Physical Sciences and Mathematics Commons^™

An Analysis Of Urban Heat Islands In Kentucky, Logan Mitchell

Mahurin Honors College Capstone Experience/Thesis Projects

The purpose of this research is to increase understanding of the Urban Heat Island (UHI) effect in Kentucky by studying its three largest cities: Louisville, Lexington, and Bowling Green. By examining the UHIs of these three cities, two major attributes can be determined: if there is a relationship between the size of the city by population and the UHI magnitude, and if UHI magnitude follows any diurnal and/or seasonal cycles. Data was collected from weather stations within the three major cities, as well as from weather stations located in the rural areas surrounding them. The length of the time series …

Project-Based And Problem-Based Instruction: A Literature Review, Sarah Angelle

Mahurin Honors College Capstone Experience/Thesis Projects

Science, technology, engineering, and mathematics (STEM) education has undergone great transformative reform during the last two decades with revised education standards calling for increased rigor to promote conceptual understanding of ideas and transferable 21st Century practices. Student-centered inquiry-based pedagogies like problem- and project-based instruction (PBI and PjBI) have begun to take root in K-12 STEM classrooms as an answer to the reform call. However, there is some disagreement of the specific characteristics of each pedagogy. There is also limited information regarding prevalence of these pedagogies in practice, their contextual patterns, degree to which they benefit all children, and the benefits/challenges …

The Voice Of Iceland: Communication Of Climate Science Through Choral Music, Jason Fox

Mahurin Honors College Capstone Experience/Thesis Projects

As the environmental sciences expand with the intent to more fully analyze and understand human interactions with the environment in a time of rapid environmental change, a need has arisen to more widely communicate new environmental knowledge with the public; however, environmental communication efforts often fail to capture the interest of audiences in relatable, emotional ways. This research constitutes an exploratory evaluation of the potential of choral music to effectively communicate climate change to musical audiences using Iceland as a geographic backdrop. Based on the author’s own experiences regarding climate change in Iceland, a three-movement original choral composition Icelandic Sketches: …

Vertex-Relaxed Graceful Labelings Of Graphs And Congruences, Florin Aftene

Masters Theses & Specialist Projects

A labeling of a graph is an assignment of a natural number to each vertex

of a graph. Graceful labelings are very important types of labelings. The study of graceful labelings is very difficult and little has been shown about such labelings. Vertex-relaxed graceful labelings of graphs are a class of labelings that include graceful labelings, and their study gives an approach to the study of graceful labelings. In this thesis we generalize the congruence approach of Rosa to obtain new criteria for vertex-relaxed graceful labelings of graphs. To do this, we generalize Faulhaber’s Formula, which is a famous result …

Kinetic Modeling Of The Atmospheric Photooxidation Of Reduced Sulfur And Nitrogen Compounds, Jesus Alejandro Berlanga

Masters Theses & Specialist Projects

Atmospheric aerosols encapsulate a wide variety of particles with different compositions, sizes and sources of origin. They also directly and indirectly affect climate by their interactions with sunlight, clouds, atmospheric chemical species, and even other suspended particles. To understand the atmospheric aerosol processes and the effects they have in global and regional climate is of utmost importance for the future establishment of environmental regulations and emission policies that affect aerosol precursor compounds in an effective and beneficial manner. In particular, aerosols are known to be formed from emissions from human activities, such as fossil fuel burning, agriculture, or concentrated animal …

Application Of Huffman Data Compression Algorithm In Hashing Computation, Lakshmi Narasimha Devulapalli Venkata,

Masters Theses & Specialist Projects

Cryptography is the art of protecting information by encrypting the original message into an unreadable format. A cryptographic hash function is a hash function which takes an arbitrary length of the text message as input and converts that text into a fixed length of encrypted characters which is infeasible to invert. The values returned by the hash function are called as the message digest or simply hash values. Because of its versatility, hash functions are used in many applications such as message authentication, digital signatures, and password hashing [Thomsen and Knudsen, 2005].

The purpose of this study is to apply …

An Integration Setup If The In-Situ Mass And Spectroscopic Analysis For Volatile Liquids Or Solids, Kolton K. Jones

Masters Theses & Specialist Projects

To help address the growing need for more and better sensors, an attempt was made to produce an in-situ mass and spectroscopic analysis of liquid and solid samples, to characterize samples and sensors. Spectroscopic analysis consisted of Raman and FTIR where mass measurements were carried out. The sample or sensor’s holder would allow for spectroscopic analysis as well as expose the sample to high temperatures and various chemicals. While Raman and FTIR were successful in producing reliable and consistent data, the constructed watt balance was not. This failure was a result of eliminate vibrational noise.

Policy Communication And The Influence Of Agricultural Communities On Karst Landscapes: A Case Study In Phong Nha-Kẻ Bàng National Park, Vietnam, Elizabeth Willenbrink

Masters Theses & Specialist Projects

Karst landscapes are vulnerable to human influence, especially agricultural practices. The interconnectedness between surface activities and subsurface environments make karst landscapes particularly susceptible to soil erosion and water contamination. The likelihood of these two phenomena happening increases when agricultural intensification, irrigation, or fertilizer application occurs. This situation arises frequently in Vietnam, where 18% of the country is karst terrain and 60% of the population depends on agriculture for their livelihoods (Farming First 2009). In order to mitigate the negative consequences of agriculture on karst landscapes, effective implementation of policy to regulate human activities and increased communication of these policies to …

Biomimetic Studies Of Oxidation Reactions By Metalloporphyrins Through Ligand Effect And Kinetic Studies Of Photo-Generated Porphyrin-Iron(Iv)- Oxocompound Ii Models, Dharmesh J. Patel

Masters Theses & Specialist Projects

High-valent iron(IV)-oxo porphyrins are the central oxidizing species in hemecontaining enzymes and synthetic oxidation catalysts. Many transition metal complexes have been extensively studied as models of the ubiquitous cytochrome P450 enzymes to probe the sophisticated oxygen atom transfer (OAT) mechanism as well as to invent enzyme-like oxidation catalysts. In this work, two metalloporphyrin complexes have been successfully synthesized, and spectroscopically characterized. A new photochemical entry to porphyrin-iron(IV)-oxo derivatives, commonly referred to as compound II models, was also investigated in two porphyrin ligands that differ in electronic and steric environments. As determined by their distinct UV-vis spectra and kinetic behaviors, iron(IV)-oxo …

Cayley Graphs Of Psl(2) Over Finite Commutative Rings, Kathleen Bell

Masters Theses & Specialist Projects

Hadwiger's conjecture is one of the deepest open questions in graph theory, and Cayley graphs are an applicable and useful subtopic of algebra.

Chapter 1 will introduce Hadwiger's conjecture and Cayley graphs, providing a summary of background information on those topics, and continuing by introducing our problem. Chapter 2 will provide necessary definitions. Chapter 3 will give a brief survey of background information and of the existing literature on Hadwiger's conjecture, Hamiltonicity, and the isoperimetric number; in this chapter we will explore what cases are already shown and what the most recent results are. Chapter 4 will give our decomposition …

Imidazolium Ionic Liquids As Multifunctional Solvents, Ligands, And Reducing Agents For Noble Metal Deposition Onto Well-Defined Heterostructures And The Effect Of Synthetic History On Catalytic Performance, Michael Drake Ballentine

Masters Theses & Specialist Projects

1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIM]Tf2N) was investigated as a multifunctional solvent, ligand, and reducing agent for platinum deposition onto well-defined CdSe@CdS nanorods. Platinum deposition was carried out thermally and photochemically using Pt(acac)2 as the metal precursor. Thermal deposition was investigated in [BMIM]Tf2N with and without addition of a sacrificial reducing agent, and product topology was compared with the products obtained from polyol reduction using 1,2-hexadecanediol, oleic acid, and oleylamine in diphenyl ether. Photochemically induced platinum deposition was carried out at room temperature in [BMIM]Tf2N, and product topology was compared with the photodeposition products obtained from a toluene dispersion. Thermal deposition of platinum …

The Influence Of A Proposed Margin Criterion On The Accuracy Of Parallel Analysis In Conditions Engendering Underextraction, Justin M. Jones

Masters Theses & Specialist Projects

One of the most important decisions to make when performing an exploratory factor or principal component analysis regards the number of factors to retain. Parallel analysis is considered to be the best course of action in these circumstances as it consistently outperforms other factor extraction methods (Zwick & Velicer, 1986). Even so, parallel analysis could benefit from further research and refinement to improve its accuracy. Characteristics such as factor loadings, correlations between factors, and number of variables per factor all have been shown to adversely impact the effectiveness of parallel analysis as a means of identifying the number of factors …

Score Test And Likelihood Ratio Test For Zero-Inflated Binomial Distribution And Geometric Distribution, Xiaogang Dai

Masters Theses & Specialist Projects

The main purpose of this thesis is to compare the performance of the score test and the likelihood ratio test by computing type I errors and type II errors when the tests are applied to the geometric distribution and inflated binomial distribution. We first derive test statistics of the score test and the likelihood ratio test for both distributions. We then use the software package R to perform a simulation to study the behavior of the two tests. We derive the R codes to calculate the two types of error for each distribution. We create lots of samples to approximate …

Carbon Flux And Weathering Processes In Icelandic Glacial-Fed Rivers, Allison Quiroga

Masters Theses & Specialist Projects

An investigation into the carbon dynamics and weathering processes occurring in Icelandic glacial-fed streams was conducted during the spring to summer seasonal transition in June of 2017. Four major outlet rives were sampled from the glaciers of Gígjökull, Steinsholtsjökull, Sólheimajökull, and Falljökull. Markarfljót, the major river that Gígjökull, Steinsholtsjökull, and many other glaciers drain into, was also sampled. Longitudinal sampling occurred at all sites to capture downstream trends in the hydrogeochemistry and carbon dynamics. Distinct differences in geochemistry between glacier surface meltwater, sub-glacial waters, pro-glacial lake water, and post-mixed downstream samples were evident in the data. Glacier surface streams were …

Investigating The Influence Of Esri Story Map Design On Partcipation In Sustainability-Related Activities, Brittany Grace Austin

Masters Theses & Specialist Projects

Decades of scientific inquiry have conveyed evidence in support of sustainability efforts to mitigate some of the greatest challenges and dilemmas facing modern and future societies. The solutions to these dilemmas may not be achievable in the short-term, yet, through increased public participation in sustainable community development, smallscale, localized solutions can be obtained. This preliminary research explored the influence of Environmental Systems Research Institute (Esri) story map designs on participation in sustainability-related activities among individuals who expressed interest in sustainable lifestyles. Specifically, this exploratory study was designed to demonstrate the applicability of interactive web geographic information systems (GIS) applications as …

Foutier Transform Infrared Spectroscopy Instrumentation And Integration With Thermogravimetry, Junjie Xiang

Masters Theses & Specialist Projects

To discover the potential of IR spectroscopy and explore the details of FTIR instrumentation, a FTIR was built from most basic parts to provide access to every aspect of a IR spectrometer including the hardware and software. The optical system followed the most widely used double-interferometer design. The software control system was developed with LabVIEW to perform data acquisition of the detectors, data processing and controls of the actuators. The FTIR built will be able to provide a full optical IR spectroscopy platform which has a complete control and data acquisition system and can be continuously improved in accuracy and …

Controllability And Observability Of The Discrete Fractional Linear State-Space Model, Duc M. Nguyen

Masters Theses & Specialist Projects

This thesis aims to investigate the controllability and observability of the discrete fractional linear time-invariant state-space model. First, we will establish key concepts and properties which are the tools necessary for our task. In the third chapter, we will discuss the discrete state-space model and set up the criteria for these two properties. Then, in the fourth chapter, we will attempt to apply these criteria to the discrete fractional model. The general flow of our objectives is as follows: we start with the first-order linear difference equation, move on to the discrete system, then the fractional difference equation, and finally …

Secondary Electronic And Solvent Effects On Regiospecific P-Bromination Of Aromatic Systems, Selahaddin Gumus

Masters Theses & Specialist Projects

Bromoarenes are important aromatic building blocks that are commonly used to synthesize various functional compounds in pharmaceutical, agrochemical and related industries.^1,2 This great demand for bromoarenes makes their preparation a widely studied area of synthetic organic chemistry. However, further understanding of the reactivity and regiochemistry of aromatic functionalization reactions is still necessary, as much about the secondary substitution and solvent effects remain unknown.

Resonance Theory is a widely used theoretical model to predict the regiospecifity and reactivity of the bromination of various aromatic compounds.³ The reactivity and regiospecificity of many substituted aromatic compounds is well explained using resonance …

Runs Of Identical Outcomes In A Sequence Of Bernoulli Trials, Matthew Riggle

Masters Theses & Specialist Projects

The Bernoulli distribution is a basic, well-studied distribution in probability. In this thesis, we will consider repeated Bernoulli trials in order to study runs of identical outcomes. More formally, for t ∈ N, we let Xt ∼ Bernoulli(p), where p is the probability of success, q = 1 − p is the probability of failure, and all Xt are independent. Then Xt gives the outcome of the tth trial, which is 1 for success or 0 for failure. For n, m ∈ N, we define Tn to be the number of trials needed to first observe n …

Temperature And Electric Field Dependency Of Asymmetric Stretching Of Nitrate And Carbonate Ions, Konnor Jones

Masters Theses & Specialist Projects

Photolysis of nitrate ion in the natural environment produces NO, NO2, and O3, releasing these toxic gases into the atmosphere. Work done by other groups has shown ionic strength dependence of the ratio of products from photolysis of aqueous nitrate ion. To better understand the kinetic mechanisms of nitrate photolysis, the effects that ionic strength in solution have on nitrate ion symmetry breaking are needed. Different solvation environments induce nitrate bonding motifs that may be correlated to the product ratio. Fourier-transform infrared spectra of aqueous nitrate–ion solutions were obtained over a range of temperatures for several total electrolyte concentrations. The …

Iterative Methods To Solve Systems Of Nonlinear Algebraic Equations, Md Shafiful Alam

Masters Theses & Specialist Projects

Iterative methods have been a very important area of study in numerical analysis since the inception of computational science. Their use ranges from solving algebraic equations to systems of differential equations and many more. In this thesis, we discuss several iterative methods, however our main focus is Newton's method. We present a detailed study of Newton's method, its order of convergence and the asymptotic error constant when solving problems of various types as well as analyze several pitfalls, which can affect convergence. We also pose some necessary and sufficient conditions on the function f for higher order of convergence. Different …

Analyzing The Efficiency Of Reforestation Efforts In Regaining Carbon Storage In A Costa Rican Cloud Forest, Elvin Irihamye

Student Research Conference Select Presentations

Forests hold an important place in offsetting carbon emissions, absorbing nearly 40 percent of man-made fossil fuel emissions every year. Over the last 100 years, the effects of deforestation have crippled our forest’s ability to store excess carbon, leading to drastic atmospheric change. Efforts to regrow deforested forests have increased rapidly to address issues like climate change. There is thus a need to analyze current efforts at regaining carbon storage, a critical component to maintaining atmospheric homeostasis. Accordingly, we traveled to the Cloudbridge Nature Reserve in San Gerardo, Costa Rica to aggregate data on the carbon storage capabilities across three …

Highway Construction Or Stream Destruction: A Water Quality Analysis In The Black Warrior Basin, Walker County, Alabama, Cayla Baughn

Mahurin Honors College Capstone Experience/Thesis Projects

In 2012, residents along Freeman Branch Creek in Eldridge, Alabama observed unusual orange discoloration along the stream and on stream vegetation; an unprecendented black veneer coating pebbles along the streambed; and life in the stream seemed to have vanished. Freeman Branch Creek is located in Walker County, Alabama, which is known for its production of coal and natural gas from the underlying Pennsylvanian-aged Pottsville Formation, which is the uppermost geologic layer within the the Black Warrior Basin. Concerns for environmental safety related to intensive mining operations include the concern that shallow aquifers will be contaminated by mining in deep reservoir …

Solar Eclipse, 2017 (Sc 3152), Manuscripts & Folklife Archives

MSS Finding Aids

Finding aid only for Manuscripts Small Collection 3152. Materials relating to the 2017 solar eclipse as experienced primarily in Bowling Green and Hopkinsville, Kentucky and vicinity. Includes viewing glasses, first day stamped covers, stickers, art work, photographs (in digital format), promotional materials, and impressions of the eclipse contributed as part of WKU’s Department of Library Special Collections’ “Tell Us About Your Eclipse Day” project. Also includes wristbands, handouts and volunteer information relating to an eclipse viewing event for schoolchildren held at WKU’s Smith-Houchens Stadium. Digital photographs are stored in the Photo Archives.

Ua37/42 Faculty Personal Papers Nina Hammer, Wku Archives

WKU Archives Collection Inventories

Personal papers of Nina Hammer, Bowling Green Business University Registrar 1938-1963; WKU Registrar 1963-1969.

Wku Office Of Sustainability Annual Report 2017, Christian Ryan, Catherine Walters, Alexa Hatcher, Noelle Legrand

Sustainability Publications and Resources

No abstract provided.

Ua66/1/1 Spring "New"Sletter, Issue 16, Wku Ogden College Of Science & Engineering

WKU Archives Records

Newsletter created by and about WKU Ogden College of Science & Engineering.

U.S. Geological Survey (Usgs) Topographic Map Collection, Kentucky Library Research Collections

Research Collections

This is a listing of the Topo maps housed in the KLRC; 7.5, 15 and 30 minute Kentucky and Boundary State Maps. These maps are helpful in genealogy to show how the landscape may have changed and they may have the locations of lost towns and cemeteries and indicate houses, barns, and other structures and how place names, roads, and streams changed over time.

Using Mixed Effects Modeling To Quantify Difference Between Patient Groups With Diabetic Foot Ulcers, Rachel French

Mahurin Honors College Capstone Experience/Thesis Projects

When diabetes progresses, many patients suffer from chronic foot ulcers. In a study described in Matrix Metalloproteinases and Diabetic Foot Ulcers (Muller et al., 2008), sixteen patients with diabetic foot ulcers were examined throughout a twelve week healing period. During this period, levels of matrix metalloproteinases (MMP-1), their inhibitors (TIMP-1), and the extracellular matrix in a wound area were measured at distinct time intervals for each patient. The ratios of these healing components are vital in determining whether a wound will heal or become chronic and never properly heal. Connecting Local and Global Sensitivities in a Mathematical Model for Wound …

De Paepe, Duane - Collector (Mss 625), Manuscripts & Folklife Archives

MSS Finding Aids

Finding aid only for Manuscripts Collection 625. The Duane De Paepe Kentucky Cave Saltpetre History Research Collection, a collection of historical research, field notes, cave surveys, photographs, maps, reports, and scholarly writing on saltpetre mining in Kentucky, especially at Mammoth Cave. The collection was created under a research program sponsored by the Cave Research Foundation and the National Geographic Society in Kentucky, 1976-1980, and directed by De Paepe.