Physical Sciences and Mathematics Commons^™

Evaluation Of Extraction Chromatography Resins For Rapid Actinide Analysis, Julie Marisa Gostic

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this work, physical and chemical parameters associated with extraction chromatography separation procedures were investigated for rapid actinide analysis. A vacuum box system was designed in-house and was characterized in terms of flow rate reproducibility, matrix effects on flow rate for sequential elution, and actinide separation efficiency using different types of resin (TEVA, DGA and TRU). Results indicated that the columnar kinetics of the resins were sufficiently rapid to run high purity samples through the unit over a wide range of flow rates for all resin types. Single matrix interferences at a metal ion ratio of 1:10 6 relative to …

Optimization Of Solid Oxide Fuel Cell Interconnect Design, Krishna C. Pulagam

UNLV Theses, Dissertations, Professional Papers, and Capstones

Performance of solid oxide fuel cells (SOFC) is dependent of a set of complex physical and chemical processes occurring simultaneously. Interconnect for SOFC is important as it provides electrical connection between anode of one individual cell to the cathode of neighboring one. It also acts as a physical barrier to protect the air electrode material from the reducing environment of the fuel on the fuel electrode side, and it equally prevents the fuel electrode material from contacting with oxidizing atmosphere of the oxidant electrode side. A three-dimensional numerical model has been developed to evaluate the SOFC including the current collector, …

Experimental And Numerical Study Of A Proton Exchange Membrane Electrolyzer For Hydrogen Production, Sachin S. Deshmukh

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrogen as a fuel source has received attention from researchers globally due to its potential to replace fossil based fuels for energy production. Research is being performed on hydrogen production, storage and utilization methods to make its use economically feasible relative to current energy sources. The PEM electrolyzer is used to produce hydrogen and oxygen using water and electricity. Focus of our study is to provide a benchmark experiment and numerical model of a single cell electrolyzer that can assist in improving the current state of understanding of this system. Parametric analysis of an experimental cell was performed to understand …

Geoelectrical Response Of Surfactant Solutions In A Quartzitic Sand Analog Aquifer, Meghan Therese Magill

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this project, the resistivity and phase shift of ten surfactant aqueous solutions in a sand matrix were measured using spectral induced polarization (SIP). In addition, specific conductivity, pH, dissolved oxygen, and dielectric constant measurements of the solutions were also evaluated. The frequency range assessed was 0.091-12000Hz. The surfactants, which are typically used in the remediation of tetrachloroethylene, were Aerosol MA 80-I, Dowfax 8390, and Steol CS-330. The surfactants were mixed into solutions of both deionized and tap water at varying concentrations and injected into a closed system of silica sand. The surfactant treatments altered resistivity, specific conductivity, and pH …

Ac Susceptibility And Heat Capacity Studies Of The Geometrically Frustrated Pyrochlores Terbium Titanium Tin Oxides And Holmium Titanates, Daniel Antonio

UNLV Theses, Dissertations, Professional Papers, and Capstones

Materials with a geometrically frustrated magnetic pyrochlore lattice have been of interest due to their unusual ground states. Tb 2 Ti 2 O 7 is known for having a spin liquid ground state which does not transition to a long-range ordered state down to at least 50 mK. Ho 2 Ti 2 O 7 has a macroscopically degenerate spin ice ground state which resembles that of the proton ordering in water ice. Heat Capacity measurements of Tb 2 Ti 2- x Sn x O 7 were done down to 0.36 K and AC magnetic susceptibility measurements of Ho 2- x …

Characterization Of Iron Oxide Thin Films For Photoelectrochemical Hydrogen Production, Kyle Eustace Nelson George

UNLV Theses, Dissertations, Professional Papers, and Capstones

Solar energy is the most sustainable source of energy available. However, solar applications such as photovoltaic cells represent only a partial solution to weaning our dependence upon fossil fuels. Several methods of storing solar energy are currently being pursued, and chemical storage stands out as a promising option - combining design simplicity with high energy density, with hydrogen being particularly attractive because of its abundance and inherently clean nature. A monolithic Photoelectrochemical (PEC) device that produces hydrogen by electrolyzing water directly from sunlight has the benefit of utilizing "free" solar energy to drive the reaction.

Although α-Fe 2 O 3 …

Static High Pressure Ft-Ir Spectroscopic Studies Of Tatb, Brian F. Yulga

UNLV Theses, Dissertations, Professional Papers, and Capstones

Static high-pressure experiments utilizing diamond anvil cells (DACs) provide an alternative method to shockwave studies for extracting precise information on the physical and chemical properties of energetic materials. Due to mechanical restraints (e.g. small sample sizes and apertures), synchrotron radiation sources are ideal for probing the structure of materials at the molecular level. 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) is an insensitive (tertiary) high explosive (iHE) useful in military applications. Compared to other conventional iHEs, it is a safer and more stable energetic material. Its unique properties cause it to be of interest in the energetic materials research community. A series of Fourier-transform infrared …

Optimization Of The Microprecipitation Procedure For Nuclear Forensics Applications, Lyndsey Renee Kelly

UNLV Theses, Dissertations, Professional Papers, and Capstones

Microprecipitation has become one of the most widely used sample preparation techniques for alpha spectroscopy. Many factors during the precipitation process can affect the yield and energy resolution by adding unwanted mass to the sample. Current applications in nuclear forensics call for an optimization of energy resolution and yield in order to improve identification and quantify specific radionuclides. The purpose of this research is to determine the optimal parameters used for microprecipitation. The optimal solution temperature, precipitation time, carrier amount, and hydrofluoric acid amount are used to investigate the influence of varying the type of carrier, as well as, the …

Analytical Method Development For Determination Of Volatile Organic Compounds In Calcareous Desert Soil, Mary F. Turner

UNLV Theses, Dissertations, Professional Papers, and Capstones

Soil sample preservation for volatile organic compound analysis generally requires short sample holding times or preservation of the sample's chemical constituents with sodium bisulfate (NaHSO 4 ). Calcareous soils cannot be preserved using NaHSO4 because effervescence will promote the loss of analytes, and short holding times before analysis are not practical for remote sampling locations. An experimental approach was developed for determination of volatile organic compounds (VOCs) in soil that utilizes solid sorbents for sample preservation and solid-phase microextraction (SPME) sample preparation technique coupled with gas chromatography/mass spectrometry (GC/MS) for analysis. Solid sorbents are used to sequester readily extractable (vapor …

Systematic Analysis Of Identifying Key Dimensions Of Environmentally And Socially Responsible Hotels, Courtney Suess

UNLV Theses, Dissertations, Professional Papers, and Capstones

Development in Southeast Asia involves making good decisions for the future, so the idea that good planning can ignore sustainability is something of an oxymoron. Good development has to be sustainable and we have reached a point where the old ways of tourism development are intolerable. For example, hotels spring up without planning for the future. This short sightedness means natural endowments, like coastlines, erode and forests are cut down, chasing away the wildlife; or cultural history in the form of temples, historic buildings, and sacred places are destroyed. Ironically, tourism development is eradicating the very forms of product that …

Parametric Study Of Efficiency Measures For Home Energy Conservation In Las Vegas, Nevada, Todd M. France

UNLV Theses, Dissertations, Professional Papers, and Capstones

Pulte Homes, a production home builder and community developer partnering with the U.S. Department of Energy's Building America program, has collaborated with the Center for Energy Research at the University of Nevada, Las Vegas and NV Energy, the local electric utility, on an energy conservation project in the Las Vegas Valley.

This study entails four model homes at a new development in the Summerlin community of Las Vegas, Nevada, named Villa Trieste. The home models, ranging in floor plan area from 1,487 to 1,777 square feet, have been constructed under the Environments for Living program and are LEED (Leadership in …

Water Use And Natural Limits In The Las Vegas Valley: A History Of The Southern Nevada Water Authority, Christian Harrison

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis examines the history of the Southern Nevada Water Authority (SNWA) and how it has helped transform various aspects of southern Nevada's economy and environment. Prior to the establishment of the SNWA in 1991 the Las Vegas Metropolitan Area (LVMA) possessed several competing water providers whose opposition to one another adversely affected the management of water in the region. These water providers recognized this problem, came together, and negotiated the creation of a regional water agency, the SNWA. This organization, comprised of representatives from each of the LVMA's water providers has the power to institute policy across municipal boundaries. …

Effects Of Plant Uptake And Micro-Topography On Chloride Transport In Arid Soils, Wenming Nie

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chloride concentration profiles to depths of 1 m were evaluated on a young alluvial fan in Eldorado Valley, NV. It was found that chloride beneath plant canopies were 11 to 222 times higher than adjacent (1 - 2 m away) bare soil locations. Two-dimensional numerical simulations using HYDRUS 2D/3D model were used to further explore the impact of plants on chloride transport. The simulation results indicated that lateral flow driven by root uptake concentrated chloride toward root zones, leading to the accumulation of chloride under plant canopies. Results also suggest that locally micro-topography can have a substantial impact on chloride …

Study Of Corrosion Of Materials In The Sulfur-Iodine Hydrogen Production Cycle, Thao Trung Ho

UNLV Theses, Dissertations, Professional Papers, and Capstones

Hydrogen is of great interest since the availability of traditional fossil fuels is in decline. Strictly speaking, hydrogen is not a primary source of energy but is an energy carrier, since energy typically must be used from another source (electricity, natural gas, coal, etc.) to produce it. Of hydrogen production techniques, the Sulfur-Iodine thermochemical water splitting process (S-I cycle), which was proposed by General Atomics (GA), is promising with its simplicity and high efficiency. Most of the chemicals are recycled except water. However, the S-I cycle operates in a harsh, corrosive environment in the presence of a mixture of iodine …

High Pressure Phase Transistions In The Lanthanide Sesquioxides, Jason Patrick Mcclure

UNLV Theses, Dissertations, Professional Papers, and Capstones

Crystallizing into 5 known polymorphic forms, the rare-Earth sesquioxides RE 2 O 3 represent a family of 4-f electron compounds that have been the subject of study for many years. Aspects of the systematics in the structural phase transitions for RE 2 O 3 (RE=La, Sm, Eu, Gd, Y, Er, Yb, Lu) under pressure were studied using diamond anvil cells (DACs). As a part of this study, detailed equation of state (EOS) data for all these compounds were obtained through the use of angle-dispersive x-ray diffraction (XRD) where anomalies in compression data led to the detailed investigation into one particular …

Spectroscopic Investigation Of Palladium-Copper Bimetallic Systems For Pem Fuel Cell Catalysts, Timo Hofmann

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the main barriers to commercialization of polymer electrolyte membrane fuel cells systems is cost, which is largely due to the need of platinum (Pt)-containing catalysts. In this thesis we investigate bimetallic systems consisting of a base metal (copper) and a noble metal (palladium) that, as an alloy on the nanoscale, mimic the electronic properties that make Pt desirable as a catalyst.

We present a detailed investigation of the electronic structure of carbon-supported Pd/Cu nanoparticle catalysts, model bilayer thin film systems, alloys, and various metal reference samples. We have investigated the valence band structure of the catalysts using a …

Provenance Of The Miocene-Pliocene Muddy Creek Formation Near Mesquite, Nevada, Steven Wayne Forrester

UNLV Theses, Dissertations, Professional Papers, and Capstones

The provenance, stratigraphy, and depositional history of the Miocene-Pliocene Muddy Creek Formation (MCF) in southern Nevada are poorly studied and poorly constrained. Previous studies of the MCF have concluded that the formation consists of lacustrine, eolian, and fluvial deposits. Currently the age of deposition is loosely constrained between 8.5 and 4.1 Ma. This study documents the evolution of one portion of the eastern extent of the MCF and determines its provenance and depositional history at Flat Top and Mormon Mesas in Nevada; and near Beaver Dam and Littlefield, Arizona.

This study intended to determine whether the MCF was deposited by …

Empirically Derived Formulas To Predict Indoor Maximum, Average, And Minimum Temperatures In Roofpond Buildings Using Minimum Climatic Information, Ibrahim Kivarkis Kako

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis introduces an empirically developed formula to predict the comfort conditions and thermal performance of a Skytherm(TM) Southwest Roofpond placed over a light-weight un-insulated structure built at the School of Architecture at the University of Nevada, Las Vegas.

The predictive formula introduced in this study may be used in different parts of the world (particularly developing nations where insulation and air-conditioning are rarely used) to predict the performance of a Skytherm(TM) Southwest Roofpond using minimal climate data.

The data collected in the experimental setup at the Natural Energies Advanced Technologies Laboratory included outside and inside temperatures of various surfaces …

Mineralogy And Micromorphology Of An Atacama Desert Soil, Chile: A Model For Hyperarid Pedogenesis, Michael S. Howell

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Atacama Desert is the oldest and driest desert on Earth. Hyperarid soils in this desert are dominated by rare (or exclusive) salt minerals and assemblages. Previous research details salt origins and abundance, however pedogenic processes involved in salt distribution are not adequately explained. Therefore, the main goal of this investigation was to identify and document evidence for hyperarid pedogenesis (via salt mineralogy and soil micromorphology) at a field site, Oficina Ercilla, located ~80 km northeast of Antofagasta, Chile within the Central Depression and hyperarid core of the Atacama Desert. This study presents an interpretational model for hyperarid pedogenesis, which …

Sequence And Chemostratigraphic Study Across The Basal Eureka Quartzite Unconformity In The Great Basin, Nevada: Implications For The Origin Of The Late Ordovician Carbon Isotope Excursion, Apostolos Paul Kosmidis

UNLV Theses, Dissertations, Professional Papers, and Capstones

The positive carbon isotope (δ 13 C) excursion from the late Middle Ordovician Copenhagen Formation that underlies the Eureka Quartzite in central Nevada has been hypothesized to record a global cooling event ∼10 Myr prior to the well-recognized Late Ordovician Hirnantian glaciation (∼443 Ma). However, direct evidence for pre-Hirnantian continental glaciation remains scarce, raising uncertainties in the relationship between the inferred eustatic sea-level fall and the origin of the positive δ 13 C excursion. Additionally, previous stratigraphic studies from southern Nevada and California suggest relative sea-level fall in excess of ∼ 150 meters, which exceeds estimates for younger glacial periods …

Effects Of Similarity Metrics On Document Clustering, Rushikesh Veni

UNLV Theses, Dissertations, Professional Papers, and Capstones

Document clustering or unsupervised document classification is an automated process of grouping documents with similar content. A typical technique uses a similarity function to compare documents. In the literature, many similarity functions such as dot product or cosine measures are proposed for the comparison operator.

For the thesis, we evaluate the effects a similarity function may have on clustering. We start by representing a document and a query, both as a vector of high-dimensional space corresponding to the keywords followed by using an appropriate distance measure in k-means to compute similarity between the document vector and the query vector to …

Bending Of Woody Riparian Vegetation As A Function Of Hydraulic Flow Conditions, John O. Goreham

UNLV Theses, Dissertations, Professional Papers, and Capstones

Vegetation encroachment reduces channel conveyance capacity below design objectives and greatly increases the risk for loss of life and property damage in the case of large flood events. Given minimal knowledge of hydraulic roughness for shrubs and woody vegetation, accurate estimation of channel capacity and water surface elevation is difficult. The ability to predict a tree's bent, reduced height in the presence of flow permits more accurate prediction of hydraulic roughness and water surface elevation.

In this study, field tests were performed to elucidate tree bending properties, which in turn served as input parameters for a numerical algorithm designed to …

Hierarchical Routing In Manets Using Simple Clustering, Adam Carnine

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis presents both a review of current MANET routing protocols and a new MANET routing algorithm. The routing protocols reviewed include representative samples from the three primary forms of routing found in MANETS: proactive routing, reactive routing and hybrid routing. Secure algorithms are given special treatment in the review. In addition several protocol enhancements are discussed.

The proposed routing protocol is designed to support networks of a medium size, containing over 200 nodes but less than 3,000 nodes. The design is intentionally simple to allow ease of implementation in comparison with other MANET protocols that provide similar functionality.

Examining The Influence Of Restaurant Green Practices On Customer Return Intention, Audrey L. Szuchnicki

UNLV Theses, Dissertations, Professional Papers, and Capstones

In recent years there has been an increased awareness of how the actions of the foodservice industry are effecting the environment. With this awareness we have begun to see a change in priorities for both new and existing businesses. At the forefront of this change in the "green" direction is the GRA who certifies how eco-friendly an establishment is based on its' environmental guidelines. This study will examine the correlation between customer return intention and the institution of green practices within a restaurant setting. The expected outcome would be that a restaurant that is certified green or, implementing measures to …