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Western Kentucky University

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2016

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Full-Text Articles in Physical Sciences and Mathematics

Density-Dependent Leslie Matrix Modeling For Logistic Populations With Steady-State Distribution Control, Bruce Kessler, Andrew Davis Dec 2016

Density-Dependent Leslie Matrix Modeling For Logistic Populations With Steady-State Distribution Control, Bruce Kessler, Andrew Davis

Mathematics Faculty Publications

The Leslie matrix model allows for the discrete modeling of population age-groups whose total population grows exponentially. Many attempts have been made to adapt this model to a logistic model with a carrying capacity (see [1], [2], [4], [5], and [6]), with mixed results. In this paper we provide a new model for logistic populations that tracks age-group populations with repeated multiplication of a density-dependent matrix constructed from an original Leslie matrix, the chosen carrying capacity of the model, and the desired steady-state age-group distribution. The total populations from the model converge to a discrete logistic model with the same …


How We’Ll Fight The Next Deadly Virus Ted Talk Annotated Resource List, Susie Roy Oct 2016

How We’Ll Fight The Next Deadly Virus Ted Talk Annotated Resource List, Susie Roy

Undergraduate Research Award

No abstract provided.


Your Body Language Shapes Who You Are Ted Talk Annotated Resource List, Elizabeth Hurm Oct 2016

Your Body Language Shapes Who You Are Ted Talk Annotated Resource List, Elizabeth Hurm

Undergraduate Research Award

No abstract provided.


In Situ Ion Exchange In A Micro-Porous Transition Metal Silicate Framework, Jason M. Lively Oct 2016

In Situ Ion Exchange In A Micro-Porous Transition Metal Silicate Framework, Jason M. Lively

Masters Theses & Specialist Projects

Ion selectivity of minerals has traditionally been utilized in industry as a catalyst, metal separation, and environmental reclamation/sequestration tool. There is an increased interest in understanding ion selectivity mechanisms of micro-porous minerals and mineral-like structures and how they can be applied in various industries: environmental and, potentially, pharmaceutical. This study seeks to understand the ion exchange mechanisms in micro-porous zirconosilicates using time-resolved Raman spectroscopy and X-ray diffraction. The thesis material was exchanged with H+, Na+, K+, and Cs+ in order to better understand structural changes as well as the influence of the H+-bonding during the exchange process. It is hypothesized …


Dispersion Of Ammonia From Concentrated Animal Feeding Operations, Austin D. Wardall Oct 2016

Dispersion Of Ammonia From Concentrated Animal Feeding Operations, Austin D. Wardall

Masters Theses & Specialist Projects

The purpose of this research is to investigate the dispersion of ammonia (NH3) from three Concentrated Animal Feeding Operations (CAFOs) in western Kentucky, as well as to investigate the Weather Research and Forecasting – Chemistry (WRF-Chem) model’s sensitivity response to initial NH3 concentrations under both wet conditions (significant precipitation) and dry conditions (no precipitation). As expected, pollutant concentrations generally were significantly higher near their points of origin and generally declined away from the sources. Contrary to expectations, ammonia tended to rise through the planetary boundary layer (PBL) regardless of atmospheric conditions. Results showed modeled NH3 pollution levels at the surface …


The Investigation Of The Electrical Control Of Hemimicelles And Admicelles On Gold For Analyte Preconcentration, Dheyaa Hussein Al-Karawi Oct 2016

The Investigation Of The Electrical Control Of Hemimicelles And Admicelles On Gold For Analyte Preconcentration, Dheyaa Hussein Al-Karawi

Masters Theses & Specialist Projects

Hemimicelles and admicelles are well-investigated wonders in modern science; they are surfactant monolayers and surface adsorbed micelles, respectively. Capacitance measurements for monitoring the formation of dodecyl sulfate (DS) surfactant monolayer on positively charged gold substrates (planar gold) and the adsorbance of 2-naphthol onto DS surfactant monolayer were performed. The investigation of the electrical control of DS at various concentrations (4, 6, 16, and 32 mM) below and above the critical micelle concentration (CMC= 8 mM) on gold surfaces for analyte preconcentration, prior to chromatographic analysis, is presented. Charged ionic surfactants, such as DS, drawn to a surface of opposite charge …


Feasibility Of The Use Of Neutron Activation Analysis Techniques In An Underwater Environment, Michael D. Chick Oct 2016

Feasibility Of The Use Of Neutron Activation Analysis Techniques In An Underwater Environment, Michael D. Chick

Masters Theses & Specialist Projects

Elements when bombarded with neutrons emit a gamma ray that is characteristic of the isotope that underwent a neutron induced nuclear reaction; this is known as neutron activation. The characteristic gamma energy of an isotope can then be detected and recorded. One can then analyze the gamma energies captured and determine the elemental makeup of the sample. This form of analysis can be used in an underwater environment making it potentially a valuable tool for agencies tasked with maritime security of ports and waterways, or clean-up operations. This thesis will focus on the feasibility of neutron interrogation using pulsed fast/thermal …


The Effects Of Sulfuric Acid Deposition On The Growth And Development Of Pond Breeding Salamanders In The Genus Ambystoma, Kenneth J. Anderson Oct 2016

The Effects Of Sulfuric Acid Deposition On The Growth And Development Of Pond Breeding Salamanders In The Genus Ambystoma, Kenneth J. Anderson

Masters Theses & Specialist Projects

In terrestrial habitats with a history of mining activity and previous or ongoing reclamation efforts, understanding the effects of acidification on the ecology of amphibians is an important part of the restoration process and the conservation of local amphibian populations. Pond-breeding amphibians spend much of their post metamorphic life history in direct contact with the soil in upland habitat adjacent to aquatic breeding sites. I reared recently metamorphosed marbled salamanders (Ambystoma opacum) to evaluate the role of soil acidity on determinants of fitness such as growth and survival. My results indicate that a substrate of pH 4 was lethal to …


Mabic: Mobile Application Builder For Interactive Communication, Huy Manh Nguyen Oct 2016

Mabic: Mobile Application Builder For Interactive Communication, Huy Manh Nguyen

Masters Theses & Specialist Projects

Nowadays, the web services and mobile technology advance to a whole new level. These technologies make the modern communication faster and more convenient than the traditional way. People can also easily share data, picture, image and video instantly. It also saves time and money. For example: sending an email or text message is cheaper and faster than a letter. Interactive communication allows the instant exchange of feedback and enables two-way communication between people and people, or people and computer. It increases the engagement of sender and receiver in communication.

Although many systems such as REDCap and Taverna are built for …


Metal-Organic Hybrid Nanocomposites For Energy Harvesting Applications, Thulitha Madawa Abeywickrama Oct 2016

Metal-Organic Hybrid Nanocomposites For Energy Harvesting Applications, Thulitha Madawa Abeywickrama

Masters Theses & Specialist Projects

Various synthetic methods have been developed to produce metal nanostructures including copper and iron nanostructures. Modification of nanoparticle surface to enhance their characteristic properties through surface functionalization with organic ligands ranging from small molecules to polymeric materials including organic semiconducting polymers is a key interest in nanoscience. However, most of the synthetic methods developed in the past depend widely on non-aqueous solvents, toxic reducing agents, and high temperature and high-pressure conditions. Therefore, to produce metal nanostructures and their nanocomposites with a simpler and greener method is indeed necessary and desirable for their nano-scale applications. Hence the objective of this thesis …


Development Of Dihydrochalcone Functionalized Gold Nanoparticles For Augmented Antineoplastic Activity, Jason N. Payne Oct 2016

Development Of Dihydrochalcone Functionalized Gold Nanoparticles For Augmented Antineoplastic Activity, Jason N. Payne

Masters Theses & Specialist Projects

Phloridzin, an antidiabetic and antineoplastic agent usually found in fruit trees, is a dihydrochalcone constituent that has a clinical/pharmaceutical significance as a sodiumglucose linked transport 2 (SGLT2) inhibitor. Phloridzin never experienced widespread clinical usage in the pharmaceutical market due to its side effects and poor bioavailability when compared to other antidiabetic therapeutics. The poor bioavailability is primarily attributed to the degradation of the glycosidic bond of the phloridzin, resulting in the formation of phloretin, the aglycone of phloridzin and glucose. While phloretin displays a reduced capacity of SGLT2 inhibition, this nutraceutical shows enhanced antineoplastic activity in comparison to phloridzin. Gold …


Visible-Light Generation Of High-Valent Metal-Oxo Intermediates And A Biomimetic Oxidation Catalyzed By Manganese Porphyrins With Iodobenzene Diacetate, Ka Wai Kwong Oct 2016

Visible-Light Generation Of High-Valent Metal-Oxo Intermediates And A Biomimetic Oxidation Catalyzed By Manganese Porphyrins With Iodobenzene Diacetate, Ka Wai Kwong

Masters Theses & Specialist Projects

High-valent iron-oxo intermediates play central roles as active oxidants in enzymatic and synthetic catalytic oxidations. Many transition metal catalysts are designed for biomimetic studies of the predominant oxidation catalysts in Nature, the cytochrome P450 enzymes.

In this work, a new photochemical method to generate high-valent iron-oxo porphyrin models was discovered. As controlled by the electronic nature of porphyrin ligands, iron(IV)-oxo porphyrin radical cations (Compound I model) and iron(IV)-oxo porphyrin derivatives (Compound II model) were produced. These observations indicate that the photochemical reactions involve a heterolytic cleavage of O-Br in precursors to give a putative iron(V)-oxo intermediate, which might relax to …


Manufacturing And Engineering [Career Paper], Mahdi Alawami Oct 2016

Manufacturing And Engineering [Career Paper], Mahdi Alawami

Undergraduate Research Award

No abstract provided.


Icelandic Fisheries: Scenario Planning For Climate Change, Tara Sorrels Sep 2016

Icelandic Fisheries: Scenario Planning For Climate Change, Tara Sorrels

Mahurin Honors College Capstone Experience/Thesis Projects

This study aimed to develop an understanding of how a scenario planning process could be used to assist businesses to adapt to climate change. The focus of this study was on the Icelandic fishing industry since Iceland is experiencing firsthand climate change impacts. Mitigation strategies are the main focus in climate change research, but this study focused on a possible adaptation method that requires changing management practices in order to reduce the impact of climate change on the economy. Tours of Icelandic fisheries and interviews with individuals within the Icelandic fishing industry were conducted to assess the current adaptive capacity …


A Multi-Wavelength Analysis Of Cold Evolving Interstellar Clouds, Mary Spraggs Sep 2016

A Multi-Wavelength Analysis Of Cold Evolving Interstellar Clouds, Mary Spraggs

Mahurin Honors College Capstone Experience/Thesis Projects

The interstellar medium (ISM) is the dynamic system of gas and dust that fills the space between the stars within galaxies. Due to its integral role in star formation and ga-lactic structure, it is important to understand how the ISM itself evolves over time, in-cluding the process of cooling and condensing required to form new stars. This work aims to constrain and better understand the physical properties of the cold ISM with sev-eral different types of data, including large surveys of neutral atomic hydrogen (HI) 21cm spectral line emission and absorption, carbon monoxide (CO) 2.6mm line emission, and multi-band infrared …


Expanding The Applicability Of Raman Spectroscopy For Monitoring Photocatalytic Degradation, Franklyn Wallace Sep 2016

Expanding The Applicability Of Raman Spectroscopy For Monitoring Photocatalytic Degradation, Franklyn Wallace

Mahurin Honors College Capstone Experience/Thesis Projects

Compared to other types of wastewater pollutants, dangerous chemical compounds such as pharmaceuticals, pesticides, and herbicides are difficult to remove and consequently being detected (at least in part because detection limits have decreased) in drinking water at increasing concentrations. Photocatalytic degradation degrades harmful compounds to innocuous end products using energy from light. Although it is effective and cost-efficient, the underlying chemical mechanisms are not understood well enough to ensure that dangerous intermediate products are not formed during the degradation process. Raman spectroscopy can be used to analyze photocatalytic degradation reactions in real time, identifying intermediate products based on spectral features. …


Universities And Sustainable Food Practices: An International Comparison Along The Pacific Coast Of North America, Alexandra Schulte Aug 2016

Universities And Sustainable Food Practices: An International Comparison Along The Pacific Coast Of North America, Alexandra Schulte

Mahurin Honors College Capstone Experience/Thesis Projects

My research project examined sustainable practices in relation to food sources at three universities located along the Pacific Coast of North America. The academic institutions were the University of Alaska Anchorage (UAA), the University of California Santa Barbara (UCSB), and the University of British Columbia (UBC) in Vancouver. These schools were selected because while they each foster an abundance of “local” foods and food industries, they represent different stages in the three pillars of sustainability for food practices. My project sought to understand the role of each institution in building a local and sustainable food culture at each university. I …


A Study Of Chemistry: For Wind Ensemble, Morgan Duff Aug 2016

A Study Of Chemistry: For Wind Ensemble, Morgan Duff

Mahurin Honors College Capstone Experience/Thesis Projects

Many musicians have a limited understanding of chemistry, while many chemists aren't familiar with details of music theory or composition. Through the composition of a four-part musical work based entirely on several broad areas of chemistry, certain relationships have been shown between music and chemistry. Because of the overlap between certain scientific concepts and many aspects of music theory, it is possible for members of both fields to use what they already know in order to gain a deeper understanding of the other, very different, subject. Because everyone has learning strengths in differing areas, I believe the use of disciplinary …


Toward Autonomous Multi-Rotor Indoor Aerial Vehicles, Connor Brooks Aug 2016

Toward Autonomous Multi-Rotor Indoor Aerial Vehicles, Connor Brooks

Mahurin Honors College Capstone Experience/Thesis Projects

In this project, we worked to create an indoor autonomous micro aerial vehicle (MAV) using a multi-layer architecture with modular hardware and software components. We required that all computing was done onboard the vehicle during time of flight so that no remote connection of any kind was necessary for successful control of the vehicle, even when flying autonomously. We utilized environmental sensors including ultrasonic sensors, light detection and ranging modules, and inertial measurement units to acquire necessary environment information for autonomous flight. We used a three-layered system that combined a modular control architecture with distributed on-board computing to allow for …


The Rise Of Nuclear Energy In Arab States: Future Impacts, Brittany Broder Aug 2016

The Rise Of Nuclear Energy In Arab States: Future Impacts, Brittany Broder

Mahurin Honors College Capstone Experience/Thesis Projects

The signing of the Iranian nuclear deal during the Summer of 2015 highlighted the threat of nuclear proliferation from foreign powers, but largely overlooked the rise of nuclear energy in the Middle East and North Africa (MENA). With growing energy demands and heightened environmental regulations, countries in this region are turning to nuclear power to fuel their next generation. However, the rise of nuclear power in the MENA region holds serious implications for the future of the area’s energy, economic, and social reforms that have largely gone unexplored as a whole thus far. The purpose of this thesis is to …


Incorporating Exponential Functions Into An Optimal Control Model For A Chronic Wound, Peter Agaba Aug 2016

Incorporating Exponential Functions Into An Optimal Control Model For A Chronic Wound, Peter Agaba

Mahurin Honors College Capstone Experience/Thesis Projects

A chronic wound is a wound that does not heal in an orderly manner and on time. In this project, we simulate different ways of minimizing the time of therapy using exponential functions. The analysis in this research project focuses on treating chronic wounds using both mathematical and biological models. These models primarily focus on the amount of oxygen supplied to the wound using both hyperbaric and topical oxygen therapies. This amount should be optimal since too much oxygen is toxic to the body, and can potentially lead to death. The goal is to minimize the time spent in therapies …


A Classification Of The Intersections Between Regions And Their Topical Transitions, Kathleen Bell Aug 2016

A Classification Of The Intersections Between Regions And Their Topical Transitions, Kathleen Bell

Mahurin Honors College Capstone Experience/Thesis Projects

As two topological regions are morphed and translated, how does their intersection change? Previous research has been done on static configurations with planar spatial regions. I expand upon this research to include dynamically changing regions and intersections. I examine what forms of intersection are possible, and what transitions are directly possible, while considering such variables as the connectedness of the regions.


Ogden College Of Science & Engineering Newsletter (Summer 2016), Cheryl Stevens, Dean Jul 2016

Ogden College Of Science & Engineering Newsletter (Summer 2016), Cheryl Stevens, Dean

Ogden College of Science & Engineering Publications

No abstract provided.


Multiplexed Detection Of Double-Stranded Pathogenic Dna With Engineered Zinc Finger Proteins, Juhwa Kim Jul 2016

Multiplexed Detection Of Double-Stranded Pathogenic Dna With Engineered Zinc Finger Proteins, Juhwa Kim

Masters Theses & Specialist Projects

The development of a new technology for the detection of doublestranded (ds) DNA enables multiple biomedical applications including identifying multiple pathogens simultaneously. We previously employed colorimetric SEquence-Enabled Reassembly with TEM-1 β-lacatamase (SEER-LAC) to detect specific bacterial DNA sequence. SEER-Lac consists of the two inactive β-lactamase fragments which of each attached to a zinc finger protein (ZFP) would reassemble into an active full-length enzyme upon ZFPs binding to its target DNA. Here, we engineered two pairs of ZFPs which of each recognizes shiga toxin in E. coli O157 and staphylococcal enterotoxin B in Staphylococus Aureus, respectively. Biotin was simply conjugated to …


Evaluating The Influences Of Karst Hydrogeology On Freshwater Harmful Algal Blooms In Kentucky Lakes, Robert T. Schaefer Jul 2016

Evaluating The Influences Of Karst Hydrogeology On Freshwater Harmful Algal Blooms In Kentucky Lakes, Robert T. Schaefer

Masters Theses & Specialist Projects

A problem exists in Nolin River Lake and Rough River Lake in Kentucky, due to the increasing prevalence of cyanobacterial-based harmful algal blooms (CyanoHABs) and the threats they pose to local communities. These lakes were developed as artificial reservoirs from embankment. Further complicating the issue, the lakes are located within a heavily karstified region and there exists no plan or method currently for monitoring or managing CyanoHABs in a karst region with regard to groundwater inputs to the lake systems or their tributaries. A mixture of techniques and analysis methods was used to determine the best way to monitor and …


Nullification Of Torus Knots And Links, Zachary S. Bettersworth Jul 2016

Nullification Of Torus Knots And Links, Zachary S. Bettersworth

Masters Theses & Specialist Projects

Knot nullification is an unknotting operation performed on knots and links that can be used to model DNA recombination moves of circular DNA molecules in the laboratory. Thus nullification is a biologically relevant operation that should be studied.

Nullification moves can be naturally grouped into two classes: coherent nullification, which preserves the orientation of the knot, and incoherent nullification, which changes the orientation of the knot. We define the coherent (incoherent) nullification number of a knot or link as the minimal number of coherent (incoherent) nullification moves needed to unknot any knot or link. This thesis concentrates on the study …


Devonian Hydrocarbon Production In South Central Kentucky: A Gis Study, Andrew David Reeder Jul 2016

Devonian Hydrocarbon Production In South Central Kentucky: A Gis Study, Andrew David Reeder

Masters Theses & Specialist Projects

Historically, Devonian Corniferous hydrocarbon production in south-central Kentucky has been a major contributor to the total hydrocarbon resources within Butler, Edmonson, and Warren counties. The Corniferous adds to the already large hydrocarbon totals produced from the Illinois Basin; however, this hydrocarbon contribution does not come without major pitfalls and inconsistencies. The south-central Kentucky Devonian Corniferous rocks comprise a diverse and complex hydrocarbon system made up of multiple migration pathways, trapping mechanisms, and seals. The multiple Corniferous units all derive production from the same source rock: the New Albany Shale.

A Geographic Information System (GIS) containing data on surface elevations, structure …


Linking In-Situ Data With Remote Sensing To Analyze Tropical Glacier Stability And Retreat In The Cordillera Blanca, Peru, Chandler H. Santos Jul 2016

Linking In-Situ Data With Remote Sensing To Analyze Tropical Glacier Stability And Retreat In The Cordillera Blanca, Peru, Chandler H. Santos

Masters Theses & Specialist Projects

Glaciers are a major source of freshwater around the world, but they are melting at an increased rate due to atmospheric warming resulting from anthropogenic climate change. In addition to temperature increases, light-absorbing particulates on glaciers also are contributing to glacial melt. This research examines how black carbon, released into the air through partial combustion of biofuels, is affecting the surface albedo of glaciers. I also delineate possible sources of black carbon in the Cordillera Blanca region of Peru. Ground data were collected each year from 2011 to 2013 during the local dry season. Effective black carbon (eBC) values were …


Low-Cost Quartz Crystal Microbalance System Platform Designed For Chemical Nanoparticle, Danming Wei Jul 2016

Low-Cost Quartz Crystal Microbalance System Platform Designed For Chemical Nanoparticle, Danming Wei

Masters Theses & Specialist Projects

QCM sensor is a response to a kind of broad spectrum, high sensitivity, and simple structure, low-cost detection device, and particularly its quality as a type of gas sensor is widely used. With the successful oscillation in liquid phase, QCM sensor has been involved in the application analytical chemistry, surface chemistry, biochemistry and environmental monitoring side and many other scientific fields. With sensitive surface film as the sensitive element, AT-cut quartz crystal as energy transducer components by changes of the relationship between mass of surface film and frequency of QCM sensor transduces signals of mass or concentration into output frequency …


Using Zinc Finger Proteins As A Diagnostic Tool For The Detection Of A Cancer Biomarker, Anu Kini Jul 2016

Using Zinc Finger Proteins As A Diagnostic Tool For The Detection Of A Cancer Biomarker, Anu Kini

Masters Theses & Specialist Projects

RASSF1A is a tumor suppressor gene which loses its function due to methylation of CpG islands on its promoter region. Detection of methylation leads to early diagnosis of cancer.

Zinc finger proteins are capable of detecting a specific DNA sequence and Methyl binding domain can bind to the methyl group on the CpG, using this idea mCpG SEER- Lac system makes use of a split protein, β-lactamase. Lac A attached to the ZFP and Lac B attached to the MBD protein. On binding to the DNA, the Lac A and Lac B come in close proximity with each other causing …