Physical Sciences and Mathematics Commons^™

2023 Celebration Of Scholarship, Creativity, And Engagement, Todd Bruns, Diane Highland

Programs

Annually, Eastern Illinois University honors faculty achievements in the areas of research, creativity, and engagement. This year, the list of faculty accomplishments is again truly impressive, reflective of an engaged faculty committed to excellence and the ongoing pursuit and creation of knowledge. A number of these accomplishments occurred in collaboration with our students, who serve as co-authors, research assistants and partners in bringing these activities to fruition. Indeed, in some cases these professional ambitions transpired over the course of many years, and are a testament to persistence and tenacity--ensuring that these works extend to a broader community of scholars that …

Graduate, 2nd Place: Assessing The Knowledge, Attitude, And Everyday Life Practices Adopted Among Eastern Illinois University Students Towards Sustainability, Joel Holison

2023 Awards for Excellence in Student Research and Creative Activity - Documents

The concept of sustainable development gained attention and came into focus with the publication of the Brundtland Report (Brundtland, 1987). later the Education for Sustainability (EfS) initiative was presented in 1997 through the “Thessaloniki Declaration” as a carrier of the common and single message (Knapp, 2000). Sustainable development is the way a country pursues its economic development that does not jeopardize the opportunity for future generations to achieve their development (Brundtland, 1987). Deforestation, land destruction, soil degradation, air and water pollution, and other types of environmental deterioration are paid in the name of economic progress. This detriment may outweigh the …

Graduate, 3rd Place: A Comparative Analysis Of Sustainability Report Communication In The Consumer Goods Industry, Nancy Ladeinde

2023 Awards for Excellence in Student Research and Creative Activity - Documents

Sustainability reports are communicated in areas visible to stakeholders. One of such areas is corporate social responsibility. Sustainability reports have the function of image enhancement and trust building for organizations, particularly for those in the consumer goods industry. Advancing the research on corporate social responsibility, this study examines how consumer goods organizations communicate their sustainability/impact activities by comparing three large global organizations. The paper is premised on legitimacy and stakeholder theories and reviews the six ESG reports through content analysis. The comparative analysis of a two-year report of these organizations shows differences in patterns and language used in the ESG …

Assessing The Knowledge On Sustainability And Barriers To Daily Sustainable Practices Among Faculty And Students In Higher Education: The Case Of Eastern Illinois University, Joel Edem Holison

Masters Theses

The concept of sustainable development gained prominence with the publication of the Brundtland Report, which emphasized economic progress without jeopardizing future generations' well-being. Following that, the Education for Sustainability (EfS) program was created by the United Nations to raise sustainability awareness. However, the transition to sustainable living is fraught with difficulties, including a lack of knowledge, financial constraints, infrastructure gaps, and political ideologies. This study focuses on sustainable practices among Eastern Illinois University (EIU) students and faculty, as well as the barriers to daily sustainable behaviors. As independent variables influencing sustainable practices, the study evaluates sustainability knowledge/awareness, personal financial situation, …

2022 Celebration Of Scholarship, Creativity, And Engagement, Todd Bruns, Beth Heldebrandt

Programs

At this annual celebration, the entire Division of Academic Affairs is pleased that the important work of faculty continues and evolves as EIU’s professors have individually and collectively redefined the boundaries of scholarship, creativity, and innovation for the emerging post-COVID era. Indeed, we are excited to come together to celebrate the achievements and outstanding contributions of our colleagues and students to their disciplines and professions. And, as the following pages illustrate, faculty have engaged in continuing scholarly and creative activities that have provided outstanding mentoring experiences for our undergraduate and graduate students.

In addition to sharing faculty productivity, research excellence …

Low-Head Dam Removal Increases Functional Diversity Of Stream Fish Assemblages, Adam Christopher Jones

Masters Theses

Despite the growing number of dam removals to date, very few have been studied to understand their impacts on stream fish communities. Despite being the most common type of dam in the U.S., an even smaller proportion of studies focus on the impacts of low-head dam removals, instead, focusing on the impacts of removal of larger dams. In this study, two previously impounded Illinois rivers were monitored to assess the impacts of low-head dam removal on the functional assemblage of stream fishes. This was accomplished by aggregating fishes into habitat and reproductive guilds, relating community changes to habitat, environmental metrics, …

Pd-Based Photocatalysts For Heck C-C Cross-Coupling Reactions, Suha Ali Alshehri

Masters Theses

Heck C-C cross-coupling reaction has been widely employed in synthetic organic chemistry because of its high efficiency and simplicity, however the conventional Heck C-C cross-coupling reaction conditions involve the use of an expensive toxicant phosphine-ligated palladium complexes, and high temperature. To address these drawbacks, a highly efficient, homogeneous photocatalyst based on BODIPY for the Heck C-C cross-coupling reactions of aryl iodide and methyl acrylate in DMF solvent under inert conditions has been developed. The 4-Py-BDP-Pd, 3-Py-BDP-Pd and, 2-Py-BOD-Pd catalysts were synthesized and purified using column chromatography. The optical properties of products and intermediates were studied by UV/vis absorption and fluorescence …

2021 Celebration Of Scholarship, Creativity, And Engagement, Todd Bruns, Beth Heldebrandt

Programs

At this annual celebration, we, as a shared community, are pleased that the important work of faculty continues and evolves as faculty have broadened and redefined the boundaries of scholarship, creativity, and innovation throughout the COVID, late-COVID, and soon-to-be post-COVID eras. While we are pleased to return to more familiar campus-based traditions, functions, and activities, the experiences of 2020-2021 have contributed to the development of new forms and strategies for scholarship and creativity that reflect the core principles of faculty life and ensure that student learning remains central to the mission of Eastern Illinois University.

For that reason, our faculty, …

Synthesis And Characterization Of A Two Station Starburst Pseudorotaxane, Janaka Prasad Kaviraj Kavikarage

Masters Theses

Mechanically interlocked molecules (MIMs) are arranged with mechanical bonds. These molecules cannot be separated without breaking the required covalent bonds. There are different kinds of MIMs, such as rotaxanes, catenanes, suitanes, borromean rings, and molecular knots. These MIMs are stabilized by non-covalent interactions such as hydrogen bonds, π-π stacking, and ion-dipole interactions. Dialkylammonium ions, bis(pyridinium)ethane dications, viologen species, and naphthalene diimide π-deficient groups are typical examples of recognition motifs for crown ethers.

In the research described here, we synthesized a new axle, based on a combination of benzobis(imidazolium) (BBI) and viologen species. The axle contains two recognition sites: one is …

Metal Complexes Of Bis(Pyrazolyl)Methane-Based Ditopic Ligands, Pubudu Nuwan Perera Hapuarachchige

Masters Theses

No abstract provided.

A Novel Palladium Bodipy Photocatalyst For Sonogashira Carbon-Carbon Cross-Coupling, Prahadeesh Nagaretnam

Masters Theses

No abstract provided.

Cheeger Constants Of Two Related Hyperbolic Riemann Surfaces, Ronald E. Hoagland

Masters Theses

This thesis concerns the study of the Cheeger constant of two related hyperbolic Riemann surfaces. The first surface R is formed by taking the quotient U²/Γ(4), where U² is the upper half-plane model of the hyperbolic plane and Γ(4) is a congruence subgroup of PSL2(Z), an isometry group of U² . This quotient is shown to form a Riemann surface which is constructed by gluing sides of a fundamental domain for Γ(4) together according to certain specified side pairings. To form the related Riemann surface R' , we follow a similar procedure, this time taking the …

2020 Celebration Of Scholarship, Creativity, And Engagement, Todd Bruns, Beth Heldebrandt

Programs

The 2020-2021 academic year is truly extraordinary and higher education’s new, hopefully temporary, normal began on rather short notice in Spring 2020. While our environment has changed, we, as a shared community, are pleased that the important work of faculty continues and evolves as faculty broaden and redefine the boundaries of scholarship, creativity, and innovation in accelerating hybrid and remote environments. And, as new forms and strategies for scholarship and creativity emerge, the core principles of faculty life and student learning remain central to the mission of Eastern Illinois University.

For that reason, our faculty, department chairs, college deans, the …

A Perspective On Changes Across The U.S. Corn Belt, Eric Hunt, Hannah Birge, Christopher Laingen, Mark Licht, Justin Mcmechan, William Baule, Tom Connor

Faculty Research and Creative Activity

No abstract provided.

A Study On Real-Time Database Technology And Its Applications, Geethmi Nimantha Dissanayake

Masters Theses

No abstract provided.

Design, Synthesis, And Characterization Of Chemical Tools To Study Peroxisomal Import, Jhalak N. Timilsena

Masters Theses

Peroxisomes are dynamic and interconnected single lipid membrane bound organelles found in the eukaryotic cells which are involved in various biochemical processes including the b-oxidation of very long chain and branched chain fatty acids, metabolism of reactive oxygen and nitrogen species, and reduction of hydrogen peroxide among others. These organelles are known to host numerous proteins and enzymes depending on the cellular environment. All of the proteins needed in the peroxisomes are encoded in the nucleus and synthesized in the cytosol which are then transported to the peroxisomes with the help of a sophisticated protein-transport machinery. Pex5 is one of …

Synthesis And Characterization Of Starburst Pseudorotaxanes And Their Metallic Derivatives, Shalini D. Kadinappulige

Masters Theses

Mechanically Interlocked Molecules (MIMs) are interlocked molecular architectures, characterized by the fact that they are linked through a mechanical bond. Catenanes, rotaxanes, molecular knots, and Borromean rings are typical examples for these molecules. Since MIMs are not connected by covalent bonds, hydrogen bonding, π- π stacking, and/or electrostatic interactions help bring the components together. Dialkyl-ammonium centers, bis(pyridinium)ethane dications, viologen species, and naphthalenediimide π-deficient groups are well known as recognition motifs for crown ethers. In the research described here, we have synthesized several pseudorotaxanes and their tricyclohexyltin metallic derivatives, based on benzobis(imidazolium) (BBI) salts as axles, in combination with the 15DN38C10 …

2019 Celebration Of Scholarship, Creativity, And Engagement, Beth Heldebrandt, Todd Bruns, Seth Yeakel, Matthew Eifrid

Programs

Scholarship, creativity, innovation, and the many forms of collaborative engagement that shape faculty life and student learning are central to the mission of Eastern Illinois University. For that reason, our faculty, department chairs, college deans, the Provost, and the entire campus community celebrate the achievements and outstanding contributions of our colleagues and students to their disciplines and professions every year. And, as the following pages illustrate, faculty engaged in continuing scholarly and creative activities that have provided outstanding mentoring experiences for our undergraduate and graduate students.

In addition to recognizing faculty performances, shows, publications, grants and other professional efforts, the …

A Systematic Review Of Blockchain Research And Applications In Business, Prinsa Roka

Undergraduate Honors Theses

Blockchain, well-known as the Distributed Ledger Technology (DLT) behind cryptocurrencies such as Bitcoin, has attracted plenty of attention from both practitioners and academics and has begun to revolutionize the way businesses handle their day-to-day operations. DLT leads to many interesting new research topics in different business fields. In this study, we applied the systematic mapping method to review existing articles related to blockchain applications and research in different business areas (accounting, finance and banking, information systems, marketing and supply chain). Our goal is to understand the current applications and research status related to blockchain, so that we can identify research …

Variation In Leaf Morphology Of An Alpine Shrub Community Along Environmental Gradients, Abdulssalam Khafsha

Masters Theses

Mountains represent complex environment gradients which strongly affect local temperature regimes and rainfall. These changes in climate conditions drive a diversity of plant responses. As alpine environments are expected to change dramatically in response to climate change, understanding plant responses to environmental variation is critical in these environments. Although they are a critical component of alpine communities, the environmental responses of shrubs have been much less examined than trees, representing an important knowledge gap. Leaves, as the primary photosynthetic organs on plants, would be expected to respond strongly to local climate conditions. In this study, I documented how the leaf …

Synthesis, Characterization And Mechanistic Studies Of Biomimetic Dinuclear Copper(Ii) Complexes, Millaniyage Nuwanthaka Prasad Jayaweera

Masters Theses

Dinuclear copper complexes are significant synthetic targets due to their use as model compounds for the active sites of type 3 copper proteins like catechol oxidase. A distinct class of ligands used in these studies are built on a phenol core to witch various donor side-arms were appended at the 2 and 6 positions of the arene ring. In our quest to quantify the influence of electron donating or withdrawing groups attached to the central arene ring, we have designed a set of ligands that, upon coordination to copper(II) centers, would produce complexes of the general structure. During this research …

Using A Discursive Framework To Analyze Geometric Learning And Instruction, Peter Wiles, Rick Anderson

Faculty Research and Creative Activity

In this study we applied a discursive perspective of learning (Sfard, 2008) to a sequence of 21 geometry mini-lessons taught in a fourth grade classroom. From this perspective, learning is defined as changes in mathematical discourse. We first characterize and then compare discourse from the beginning and the end of the mini-lesson sequence. We identify shifts in the discourse that occurred during the sequence. We then discuss how the characteristics of the st geometric discourse informed task design and instruction. This perspective provided a useful means for linking instruction to student learning in an operationalized manner.

Developing A Basket-Shaped Host Molecule Based On P-Tert-Butylcalix[4]Arene Featuring Urea Groups For Encapsulating Volatile Guest Molecules, Lokugama Widanelage Vidula Priyadarshana

Masters Theses

Molecular baskets are a group of synthetic host molecules which are designed to govern the inclusion of small guest molecules. The basic structural features of basket-shaped host molecules are a cavity for holding a much smaller guest molecule and tunable gates for keeping the guest molecule inside. These types of gates can be tuned by changing temperature, concentration, pH, etc. In this research group's previous study, a molecular basket of cal ix[ 4]arene with carboxylic acid groups was synthesized by functionalizing calix[4]arene's phenol hydroxyl groups with benzyl bromide building blocks. In the study detailed here, 1 , l '-((5-(bromomethyl)-1,3-phenylene)bis(methylene))bis(3-isopropylurea) was …

Solvation Properites Of Supercritical Carbon Dioxide Using Chirped-Pulse Fourier-Transform Microwave Spectra Of Carbon Dioxide / 1, 1-Difluoroethene (Dfe) Mixtures, Tulana Ariyaratne Subasinghe Arachchige

Masters Theses

Supercritical carbon dioxide (sc-C0₂) is a highly utilized industrial substance identified as an excellent solvent and a surfactant, which is cheaper and less hazardous than other typical solvents. The higher solubility of fluorinated hydrocarbons than their hydrocarbon (HC) analogs is not well understood and the theory behind the microsolvation of sc-C0₂ cannot be fully explained with the existing chemical information. Microwave spectroscopy is a good method of identifying the structural arrangement of clusters made from fluorinated HCs and C0₂. I n this project, microwave scans of the four different mixtures of 1 , 1-difluoroethene (DFE) …

Studying Carbon Dioxide Solvent Properties By Microwave Spectroscopic Investigations Of Vinyl Fluoride/Carbon Dioxide Clusters And Developing New Approaches To Decode Rotational Spectra, Prashansa Kannangara

Masters Theses

Supercritical carbon dioxide (sc-C0₂) is an excellent green solvent, but its properties are not thoroughly understood. For example, fluorinated compounds have higher than expected solubility in sc-C0₂. Microwave spectroscopy is one way to learn more about sc-C0₂ because it can be used to determine detailed structures of small clusters of molecules. The purpose of this investigation was to study weak hydrogen bonding interactions in complexes of fluorinated ethylene (solute) with carbon dioxide (C0₂, solvent). Investigations on dimers with one C0₂ molecule and fluorinated ethylene were carried out previously and found two different …

Impacts Of Plant-Microbe Interactions On Seedling Performance In A Riparian Forest Invaded By Lonicera Maackii, Taylor E. K. Strehl

Masters Theses

Soil microbes have profound impacts on plant growth and survival and can either promote or inhibit plant dominance. Exotic plants are often strongly invasive because they have escaped their natural enemies, potentially including antagonistic soil microbes. I examined how the invasive shrub Lonicera maackii and a common native tree, Acer negundo, responded to soil microbial communities to determine the role of soil microbes in regulating invasion success. This was done by growing both species with microbes from invaded (L. maackii) and uninvaded (A. negundo) soils collected from three locations within a riparian forest. Seedlings were …

Synthesis Toward A Molecular Container Based On P-Tert-Butylcalix[4]Arene With Gate Features, Balasooriya Appuhamilage Dinesh Madushan Balasooriya

Masters Theses

Nowadays molecular and supramolecular chemistry have endless examples for the development of smart devices. Among those applications, nano-baskets of calixarenes play vital roles in host-guest chemistry. One of the main appealing concepts of this field is the development of host molecules with gate features. These hosts are designed and constructed for the delivery of chemical or biochemical species that are volatile, or reactive, or sensitive to normal solution environment and they are mainly functioned by predefined groups that are responsive toward stimuli such as concentration, temperature, pH and so on. In our previous study, we found that benzyl bromides can …

Hidden Symmetries In Classical Mechanics And Related Number Theory Dynamical System, Mohsin Md Abdul Karim

Masters Theses

Classical Mechanics consists of three parts: Newtonian, Lagrangian and Hamiltonian Mechanics, where each part is a special extension of the previous part. Each part has explicit symmetries (the explicit Laws of Motion), which, in turn, generate implicit or hidden symmetries (like the Law of Conservation of Energy, etc). In this Master's Thesis, different types of hidden symmetries are considered; they are reflected in the Noether Theorem and the Poincare Recurrence Theorem applied to Lagrangian and Hamiltonian Systems respectively.

The Poincare Recurrence Theorem is also applicable to some number theory problems, which can be considered as dynamical systems. In …

Complex Varieties As Minima, Richard Koss

Masters Theses

We will explore various numeric methods of finding roots of an analytic function over some open set of the complex plane. We will discuss a method of visually observing the roots, a gradient descent method for finding the roots of an analytic function, a gradient descent method for solving systems of analytic functions, and finally a method of descent that uses osculating circles to find roots of an analytic function. Of particular interest to this thesis are roots of complex polynomials. There will be examples, code snippets, and outputs of programs to illustrate all of these methods.

The Impact Of Dutch Disease: The Case Of Nigeria, Halimat Atinuke Laguda

Masters Theses

Nigeria, over the years, has been showing a rapid appreciation of the domestic currency, a rise in real wages and the service sector and a slow-down in the industrial production which are all signs of presence of Dutch disease which predicts that a country with large natural resource rents may experience a de-industrialization and a lower long term economic growth. This paper analyses the impact of Dutch disease in Nigeria Ordinary Least square method, Two-Stage Least Square and Autoregressive Distributed Lag with a system of equation from 1981 to 2017 and found that the real wage rate emphasizes on the …