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Full-Text Articles in Physical Sciences and Mathematics

Writing And Designing A Chapter On Mercury And Pluto For The Textbook Exploring The Planets (Explanet.Info), Braxton Clark Spilker Nov 2018

Writing And Designing A Chapter On Mercury And Pluto For The Textbook Exploring The Planets (Explanet.Info), Braxton Clark Spilker

Theses and Dissertations

Exploring the Planets (http://explanet.info) is a free online college textbook covering thebasic concepts of planetary science emphasizing the character and evolution of the planetarybodies in the Solar System. The latest edition (3rd edition) was published online in 2007 by EricH Christiansen. Since the release of the third edition, two important planetary missions havebeen completed: MESSENGER (to Mercury) and New Horizons (to Pluto). These missionsprovided new information and fundamental insights into these planetary bodies, which have notyet been included in Exploring the Planets. The modern results based on recent investigations ofMercury and Pluto are critical for our understanding of the nature …


Mercury And Dissolved Organic Matter Dynamics During Snowmelt In A Montane Watershed, Provo River, Utah., Brian Noel Packer Jun 2018

Mercury And Dissolved Organic Matter Dynamics During Snowmelt In A Montane Watershed, Provo River, Utah., Brian Noel Packer

Theses and Dissertations

Mercury (Hg) transport in streams is typically facilitated by dissolved organic matter (DOM), however, the dynamics of Hg and DOM during snowmelt in montane watersheds are poorly understood. Hg transport during snowmelt is widely recognized as a significant source of Hg to downstream lakes and reservoirs, such as Jordanelle Reservoir where fish consumption advisories are in effect due to elevated Hg concentrations in certain species of fish. For this study, total mercury (THg), methylmercury (MeHg), and DOM samples were collected at three sites in the upper Provo River, northern Utah, during the 2016 and 2017 water years. To evaluate Hg …


Computational Studies On Mechanisms And Reactivity Of Mercury And Cobalt Organometallic Reactions, Jack Terrell Fuller Jul 2016

Computational Studies On Mechanisms And Reactivity Of Mercury And Cobalt Organometallic Reactions, Jack Terrell Fuller

Theses and Dissertations

Density Functional Theory (DFT) is a powerful tool for treating large organometallic structures efficiently and accurately. DFT calculations on the Hg-catalyzed oxidation of methane to methyl bisulfate in sulfuric acid suggest the lowest energy pathway involves a closed-shell electrophilic C–H activation mechanism coupled with metal alkyl reductive functionalization and oxidation by SO3. Comparison to Tl, Zn, and Cd suggests that Hg is unique in its ability to catalyze this set of reaction steps. Comparison to K2S2O8 highlights the selectivity of this C–H activation reaction as opposed to radical conditions. In contrast, DFT calculations indicate that CoIII(TFA)3 oxidizes methane through a …


Ferritin-Based Photo-Oxidation Of Biomass For Nanoparticle Synthesis, Bioremediation, And Hydrogen Evolution, Oscar Petrucci Dec 2013

Ferritin-Based Photo-Oxidation Of Biomass For Nanoparticle Synthesis, Bioremediation, And Hydrogen Evolution, Oscar Petrucci

Theses and Dissertations

The cell is the basic unit of all living organisms. It is an amazing machine capable of self-replicating, growing, and synthesizing and shuttling thousands of compounds. To perform all of these activities the cell needs energy. The original source of energy for all living beings is the Sun. The energy of the sun is collected by the autotrophs (mostly plants) through photosynthesis and stored in the chemical bonds of carbohydrates and lipids through carboxylic acid intermediates; animals use these compounds to obtain the energy for their cells. Most of the energy extracted by the cell comes from the citric acid …


Thermodynamic Equilibrium Formation Constants And Molal Concentrations Of The Complexed Mercury-Containing Species Of Mercuric Chloride In Added Hydrochloric Acid And Methanol-Water Solvent Mixtures, Karl Jennings Walker Apr 1973

Thermodynamic Equilibrium Formation Constants And Molal Concentrations Of The Complexed Mercury-Containing Species Of Mercuric Chloride In Added Hydrochloric Acid And Methanol-Water Solvent Mixtures, Karl Jennings Walker

Theses and Dissertations

Saturated solutions of mercuric chloride in different methanol-water and hydrochloric acid solvent mixtures were equilibrated at 25.00 ± 0.01°C. Total mercury and free chloride concentrations were determined by analytical procedures and the data were analyzed with the aid of the computer. Tabulated below are the results of this study: [--see thesis for table--]