Physical Sciences and Mathematics Commons^™

Groundwater Flow Across The Coyote Wash Fault And Cedar Mesa Anticline Near St. Johns, Arizona, Stephanie Lynn Latour

Theses and Dissertations

As the demand for water increases across the southwestern United States, the region's utilization of and dependence on water stored in groundwater aquifers has risen in kind. The Coconino Aquifer (C-aquifer) underlies much of the southwestern Colorado Plateau and is a primary source of groundwater in northeastern Arizona. One of the largest commercial users of water from the C-aquifer in Apache County, Arizona, is Springerville Generating Station, a coal-fired power plant owned and operated by Tucson Electric Power. The area surrounding the power plant, located between the cities of Springerville and St. Johns, Arizona (the Springerville-St. Johns area), is geologically …

Common Ground Over Common Water: Defining The Public Interest In The Milwaukee Watershed, Thomas Anthony Gentine

Theses and Dissertations

My dissertation examines government and nongovernment entities’ attempts to restore and protect the use and health of the Milwaukee River and its watershed from 1960 to 2000. Under Mayor Henry Maier’s leadership, Milwaukee worked to reclaim the urban riverway to stimulate economic growth. However, state and federal representatives, after the passage of the 1965 Water Quality Act, demanded that the city government prioritize updating the combined storm and sewer system to lessen pollution in the Milwaukee River. At the same time, other groups worked to save rural areas from unplanned development and further degradation of the waterway. Influential groups included …

Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik

Theses and Dissertations

Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …

Carbonatite Metasomatism And Water Systematics Of Peridotite Xenoliths From Lanzarote, Canaries, Sierra N. Patterson

Theses and Dissertations

Water in Earth’s mantle, present as structurally bound hydrogen in minerals, influences large scale processes like mantle deformation, plate tectonics, and melting. To better understand the processes controlling water concentrations in the Earth’s upper mantle, we analyzed hydrogen (calculated as ppm wt. H₂O), major, and trace element concentrations in minerals from peridotite mantle xenoliths of Lanzarote, Canaries. The Canaries Islands are thought to be the surface expression of a deep-seated mantle plume erupting through the Atlantic Ocean lithosphere. Carbonatite magmas have erupted in the Canaries and previous studies have shown evidence for carbonatite metasomatism in Lanzarote peridotites. Thus, …

Fate Of Persistent Contaminants And Emerging Algal Toxins In Drinking Water And The Environment, Danielle Christine Westerman

Theses and Dissertations

Population growth and global climate change has resulted in the degradation of pristine water sources, causing issues like saltwater intrusion, persistent harmful algal blooms, and drought from population growth. Future reliance on alternative sources of drinking water to is expected globally, therefore, nontraditional sources of drinking water are becoming increasingly vital sources of potable water around the world. For example, desalination (typically by reverse osmosis), despite its high energy demands and high cost, is being utilized all over the world to meet drinking water demand. Wastewater reuse, the additional treatment of wastewater to produce drinking water, either directly or indirectly, …

Water Systematics Of Samoan Peridotite Xenoliths, Aaron Wolfgang Ashley

Theses and Dissertations

Water influences geodynamic processes such as melting, deformation and rheology. Yet its distribution in the oceanic upper mantle is primarily known indirectly from melt inclusions and glasses of erupted mantle melts (i.e. MORB and OIB). To constrain the mechanisms influencing the distribution of water in the mantle, we analyzed 15 peridotite xenoliths from Savaiʻi and 2 dunite xenoliths from Taʻū (Samoa) for water concentrations (by polarized FTIR) and major/trace elements. Savaiʻi peridotites are among the most melt depleted oceanic xenoliths recovered (degrees of melt depletion ≥15%). They show strong evidence of transient metasomatism by both carbonatite and silicate melts, with …

Toward Real-Time Flip Fluid Simulation Through Machine Learning Approximations, Javid Kennon Pack

Theses and Dissertations

Fluids in computer generated imagery can add an impressive amount of realism to a scene, but are particularly time-consuming to simulate. In an attempt to run fluid simulations in real-time, recent efforts have attempted to simulate fluids by using machine learning techniques to approximate the movement of fluids. We explore utilizing machine learning to simulate fluids while also integrating the Fluid-Implicit-Particle (FLIP) simulation method into machine learning fluid simulation approaches.

Adaptive Fluid Simulation Using A Linear Octree Structure, Sean A. Flynn

Theses and Dissertations

An Eulerian approach to fluid flow provides an efficient, stable paradigm for realistic fluid simulation. However, its traditional reliance on a fixed-resolution grid is not ideal for simulations that simultaneously exhibit both large and small-scale fluid phenomena. Octree-based fluid simulation approaches have provided the needed adaptivity, but the inherent weakness of a pointer-based tree structure has limited their effectiveness. We present a linear octree structure that provides a significant runtime speedup using these octree-based simulation algorithms. As memory prices continue to decline, we leverage additional memory when compared to traditional octree structures to provide this improvement. In addition to reducing …

Application Of Ultraviolet Light Emitting Diodes For The Advanced Oxidation Of Guar Gum, Andrew W. Davenport

Theses and Dissertations

Guar Gum (GG) is one of the problematic water pollutants connected to hydraulic fracturing. There is a pressing need to investigate appropriate unit operations that can be employed to protect the aquatic environment. This study investigated the use of light-emitting diodes (LEDs) in the advanced oxidation process (AOP) of GG. Chemical oxygen demand (COD) removal provided mixed results, depending on the concentration of hydrogen peroxide (H₂O₂) in solution, and was between (0-95%) for H₂O₂-to-GG ratios between 7.0 and 176.3 g H₂O₂/g GG. COD removal was greatest at the …

Water Dynamics And The Effect Of Static And Alternating Electric Fields, Mohammadmahdi Shafiei Alavijeh

Theses and Dissertations

Having a net dipole moment, water molecules tend to align with an external electric field. The re-orientation of water molecules to align with the field direction can result in structural and dynamic changes in liquid water. Studying these changes can help us to understand the role of an E-field in many biological systems, chemical reactions, and many technological advancements.

In short, the application of static electric fields causes molecules to stay aligned with the field, so, fewer hydrogen bonds break, and molecules have slower dynamics. This type of field can be used when the mobility of water molecules needs to …

Operationalizing Resilience In The Face Of Water Conflict: Linking Social And Ecological Systems, Stephen Andrew Mcguire

Theses and Dissertations

This dissertation investigates the possibility of linked surface-groundwater governance through the application of a social-ecological systems lens to the Lake Beulah Conflict over a high capacity well in Walworth County, Wisconsin. Potential adverse impacts the loss of Ca2+ rich groundwater would have on Lake Beulah’s water quality was modeled through an ex-ante assessment method using the U.S. Army Corps of Engineers lake and reservoir model BATHTUB, the U.S. Geological Survey geochemical model PHREEQC and a Ca2+ mass balance equation. The utility of this information in a management setting was also analyzed. Reduction of Ca2+ through groundwater withdrawal revealed a eutrophication …

Applying The Water Governance Framework On Rural Water Development Projects In Guatemala, Muhanad M. Alkharaz

Theses and Dissertations

According to the Organization for Economic Cooperation and Development (OECD), ‘Water crisis is mainly a governance crisis’, (OECD, 2013). Many water experts, as individuals, organizations and even governmental bodies have developed water governance frameworks to overcome water challenges on local, national, and international levels such as Integrated Water Resource Management. In rural areas, especially in developing countries, access to safe drinking water is a daily challenge due to a variety of political, economic, and social constraints. For in-stance, some developing countries have a strong centralized governance system. Due to lack of capacity and resources, central governments are incapable of providing …

Tap Versus Bottle: A Mixed Methods Analysis Of Public Water Supply And The Bottled Water Industry In The United States, Catherine Simons

Theses and Dissertations

Discrepancies exist between the regulation of public tap water by the EPA and bottled water by the FDA. The Safe Drinking Water Act mandates the EPA to set national contaminant standards for drinking water as well as regulations to ensure source water protection, treatment, monitoring, compliance, enforcement, waste water, and public access to water quality information. Bottled water is subject to a differing mandate. As a food product regulated by the FDA, bottled water is required to comply with FDA food regulations as well as specific bottled water regulation regarding standards of identity, quality and cGMP. As a result of …

The Role Of Algorithmic Decision Processes In Decision Automation: Three Case Studies, Blake Edward Durtschi

Theses and Dissertations

This thesis develops a new abstraction for solving problems in decision automation. Decision automation is the process of creating algorithms which use data to make decisions without the need for human intervention. In this abstraction, four key ideas/problems are highlighted which must be considered when solving any decision problem. These four problems are the decision problem, the learning problem, the model reduction problem, and the verification problem. One of the benefits of this abstraction is that a wide range of decision problems from many different areas can be broken down into these four “key” sub-problems. By focusing on these key …

A Potentiometric Method, A Convenient And Rapid Technique For Determination Of The Thermodynamics Of Ionization Reactions For Water, Weak Acids, And Some Slightly Soluble Salts In Aqueous Organic Mixed Solvents, Charanai Panichajakul

Theses and Dissertations

A potentiometric method which is devised to be rapid and convenient for determining ionization constants for water, weak acids (or bases), and certain solids in mixed solvents is described. The method has been applied to the determination of ionization for water, acetic acid, benzoic acid, and phenol and the solubility product constant for silver chloride in mixtures of water with methanol, ethanol, acetone, tetrahydrofuran, and p-dioxane containing from 0 to 70 mass percent organic co-solvent at several temperatures between 10 and 40°C. Results are used to study the thermodynamics of ionization in each mixture which is discussed relative to various …

Mechanism Of Water Transport Through Reverse Osmotic Membranes, Cheryl Kay Murphy

Theses and Dissertations

Cellulose acetate membranes show a higher permeability to water than to salt and are being used for desalination of salt water by reverse osmosis. Use of highly acetylated cellulose membranes give a higher salt rejection but also decrease flow rate of the water. The addition of very-short-chain substances or alkyl groups larger than one carbon atom to the cellulose membrane also decreases water flux. A proposed mechanism of transport through the membrane is that the water molecule is passed along the chain by hydrogen bonding with the acetyl groups, The NMR shows a change in the chemical shift of water …