Physical Sciences and Mathematics Commons^™

Uranium-Series And Strontium Isotope Ratios In Soils From Basse-Terre Island, French Guadeloupe: Insights For Rapid Soil Formation And Impact Of Dust In A Tropical Volcanic Setting, Yvette Pereyra

Open Access Theses & Dissertations

Chemical weathering of silicate rocks generates soils that contain mineral nutrients, sustain ecosystems, modify water chemistry in the hydrosphere, and regulate the global carbon cycle. Understanding the timescales of soil formation and sources of soil mineral nutrients has great implications for securing the future of agriculture and food production. However, few tools are currently available to directly quantify the rates of chemical weathering and timescales of soil formation. Uranium-series isotopes fractionate during chemical weathering and the activity ratios of (234U/238U), (230Th/238U), (238U/232Th) and (230Th/232Th) have great potential to constrain the rates and timescales of chemical weathering and soil formation in …

Combining Interval And Probabilistic Uncertainty In Engineering Applications, Andrew Martin Pownuk

Open Access Theses & Dissertations

In many practical application, we process measurement results and expert estimates. Measurements and expert estimates are never absolutely accurate, their result are slightly different from the actual (unknown) values of the corresponding quantities. It is therefore desirable to analyze how this measurement and estimation inaccuracy affects the results of data processing. There exist numerous methods for estimating the accuracy of the results of data processing under different models of measurement and estimation inaccuracies: probabilistic, interval, and fuzzy. To be useful in engineering applications, these methods should provide accurate estimate for the resulting uncertainty, should not take too much computation time, …

National Evaluation For Development And Exploration Potential Of Mineral Commodities In Produced Waters, Stephanie Ray

Open Access Theses & Dissertations

The U.S. Geological Survey recently updated a geochemical database consisting of data for approximately 160,000 produced waters samples, primarily from petroleum and geothermal reservoirs. Using major and trace elements from conventional and unconventional well types from the database, this Thesis provides a comprehensive, national evaluation for mineral commodity potential in produced waters. Produced waters contain virtually every naturally occurring element and can range in salinity to several times that of seawater. Despite the typical outlook to view produced waters as a waste, they have potential for natural resource development.

This Thesis provides, for each mineral commodity found in the produced …

Modeling Of Piezoelectric Traveling Wave Rotary Ultrasonic Motors With The Finite Volume Method, Ivan Arturo Renteria Marquez

Open Access Theses & Dissertations

In 1983 Toshiiku Sashida developed a new motor concept called Piezoelectric Traveling Wave Rotary Ultrasonic Motor (PTRUSM). The advantages of these motors include high torque at low speed, absence of a generated magnetic field, and high potential for miniaturization. Unfortunately PTRUSMs have some disadvantages that limit the areas of applications for these types of motors. The disadvantages are a short operating life (about 1000 hours), small output power, and the need of a complex motor controller.

On one hand, these motors have been used in satellites, mobile phones, photocopiers, robotic arms, telescopes, automobiles, and camera autofocusing. On the other hand, …

Improving The Engineering Properties Of Pla For 3d Printing And Beyond, Carmen R. Rocha

Open Access Theses & Dissertations

Additive manufacturing (AM), now more commonly known as 3D printing, has been classified as efficient, fast, and practical in the prototyping sector of product development. In the work presented here, we will use one of the AM techniques known as Material extrusion 3D printing (ME3DP), which has all the advantages of AM. However, one of the biggest challenges facing ME3DP technologies is the limitation of the range of materials used by this technique. Acrylonitrile butadiene styrene (ABS) and poly-lactic acid (PLA) are currently the most common thermoplastics materials used in ME3DP because of their ability to melt and be reprocessed. …

Development Of Efficient Simultaneous Confidence Bounds For Linear Mixed Models With Applications In Alcohol Research, Emmanuel Joseph Sequeira

Open Access Theses & Dissertations

Multiplicity corrections are necessary to ensure the accuracy of conclusions made in studies that carry out multiple inferences simultaneously. This Thesis uses the methodology derived by Hunter and Worsley to obtain improved simultaneous confidence bounds (SCBs) that are less conservative than the highly used Bonferroni SCBs, for studies using linear mixed modeling. Empirical coverage rates were obtained for data that was generated using simulations, to compare the accuracy of the Hunter-Worsley SCBs with that of the Bonferroni SCBs. The bounds were also applied to data in the field of alcohol research, where comparisons were made to determine the moderating effect …

3-D Structure Of Colombia From 1-D Constrained Joint Inversion Of Receiver Functions And Surface Wave Dispersion, Nick Talavera

Open Access Theses & Dissertations

The country, Colombia, resides at the northwest corner of the South America with seismicity and volcanism due to the intersections of the Nazca, South America and Caribbean tectonic plates (Figure 1). The boundaries of the South America plate, on which Colombia lies, borders between 60 to 200 kilometers from its coasts. A dense spot of seismicity known as the Bucaramanga Nest has had many theories to explain its existence. Two tectonic microplates suspected in this region have not been well understood. With many mysteries of the behavior of the tectonic plates beneath Colombia, using new methods may shed light on …

Pre-Tuned Principal Component Regression And Several Variants, Pei Wang

Open Access Theses & Dissertations

The regression coecient estimates from ordinary least squares (OLS) have a low probability of being close to the real value when there is a multicollinearity problem in the design matrix. In order to combat this problem, many regularized methods have been introduced. Principal components regression (PCR) is an important analysis tool for dealing with multicollinearity and high-dimensionality. In conventional PCR, the rst step is to change the original predictors to orthogonal principal components (PC's) by a linear transformation. These PC's correspond to the eigenvalues which are sorted in a decreasing order. The next step is to regress the response on …

An Effective And Optimal Quality Control Approach For Green Energy Manufacturing Using Design Of Experiments Framework And Evolutionary Algorithm, Juan Alejandro Saavedra

Open Access Theses & Dissertations

Quality Control (QC) and Quality Assurance (QA) strategies vary significantly across industries in the manufacturing sector depending on the product being built. Such strategies range from simple statistical analysis and process controls, decision-making process of reworking, repairing, or scraping defective product. This study proposes an optimal QC methodology in order to include rework stations during the manufacturing process by identifying the amount and location of these workstations. The factors that are considered to optimize these stations are cost, cycle time, reworkability and rework benefit. The goal is to minimize the cost and cycle time of the process, but increase the …

Identifying Non-Classical Active Sites As A Tool For Enzyme Inhibition, Marisol Serrano

Open Access Theses & Dissertations

Chagas disease, caused by the parasite Trypanosoma cruzi, is an endemic life-threatening disease that affects mainly the heart. It remains the leading cause of heart failure in Latin American countries. Since current treatments against this parasite are highly toxic and somewhat ineffective, novel and more efficacious types of interventions are desired. Cruzain, identified as the major cathepsin for T. cruzi, plays a major role in the parasite's life cycle; making this enzyme very attractive for potential trypanocidal drugs discovery. The recombinant cruzain is synthesized as a zymogenic pro-protein (PCZN) which possesses a pro domain and a catalytic domain. In this …

Predicting The Water Quality Of Shallow Arctic Ponds Using Remote Sensing, Gabriela Tarin

Open Access Theses & Dissertations

Barrow, Alaska is in a region dominated by Arctic tundra of which a substantial part is covered by lakes and ponds. Despite their dominance in the landscape, freshwater ecosystems in the Arctic have been insufficiently studied. It is clear that furthering understanding of how Arctic water bodies are responding to warming will depend on the analysis of changes in the concentration of organic and inorganic constituents in the water; however, scientists are faced with the task of sampling many remote sites in a relatively hostile environment. Thus, the exploration and incorporation of remote methods for monitoring changes in water quality. …

Using Word Embeddings For Text Classification In Positive And Unlabeled Learning, Emmanuel Carlo Tafoya

Open Access Theses & Dissertations

Machine Learning is a sub-field of Artificial intelligence that aims to automatically improve algorithms by experience. It has been used successfully to solve various problems, such as playing checkers, or even as simple as word prediction when typing a sentence. These algorithms perform best with large amounts of training data. The more labeled data, the better a machine learning algorithm will be able to recognize patterns. However, the ideal scenario, where there is a large amount of labeled data available to train the algorithm, does not occur all the time. There are cases where labeling data is both time-consuming and …

Study Of No2 Photolysis Rate Coefficients For The Paso Del Norte Region, Pema Wangchuk

Open Access Theses & Dissertations

The photolysis of nitrogen dioxide is one of the most influential chemical processes in the formation of photochemical air pollution. In this study, we compared simulated and measured nitrogen dioxide photolysis rate coefficients (J_(NO_2 )) for the Paso Del Norte (PdN) region. The Tropospheric Ultraviolet-Visible (TUV) radiation transfer model was used to calculate J_(NO_2 ) values. The measurements of hemi-spherically integrated, spectrally resolved solar photon flux between the wavelengths 400 and 700 nm were used to obtain the photolysis rate coefficients for ã??NOã??_2. Results are presented for a selected episode on July, 2015. The work investigated the use of measured …

A New Test For The Mean Vector In High Dimensional Setting, Behzad Aalipur Hafshejani

Open Access Theses & Dissertations

Traditional statistical data analysis mostly includes methods and techniques to deal with problems in which there are many observations but a few variables. Nonetheless, the current inclination is toward more observations but also, toward more variables. Today's observations gathered on individuals are images, curves, or even movies. Unfortunately many traditional methods do not work well in high dimensional settings. As an example Hotelling's test which is well known and widely used in the literature does not work when it comes to high dimensional problems. Consequently statisticians are making an effort to find remedies or new approaches to multivariate mean testing. …

Effects Of Citric Acid Coated And Uncoated Cerium Oxide Nanoparticles In Tomato (Solanum Lycopersicum) Plants, Ana Cecilia Barrios

Open Access Theses & Dissertations

This research was performed to examine the physiological and biochemical effects of bare (nCeO2) and citric acid coated (nCeO2+CA) cerium oxide nanoparticles in tomato (Solanum lycopersicum). Plants were germinated and grown to full maturity in soil amended with 0-500 mg/kg and periodically analyzed using ICP-OES/MS and other spectroscopic and biochemical techniques. Although Ce in tissues increased as the external nCeO2 increased, there were no visible signs of toxicity. In mature plants, nCeO2 induced developmental changes and altered nutritional quality (essential elements) in fruits. On the other hand, nCeO2+CA affected fruit carbohydrate composition (sugars and starch). This study gives insights on …

Gravimetrically Characterizable Common Alkali Reducing Agents And Ligand Design Of A New Electron Rich Guanidinate, Efrain Maximiliano Castillo

Open Access Theses & Dissertations

SynThesis, isolation and characterization of 12 new alkali arenides was performed by the addition of the chelating base 18-crown-6. Electrochemistry, UV-vis/NIR spectroscopy and XRD studies were performed.

The incoorporation of an imidazolin-2-iminato group to the background of a guanidinate showed that this kind of ligand is electronically flexible and metal dependent. It was found that is more electron donating than some previously reported guanidinates and ketimine guanidinates.

Sedimentologic And Stratigraphic Analysis Of Synrift Siliciclastic Fluvial And Lacustrine Strata In The Lower Cretaceous Upper Yucca Formation, Indio Mountains, West Texas, Matthew Robert Fox

Open Access Theses & Dissertations

Outcrops of the upper Yucca Formation in the Indio Mountains near Van Horn, Texas provide temporal, tectonic, and climatic similarities to Lower Cretaceous, synrift, greenhouse pre-salt lacustrine strata along in the subsurface of the South Atlantic margin. These "pre-salt" strata hold prolific petroleum reservoirs but despite extensive seismic studies performed for regional scale hydrocarbon exploration in these lacustrine reservoirs, sedimentologic and stratigraphic analyses have rarely been published. The Upper Yucca Formation in the Indio Mountains contain lacustrine reservoir analogs that intertongue with fluvial and deltaic sandstones. Near Squaw Canyon, fluvial-deltaic sandstones are reduced in abundance to lacustrine carbonates by nearly …

Seismic Modeling, Rock Physics, Avo And Seismic Attribute Analysis For Illuminating Sandstone Facies Of The Late Ordovic Ian Mamuniyat Reservoir, R-Field, Murzuq Basin-Libya, Yousf Milad Abushalah

Open Access Theses & Dissertations

The Late Ordovician Mamuniyat Formation is the main hydrocarbon reservoir in the R-Field in Murzuq Basin, SW Libya. The Lower Mamuniyat, which is the only unit that was encountered in the study area, is composed of sandstone facies called Clean Mamuniyat and shaly sandstone facies called Dirty Mamuniyat. One major problem with the development of the R-Field is the difficulty of distinguishing the two units so this project was aimed to develop better methods for distinguishing between the two units of the Lower Mamuniyat. The other problem is to distinguish the transgressive shaly facies of the Bir Tlacsin, which has …

Forecasting Customer Electricity Load Demand In The Power Trading Agent Competition Using Machine Learning, Saiful Abu

Open Access Theses & Dissertations

Accurate electricity load demand forecasting is an important problem in managing the power grid for both economic and environmental reasons. The Power TAC simulation provides a platform to do research on smart grid energy generation and distribution systems. Brokers are the focus of the design task posed to developers by the system. The brokers work as self-interested entities that try to maximize profits by trading electricity across multiple markets. To be successful, a broker has to forecast the electricity demand for customers as accurately as possible so it can use this information to operate efficiently. My proposed forecasting method uses …

Creating Multi-Functional G-Code For Multi-Process Additive Manufacturing, Efrain Aguilera Jr

Open Access Theses & Dissertations

Additive manufacturing (AM) started over thirty years ago and with it a manufacturing revolution that moves industrial production into the personal home. With recent interest shifting into multi-functional parts fabricated through AM technologies, unified systems are being developed. Merging different manufacturing technologies into one single machine is a challenge but undergoing research has shown promise in the development of multi-functional systems. Concurrent work is being done in the software, automation, and hardware aspect of multi-functional systems. An effort to use industry compatible Computer Aided Design (CAD) software to design multi-functional parts including circuits, micro-machining, and foil embedding then exporting and …

Dft Study On The Structure And Properties Of Vsc2n@C68, Surendra Bhatta

Open Access Theses & Dissertations

A computational study on the structure and electronic properties of the VSc2N@C68 molecule was carried out using the density functional theory. This molecule is based on the recent report on the synThesis of the VSc2N@C80 and V2ScN@C80 fullerenes. The Sc3N@C68 is also a stable endohedral fullerene that has a cage with fuse pentagonal rings. The doping by a V atom changes the structure as well as the spin state of the Sc3N@C68 from S=0 to S=1 state. Since the C68 has 6332 isomers, we have carried out an extensive search for the lowest energy structure of the C68 in several …

Evidence Of Active Rifts In The Southwest United States Using Geophysical Inversion Of Seismic Data, Sergio H. Celis

Open Access Theses & Dissertations

A continental rift represents a zone where the lithosphere has become thinner due to extensional forces associated with plate tectonics. Many of these rifts are still active, such as the East Africa rift, while others appear to be failed rifts. I build upon recent results of crustal structure for the southern section of the Rio Grande Rift using seismic data collected by USArray stations, and extend the analysis into the states of New Mexico, Oklahoma, Arkansas, and Louisiana to investigate the differences between active and failed rifts in the state of Texas. I collect two geophysical data sets, including receiver …

Sparse Matrix Diagonalization In The Nrlmol Electronic Structure Code, Md Mahmudulla Hassan

Open Access Theses & Dissertations

Density functional theory (DFT) based simulations are playing a major role in quantum mechanical studies of materials ranging from molecules, nanoparticles to the biological systems as they offer insights that are not directly accessible from experiments and also due to their ability to make sufficiently accurate predictions. The DFT implementation in the NRLMOL electronic structure code employs Gaussian basis sets to express the Kohn-Sham orbitals. A major computationally demanding task in the electronic structure calculations is solution of the generalized eigenvalue problem, that is the determination of nontrivial solutions (λ, c) of Hc = λOc where H and O are …

Controls On Carbonate Sedimentation And Sequence Stratigraphic Framework Of The Lower Permian (Wolfcampian) Hueco Formation (Upper-Middle And Gastropod Intervals), Robledo Shelf, Western Orogrande Basin, New Mexico, Matthew S. Harder

Open Access Theses & Dissertations

On the western margin of the Pennsylvanian/Permian Orogrande Basin, two composite measured sections in the Lower Permian upper interval of the Middle Member of the Hueco Limestone were analyzed in regards to depositional environment, facies and sequence stratigraphy. This can elucidate where potential unconventional reservoirs can be found in the Wolfcamp Shale of the Permian Basin. Based on these analyses, 12 lithofacies were identified, including 9 carbonate lithofacies: 1) fenestral dolomudstone, 2) peloidal dolomudstone, 3) ostracode foraminifera packstone, 4) foraminifera peloidal grainstone, 5) skeletal intraclast grainstone, 6) phylloid algal peloidal grainstone, 7) echinoderm phylloid algal packstone, 8) echinoderm bivalve brachiopod …

Regional Geochemical Mapping Of The Superior Upland Province; Ichnology Of The Cretaceous Mesilla Valley Formation, Cerro De Cristo Rey; A New Ichnospecies Of Cardioichnus From The Cretaceous (Albian) Of New Mexico; A Pedagogy For The Cerro De Cristo Rey Tracksite; Walking In The Footprints Of Dino, Eric J. Kappus

Open Access Theses & Dissertations

This is a multi-disciplinary study that covers a variety of geoscience topics on both international borders of the continental United States. This Dissertation is the product of several separate investigations. First is a report on the landscape geochemistry of the Superior Upland Province of Minnesota, Wisconsin, and Michigan, with regional maps of 37 chemical elements interpreted in terms of bedrock, glacial reworking, and anthropogenic influence. The next 2 sections are reports on the invertebrate ichnology of the Cretaceous Mesilla Valley Formation at Cerro de Cristo Rey, including the proposal of a new ichnospecies of echinoid resting trace, Cardioichnus biloba nov. …

Spatiotemporal Variability Of Plant Phenology In Drylands: A Case Study From The Northern Chihuahuan Desert, Naomi Robin Luna

Open Access Theses & Dissertations

With global change, which includes climate change, there is a sense of urgency to understand how shifts in climate will affect ecosystems. Although several studies have improved understanding of how and why some ecosystems respond, most studies have not explored simultaneous responses of different land cover types throughout a given region. Dryland ecosystems, such as the Chihuahuan Desert, appear to respond to climate variability and currently make up about 40% of global land surface area. It is expected that drylands will expand to cover 60% of land surface area on earth by mid-century making this ecosystem more critical to global …

The Origin Of Anomalous Carbonate Units Outcropping At The Salt Sediment Interface Of The Southern End Of Gypsum Valley Salt Wall, Paradox Basin, Colorado, Allison M. Mast

Open Access Theses & Dissertations

Understanding structural, stratigraphic, and petrographic complexities at the salt-sediment interface of diapirs has important implications in accurately assessing hydrocarbon reservoir quality and near-diapir trap geometries, and may aid in more accurate predictions for locating the true margin of salt in diapiric layered evaporites. The southwest margin of the exhumed Gypsum Valley Salt Wall, Paradox Basin, southwest Colorado, provides a rare view of this interface where onlapping and overlapping wedges of Late Permian and Jurassic halokinetic sequences overlie an angular unconformity truncating near-vertical, highly deformed carbonate beds formerly mapped as Pennsylvanian Honaker Trail Formation. This study investigates three possible alternative origins …

Geology And Mineralization Controls Surrounding The Palmarejo Mining District - A Compilation Of Remote And Hands On Exploration Techniques, Castulo Molina Sotelo

Open Access Theses & Dissertations

Exploration is the base of the mining industry, and it is often taken as synonymous with "finding a mine". In reality it is a more complex process; where the selection, evaluation, screening and testing of successively smaller areas lead to the discovery of an economic deposit. Once the deposit is found, the economic factors become more important than the geological ones, and then the exploration becomes a tool to give sustainability to the mining operation through time.

The silver and gold deposits of the world-class Palmarejo District are typical, intermediate sulfidation- style epithermal, precious metal occurrences, hosted in Cretaceous- to …

A Geophysical Investigation At The Potrillo Maar, Manuel Moncada Gutierrez

Open Access Theses & Dissertations

The Potrillo Volcanic Field (PVF) is a unique geological site located in Doña Ana County the southernmost part of New Mexico, and part of northern part of Chihuahua, Mexico. The main feature of the southern PVF is Potrillo Maar. This maar-volcano straddles the international boundary between United States and Mexico and lies within the southern part of the Rio Grande Rift. The Potrillo Maar was formed about 20,000 years ago in three major events that formed basalt lava flows and ejecta deposits that consist of crustal and mantle xenoliths.

The purpose of this Thesis is to determine the area of …

Evaluating The Effects Of The Phytohormone Indole-3-Acetic Acid In The Response Of Green Pea (Pisum Sativum L.) To Nanoscale Cuo Exposure In Soil, Loren Ochoa

Open Access Theses & Dissertations

The response of plants to copper oxide nanoparticles (nCuO) in presence of the phytohormones such as IAA, is unknown. In this study, green pea (Pisum sativum) plants were cultivated to full maturity in soil amended with nCuO, CuO bulk (bCuO), and CuCl2 at 50 and 100 mg/kg and indole-3-acetic acid (IAA) at 10 and 100 µM. Several analytical techniques were used to evaluate the effects of treatments in the agronomical, physiological, and biochemical effects of treatments. Results showed that only CuCl2 reduced root length and number of leaves. Root copper (Cu) increased in plants exposed to nCuO without IAA; however, …