region. These water providers recognized this problem, came together, and negotiated the creation of a regional water agency, the SNWA. This organization, comprised of representatives from each of the LVMA's water providers has the power to institute policy across municipal boundaries. …

Controlled Functionalization Of Crystalline Polyolefins And Their Application In Soluble Polymer Support, Jihoon Shin

UNLV Theses, Dissertations, Professional Papers, and Capstones

Functionalization of polyolefins has been recognized as a useful methodology for the generation of new materials with a wide range of applications. Recently, crystalline or semi-crystalline polyolefins have drawn increasing attention in both industrial and academic fields as one of the most interesting engineering plastics, due to their remarkable physical and mechanical properties. This dissertation describes: (1) novel methods for the direct postfunctionalization of crystalline polyolefins to introduce functionality, (2) characterizations for the functionalized polymers to analyze their structures, molecular-weight properties, thermal properties, and hydrophilicity, and (3) an application of the modified crystalline polystyrene as a soluble polymer support for …

Parametric Study Of Efficiency Measures For Home Energy Conservation In Las Vegas, Nevada, Todd M. France

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pulte Homes, a production home builder and community developer partnering with the U.S. Department of Energy's Building America program, has collaborated with the Center for Energy Research at the University of Nevada, Las Vegas and NV Energy, the local electric utility, on an energy conservation project in the Las Vegas Valley.

This study entails four model homes at a new development in the Summerlin community of Las Vegas, Nevada, named Villa Trieste. The home models, ranging in floor plan area from 1,487 to 1,777 square feet, have been constructed under the Environments for Living program and are LEED (Leadership in …

Statistical Inferences For Functions Of Parameters Of Several Pareto And Exponential Populations With Application In Data Traffic, Sumith Gunasekera

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this dissertation, we discuss the usability and applicability of three statistical inferential frameworks--namely, the Classical Method, which is sometimes referred to as the Conventional or the Frequentist Method, based on the approximate large sample approach, the Generalized Variable Method based on the exact generalized p -value approach, and the Bayesian Method based on prior densities--for solving existing problems in the area of parametric estimation. These inference procedures are discussed through Pareto and exponential distributions that are widely used to model positive random variables relevant to social, scientific, actuarial, insurance, finance, investments, banking, and many other types of observable phenomena. …

Zirconia-Magnesia Inert Matrix Fuel And Waste Form: Synthesis, Characterization And Chemical Performance In An Advanced Fuel Cycle, Kiel Steven Holliday

UNLV Theses, Dissertations, Professional Papers, and Capstones

There is a significant buildup in plutonium stockpiles throughout the world, because of spent nuclear fuel and the dismantling of weapons. The radiotoxicity of this material and proliferation risk has led to a desire for destroying excess plutonium. To do this effectively, it must be fissioned in a reactor as part of a uranium free fuel to eliminate the generation of more plutonium. This requires an inert matrix to volumetrically dilute the fissile plutonium. Zirconia-magnesia dual phase ceramic has been demonstrated to be a favorable material for this task. It is neutron transparent, zirconia is chemically robust, magnesia has good …