Physical Sciences and Mathematics Commons^™

Distribution And Impacts Of Petroleum Hydrocarbons In Louisiana Tidal Marsh Sediments Following The Deepwater Horizon Oil Spill, Rachel S. Hatch

Theses and Dissertations--Earth and Environmental Sciences

Following the 2010 Deepwater Horizon (DWH) spill, sediment cores were analyzed from marshes at various levels of oiling to determine how deeply oil penetrated sediment in these marsh environments, and if at these sites it had quantifiably affected benthic ecosystems. Minimum mixing depths were determined from penetration of the lithogenic radionuclide ²³⁴Th, which ranged from 0.25 to 4.5 cm. Sediment accumulation rates were determined using ²¹⁰Pb, with verification from ¹³⁷Cs in selected cores. Lead-210 profiles revealed long-term (decadal) mixing. Bay Jimmy, Louisiana was significantly affected by the DWH oil spill, as indicated by total polycyclic aromatic hydrocarbon …

Shear-Wave Imaging And Birefringence In A Complex Near-Surface Geological Environment, Ali Z. Almayahi

Theses and Dissertations--Earth and Environmental Sciences

Multiple geophysical and geological data sets were compiled, reprocessed, and interpreted using state-of-the-art signal processing and modeling algorithms to characterize the complex post-Paleozoic geology that overlies the southwestern projection of the Fluorspar Area Fault Complex (FAFC) in western Kentucky. Specific data included 21.5 km of SH-wave seismic reflection, 1.5 km of P-wave seismic reflection, 2 km of electrical resistivity, vertical seismic profiles, Vp and Vs sonic-suspension logs, and 930 lithologic borehole logs. The resultant model indicates three general northeast–southwest-oriented fault zones pass through the study area as southwestern extensions of parts of the FAFC. These fault zones form two significant …

Thermobarometry Of Metamorphosed Pseudotachylyte And Determination Of Seismic Rupture Depth During Devonian Caledonian Extension, North Norway, Susan E. Leib

Theses and Dissertations--Earth and Environmental Sciences

Crustal faulting has long been known as the source of shallow seismicity, and the seismogenic zone is the depth (3-15 km) within the crust that is capable of co-seismic slip, largely under brittle conditions. However, some continental seismicity occurs at depths >> 15 km. I performed thermobarometry of mylonitic pseudotachylyte to determine the P-T of a seismogenic extensional fault in the Caledonian Norwegian margin. Two shear zones (Eidsfjord and Fiskfjord) located in northern Norway exhibit brittle extension propagating into the ductile regime of the lower crust as evidenced by the presence of pseudotachylyte. Averages from Eidsfjord (653 ± 38°C and 570 …

Modeling Of Co2-Water-Rock Interactions In A Mississippian Sandstone Reservoir Of Kentucky, Anne M. Schumacher

Theses and Dissertations--Earth and Environmental Sciences

This study examined CO₂-water-rock interactions occurring during a carbon sequestration pilot test into a Mississippian oil reservoir in western Kentucky. New samples (n=62) and archived data, both collected from oil wells, were used to characterize the chemistry of formation waters from the Sugar Creek field in Hopkins County. In addition, core and cuttings samples (n=17) from the reservoir and overlying cap-rocks in, or near, the field were analyzed for bulk and clay mineralogy using X-ray diffraction. Electric logs were used to select sample intervals within the overlying cap-rocks and the center of the producing zones in the Jackson …

Spatio-Temporal Variability In Groundwater Discharge And Contaminant Fluxes Along A Channelized Stream In Western Kentucky, Ganesh N. Tripathi

Theses and Dissertations--Earth and Environmental Sciences

Spatio-temporal variability in groundwater discharge and contaminant fluxes along a channelized stream in western Kentucky

Surface and groundwater discharges and contaminant fluxes can vary with time and space depending upon the hydrogeological processes and geological setting of the area of interest. This study examined a ~300-m-long, channelized reach of a first-order perennial stream, Little Bayou Creek, in the Coastal Plain of far western Kentucky during the period October 2010–February 2012. Along the study reach, springs discharge groundwater contaminated by the chlorinated organic compound trichloroethene (TCE) and radionuclide technetium-99 (⁹⁹Tc) released as a result of past activities at the …

The Evolution Of Grenville Basement In The Eastern Great Smoky Mountains; Constraints From U-Pb Zircon Geochronology, Whole Rock Sm-Nd, And Feldspar Pb Geochemistry, Ryan Joel Quinn

Theses and Dissertations--Earth and Environmental Sciences

Identifying the crustal affinity of Grenville basement rocks in the Dellwood quadrangle, western NC, provides insight into the tectonic evolution of eastern Laurentia during Grenville orogenesis. U-Pb zircon geochronology of orthogneiss, augen gneiss, and mafic xenoliths in orthogneiss reveal magmatic pulses at 1130, 1180, and 1330 Ma and metamorphic episodes at 450 and 1040 Ma. Xenoliths in 1330 Ma orthogneiss are as old as 1382 Ma and represent the oldest component of Blue Ridge basement identified to-date. Feldspar Pb isotope values span a range between juvenile-Laurentian and southern-central Appalachian basement/Amazonia. Most Pb isotope data define an array consistent with crustal …

Integrated Geophysical Investigation Of Karst Features – Inner Bluegrass Region Of Kentucky, Jamin C. Frommel

Theses and Dissertations--Earth and Environmental Sciences

High-resolution electrical-resistivity, seismic-refraction, and seismic-reflection surveys were performed at three locations in the Inner Bluegrass Region of Kentucky along coincident survey lines in order to correlate results and determine which method is most effective at locating karst features in this area. The first two survey locations at Slack’s Cave and the Kentucky Horse Park were chosen in order to investigate known karst features. High and low electrical-resistivity anomalies were correlated to air- and water-filled karst voids, respectively. Seismic velocity anomalies, including parabolic time suppressions, amplitude terminations, and surface-wave backscatters, were also observed and correlated to these karst voids. These findings …

Geothermobarometric Analysis And Tectonic Evolution Of The Liverpool Land Eclogites, East Greenland Caledonides, Gabriel E. Richarde

Theses and Dissertations--Earth and Environmental Sciences

Mineral chemistry and thermobarometry of mafic pods in the Liverpool Land Eclogite Terrane (LLET) provide insight into potential relationships with regional high-pressure (HP) and ultrahigh-pressure (UHP) terranes such as the North East Greenland Eclogite Province (NEGEP), the Western Gneiss Region (WGR), and HP granulites in the East Greenland Caledonides at Payer Land. Grt-cpx thermometry and jadeite barometry performed on garnet and omphacite cores in a sequence of retrogressed eclogites give minimum and average P-T values across six samples for eclogite at 18.4 ± 3.7 kbar at 764 ± 156 °C. Granulite facies conditions based on early retrograde Opx-Plag symplectites, garnet …

Sh-Wave Refraction And Reflection Investigation Of Quaternary Geology―Central United States Seismic Observatory, Carrington L. Wright

Theses and Dissertations--Earth and Environmental Sciences

The Central United States Seismic Observatory (CUSSO) consists of an array of vertical strong motion accelerometers and medium period seismometers that penetrate 585 m into the Mississippi Embayment sediments and terminates into Paleozoic bedrock. The array is located in the New Madrid Seismic Zone within the upper embayment. The thick unconsolidated Quaternary sediments have the potential to influence strong motions; understanding how these sediments affect ground motion is the goal of the CUSSO array. Nine SH-wave refraction and five P-wave common midpoint reflection surveys were collected within a 1 km radius around the CUSSO borehole in order to characterize the …

Geology Of The Eau Claire Formation And Conasauga Group In Part Of Kentucky And Analysis Of Their Suitability As Caprocks For Deeper Co2 Sequestration, Ralph E. Bandy Iii

Theses and Dissertations--Earth and Environmental Sciences

Carbon sequestration, or carbon capture and storage (CCS), is the process of capturing anthropogenically generated CO₂, transporting the CO₂ to an injection site, and then injecting the CO₂ into suitable reservoirs for long-term storage, or sequestration. Integral to the successful sequestration of CO₂ is an understanding of the confining intervals (seals) above potential reservoirs. The purpose of this thesis research was to perform a detailed geological study of the Eau Claire Formation and equivalent parts of the Conasauga Group in part of the Ohio River Valley region in order to better evaluate its suitability as …

Chemical Evolution And Residence Time Of Groundwater In The Wilcox Aquifer Of The Northern Gulf Coastal Plain, Estifanos Haile

Theses and Dissertations--Earth and Environmental Sciences

This study aims to integrate groundwater geochemistry and mathematical modeling to determine the dominant geochemical processes and groundwater residence time within the Wilcox aquifer in the northern Gulf Coastal Plain. Groundwater samples were collected and analyzed for major ion chemistry, stable isotopes (¹⁸O, ²H, and ¹³C), and radioisotope ³⁶Cl content. Geochemical modeling enabled the identification of major sources and sinks of solutes in the aquifer. A two-dimensional, finite-difference, numerical model was used to determine the deep groundwater flow rate and transport of ³⁶Cl in the aquifer. Major ion chemistry shows a chromatographic pattern along …

Bedrock Geology And Tectonic Evolution Of The Western Central Maine Zone, South Central Massachusetts, Thomas Bradley Walker

Theses and Dissertations--Earth and Environmental Sciences

Bedrock geology of the East Brookfield quadrangle (EBQ), based on new 1:24000 scale mapping, consists of an interfolded sequence of Rangeley Fm. and Paxton Fm. metasediments, intruded by Early Mississippian tonalitic to granitic orthogneisses and underlain in the western half by folded orthogneisses of unknown age. Pervasive flattening strains have created planar, generally NNE-SSW striking and consistent moderately west dipping foliations. Generally strike-parallel stretching lineations and boudinage structures, with rarer dip parallel stretching lineations, reflect extrusion of CMZ metasediments and orthogneisses with a flattening component. Mapping in the EBQ demonstrates that a transition between deformational mechanisms of the southern Central …

Arsenic Heterogeneity In Aquifer Sediments From West Bengal, India, Emily Eastridge

Theses and Dissertations--Earth and Environmental Sciences

Multiple studies in the Bengal basin have shown that elevated As in groundwater coincides with reduced, relatively dark sediments of Himalayan provenance. In West Bengal state (India), As concentrations > 10 μg/L tend to occur east of the River Bhagirathi-Hoogly, the main distributary of the Ganges. Associations among sediment chemistry and mineralogy for four cores from either side of the Bhagirathi-Hoogly (cores 1 and 2 to the east, 3 and 4 to the west) in Murshidabad district were investigated. Ten sediment samples were collected from each boring at various depths to a maximum of 38 to 43 m. Sediment chemistry was …

Locating Hot Spots Of Fecal Pollution In An Urban Watershed Of Central Kentucky Using Bacteroides 16s Rrna Markers, Tricia L. Coakley

Theses and Dissertations--Earth and Environmental Sciences

The field of molecular fecal source tracking in the water environment has developed rapidly since the first PCR assays for general and host-­‐specific Bacteroides 16s rRNA markers were published. Numerous host-­‐specific molecular markers and PCR assays have been developed, adding greater specificity, sensitivity and quantitative methods to the array of options. The public demand for readying methods for transfer to the commercial lab, so that they may be used to generate data for public utilities, citizen action groups and regulatory agencies, has fueled the development of an entire new research community. These methods, however plentiful, have not found community agreement …

Depositional Environments And Petrology Of The Felix Coal Interval (Eocene), Powder River Basin, Wyoming, Peter D. Warwick

Theses and Dissertations--Earth and Environmental Sciences

A study of a 250 ft. (76.2 m) stratigraphic interval that includes the Eocene-age Felix coal of the Wasatch Formation was undertaken in the Powder River Basin of Wyoming to establish a depositional model based on the interrelations of coal-seam geometry, coal maceral composition, and spatial distribution of adjoining rocks. Regional cross sections and maps of major rock bodies were prepared from 147 measured stratigraphic sections and 56 geophysical logs. Trends in maceral and chemical properties within the Felix coal were identified from petrographic and geochemical analyses of 72 coal channel samples. The combined data sets indicate that the thickest …