Physical Sciences and Mathematics Commons^™

Origin Of Blue Ridge Basement Rocks, Dellwood Quad, Western Nc: New Evidence From U-Pb Zircon Geochronology And Whole Rock Geochemistry, Donald Franklin Loughry Jr.

University of Kentucky Master's Theses

Terrane discrimination in polycyclic continental basement rocks is challenging due to high-grade metamorphism and intense deformation. Based on early USGS mapping the Blue Ridge basement in the Dellwood quadrangle of the eastern Great Smoky Mountains was proposed to consist of augen orthogneisses of Laurentian (Grenvillian) affinity interfolded with migmatitic hornblende and biotite paragneisses (“Carolina Gneiss”) and amphibolites of uncertain affinity. However, detailed study reveals that the hornblende gneiss of Hadley and Goldsmith (1963) is a heterogeneous map unit consisting of (1)metaplutonic rocks; (2) variably foliated and folded felsic orthogneisses; (3) strongly migmatitic, folded Hbl+Bt-bearing gneisses; (4) foliated and lineated garnet …

Synthesis, Characterization And Development Of Catalysts For Co2 Capture, Anitha Suhas Wishrojwar

University of Kentucky Master's Theses

Fossil fuel and advanced industrialization techniques contribute to global warming through emissions of greenhouse gases such as CO₂. In order to mitigate climate change, there is a desperate need to reduce CO₂ emissions from different sources. CO₂ capture and sequestration (CCS) play an important role in these reductions.

Naturally occurring enzymes, e.g., carbonic anhydrase (CA), can catalyze these reactions in living systems. Much effort has been focused on complexes of zinc with ligands such as teta, cyclen and tripodal ligands including BIMA and Trispyrazolylborates. These complexes have many interesting CO₂ capture properties, but maintain toxic …

Effects Of Livestock Antibiotics On Nitrification, Denitrification, And Microbial Community Compositon In Soils Along A Topographic Gradient, Sagarika Banerjee

University of Kentucky Master's Theses

Several types of antibiotics (roxarsone, virginiamycin, and bacitracin) are widely included in poultry feed to improve animal growth yields. Most of the antibiotics are excreted in manure which is subsequently applied to soils. One concern with this practice is that antibiotics may affect several microbially-mediated nutrient cycling reactions in soils that influence crop productivity and water quality. The main objectives of this study were to determine the effects of livestock antibiotics on nitrification, denitrification, and microbial community composition in soils along a topographic gradient. These objectives were addressed in a series of lab experiments by monitoring changes in inorganic N …

Feasibility Of Using 15N-Enriched Escherichia Coli As A Bacterial Tracer In The Cane Run/Royal Spring Basin, Kentucky, John G. Warden

University of Kentucky Master's Theses

A novel tracer method has used ¹⁵N to label Escherichia coli and track the transport of bacteria, a common contaminant, through karst aquifers. Use of this method could provide valuable insight into the movement of bacteria in aquifers, which would help improve remediation methods and strategies. A wild strain of E. coli was isolated from the Cane Run/Royal Spring basin in the Inner Bluegrass region of Kentucky. The strain was serotyped O^-:H^- and virulence testing showed the strain did not have virulence factors of E. coli commonly pathogenic to humans. Five karst microcosms were filled with …

Chromium, Copper, And Arsenic Concentration And Speciation In Soil Adjacent To Chromated Copper Arsenate (Cca) Treated Lumber Along A Topohydrosequence, Donald Roy Schwer Iii

University of Kentucky Master's Theses

Arsenic (As), Chromium (Cr), and Copper (Cu) are ubiquitous in soils as a result of anthropogenic and geogenic processes. The fate of As, Cr, and Cu in the environment is largely governed by their speciation, which is influenced by soil physiochemical properties. This study investigated the influence of soil physiochemical properties and landscape position on As, Cr, and Cu concentration and speciation in soils adjacent to Chromated Copper Arsenate (CCA) treated lumber fence posts. Concentration gradients showed elevated total As and Cu adjacent to the three fence posts, which decreased with increasing distance from the posts. In addition, As and …

Soil- And Groundwater-Quality Data For An Abandoned Cattle And Hog Feedlot In Henderson County, Kentucky, E. Glynn Beck, James S. Dinger, Eugenia Pena-Yewtukhiw, John H. Grove

Information Circular--KGS

Groundwater samples collected from a livestock well in southwestern Henderson County, Ky., contained nitrate-N concentrations greater than 20 mg/L, two times the U.S. Environmental Protection Agency’s maximum contaminant level. The well is located in an abandoned cattle and hog feedlot. The feedlot is located in an upland bedrock setting with Pleistocene loess overlying Pennsylvanian bedrock. One hundred twenty-one soil cores were collected to better define the areal extent of organic-rich soil believed to be the source of the elevated nitrate-N in the groundwater. Cores were collected on 25-ft centers to a depth of 4 ft below the land surface. Soil …

Assessment Of Row Crop, Alfalfa, And Pasture Field Practices On Groundwater Quality In An Upland Bedrock Setting, Henderson County, Kentucky: Report Of Soil- And Water-Quality Data, E. Glynn Beck, James S. Dinger, John H. Grove, Eugenia Pena-Yewtukhiw

Information Circular--KGS

An assessment of how present agricultural practices have influenced shallow groundwater and soil quality was conducted on a 540-acre farm in north-central Henderson County. Groundwater- and soil-quality data were collected from row crop (corn and soybean), alfalfa, and pasture fields. In addition to the field settings, groundwater and soil data were collected from the existing farmyard and an abandoned feedlot. Groundwater samples were analyzed for pH, specific conductance, temperature, oxidation-reduction potential, metals, anions, nutrients, herbicides, and various isotopes. Soil samples were analyzed for pH, bioavailable phosphorus, potassium, calcium, magnesium, zinc, organic matter, total nitrogen, and inorganic nitrogen (nitrate-N). Soil- and …

Assessment Of Groundwater Quality In An Abandoned Feedlot, Henderson County, Kentucky: Data Report, E. Glynn Beck, James S. Dinger, John Grove, Eugenia Pena-Yewtukhiw

Information Circular--KGS

A three-phase project investigated the influence of past and present agricultural practices on groundwater resources in the Western Kentucky Coal Field. Phase II concentrated on past practices, specifically those associated with an abandoned dairy feedlot and an old homestead. Results of phase II analyses are presented in this report.

Sources And Occurrences Of Nonpoint-Source Chemicals In Groundwater, Jackson Purchase Region, Kentucky: Data Report, E. Glynn Beck

Information Circular--KGS

Groundwater from the Jackson Purchase Region was sampled to investigate possible contamination by nonpoint-source chemicals. Conclusions drawn from the resulting data and methodology can be found in “Sources and Occurrences of Nonpoint-Source Chemicals in Groundwater, Jackson Purchase Region, Kentucky,” Kentucky Geological Survey Report of Investigations 22 (series 12), by R.S. Fisher and E.G. Beck.

Inelastic Collisions In Cold Dipolar Gases, Catherine A. Newell

University of Kentucky Doctoral Dissertations

Inelastic collisions between dipolar molecules, assumed to be trapped in a static electric field at cold (> 10⁻³K) temperatures, are investigated and compared with elastic collisions. For molecules with a Λ-doublet energy-level structure, a dipole moment arises because of the existence of two nearly degenerate states of opposite parity, and the collision of two such dipoles can be solved entirely analytically in the energy range of interest. Cross sections and rate constants are found to satisfy simple, universal formulas. In contrast, for molecules in a Σ electronic ground state, the static electric field induces a dipole moment in …

Streamflow Prediction Using Gis For The Kentucky River Basin, Bakkiyalakshmi Palanisamy

University of Kentucky Doctoral Dissertations

The study was aimed at developing a simple methodology for flow prediction in ungauged basins using existing data resources. For this purpose, the streamflow measurements across the Kentucky River Basin located in Kentucky, USA were obtained from United States Geological Survey (USGS) archive. The flow transferring characteristics of the subbasins of the Kentucky River Basin were obtained by combining downstream and upstream stream gauges. The flow transferring function thus derived were related to watershed, channel and flow characteristics of the subbasins by multiple regression analysis. The gauge pairs were divided into two classes of subbasins representing Upper and Lower Kentucky, …

Physical Conditions Including Magnetic Fields In Several Star Forming Regions Of The Galaxy, Matt Lykins

University of Kentucky Doctoral Dissertations

This document describes studies of two independent regions of the interstellar medium (ISM). These studies have the common element that both pertain to regions in our Galaxy that are known to be associated with present-day star formation. These studies aim to help us understand the ISM, star formation, and ultimately where we came from, since, after all, our star, the Sun, is itself the product of star formation 4.5 billion years ago. The first project measured the Zeeman Effect on the 21 cm H I absorption line in order to create a map of the line of sight magnetic fields …

Nonparametric Estimation Of Derivatives With Applications, Benjamin Hall

University of Kentucky Doctoral Dissertations

We review several nonparametric regression techniques and discuss their various strengths and weaknesses with an emphasis on derivative estimation and confidence band creation. We develop a generalized C(p) criterion for tuning parameter selection when interest lies in estimating one or more derivatives and the estimator is both linear in the observed responses and self-consistent. We propose a method for constructing simultaneous confidence bands for the mean response and one or more derivatives, where simultaneous now refers both to values of the covariate and to all derivatives under consideration. In addition we generalize the simultaneous confidence bands to account for heteroscedastic …

Remaining Resources Of The Springfield Coal, Gerald A. Weisenfluh

Map and Chart--KGS

Historically, the Springfield (W. Ky. No. 9) opal bed has been the leading source of coal production in the Western Kentucky Coal Field. With 2009 production more than 21 million tons and another 8 million tons of idle capacity, it is also the most important resource in the state of Kentucky. The Springfield coal is known for its lateral continuity in terms of both thickness and quality. It is a medium-sulfur product, desirable for power plants with sulfur-reduction capability, and has higher Btu values and lower chlorine contents compared to other Illinois Basin areas north of Kentucky. It is estimated …

A Trusted Storage System For The Cloud, Sushama Karumanchi

University of Kentucky Master's Theses

Data stored in third party storage systems like the cloud might not be secure since confidentiality and integrity of data are not guaranteed. Though cloud computing provides cost-effective storage services, it is a third party service and so, a client cannot trust the cloud service provider to store its data securely within the cloud. Hence, many organizations and users may not be willing to use the cloud services to store their data in the cloud until certain security guarantees are made. In this thesis, a solution to the problem of securely storing the client’s data by maintaining the confidentiality and …

Assessment Of Groundwater Quality In A Remediated Abandoned Feedlot, Henderson County, Kentucky: Data Report, E. Glynn Beck, James S. Dinger, John Grove, Eugenia Pena-Yewtukhiw

Information Circular--KGS

A three-phase project investigated the influence of past and present agricultural practices on groundwater resources in the Western Kentucky Coal Field. Phase III concentrated on an abandoned dairy feedlot that had been remediated. Results of phase III analyses are presented in this report.

Sources And Occurrences Of Nonpoint-Source Chemicals In Groundwater, Jackson Purchase Region, Kentucky, R. Stephen Fisher, E. Glynn Beck

Report of Investigations--KGS

Nitrate concentrations that exceed U.S. Environmental Protection Agency drinking-water standards have been reported in Jackson Purchase Region groundwater since the 1960's. More recently, other nonpoint-source chemicals such as pesticides and volatile organic compounds have also been found. The sources of these chemicals and the pathways by which they reach domestic groundwater supplies must be determined to protect human health and to design effective land-management practices.

To investigate the occurrence of nonpoint-source chemicals in Jackson Purchase groundwater, 60 wells were selected on the basis of geographic location, hydrostratigraphic unit penetrated, and well type (bored or drilled); distances to row crops, known …

Ground Motion For The Maximum Credible Earthquake In Kentucky, Zhenming Wang

Report of Investigations--KGS

Although they are not frequent, earthquakes occur in and around Kentucky and pose certain hazards. Assessing seismic hazards is challenging, however, because of a lack of observations. The best estimates of ground motions that could be expected if the maximum credible earthquake occurs in or around Kentucky are depicted in maps showing peak ground acceleration and short-period (0.2 second) and long-period (1.0 second) response accelerations with 5 percent critical damping on hard rock. Another consideration for seismic safety is that the maximum credible earthquake has a long recurrenece interval, from 500 to 1,000 years in the New Madrid Seismic Zone …

Evaluation Of Geologic Co2 Sequestration Potential And Co2 Enhanced Oil Recovery In Kentucky, Thomas M. Parris, Stephen F. Greb, Brandon C. Nuttall

Report of Investigations--KGS

Kentucky gets approximately 95 percent of its electricity from coal-fired power plants, which produce significant amounts of carbon dioxide (CO₂). In 2005, Kentucky coal-fired plants vented 102.8 million short tons of CO₂ into the atmosphere. The economic vitality of the state will be affected by its ability to develop and apply a portfolio of technologies that will mitigate input of CO₂ into the atmosphere. One technology that has the potential to assist in this challenge is geologic carbon storage, which captures CO₂ at point sources and injects it into deep rock strata that can store …

Geology And Structure Of The Rough Creek Area, Western Kentucky, William D. Johnson Jr., Howard R. Schwalb

Bulletin--KGS

The Rough Creek area is a rectangular area about 113 mi east to west and 35 mi north to south encompassing about 3,900 mi² in west-central and western Kentucky. The Ohio River delineates most of the western border with Illinois and locally also part of the northern border with Indiana. The northeast corner of the area is about 27 mi southwest of Louisville. The principal cities are Owensboro and Henderson.

The Precambrian basement has been penetrated in only two wells in western Kentucky at depths somewhat greater than 14,000 ft. Basement is projected to underlie much of the area …

Progress Towards The Synthesis Of Type B Polycyclic Polyprenylated Acylphloroglucinol 7-Epi-Clusianone, Pushpa Suresh Jayasekara Mudiyanselage

University of Kentucky Doctoral Dissertations

Plants of the family Guttiferae produce polycyclic polyprenylated acylphloroglucinols (PPAPs), which have interesting biological activities including anticancer and antibacterial properties. The main structural features of PPAPs comprise of bicyclo[3.3.1]nonane-2,4,9-triketone with one acyl group together with prenyl, geranyl, or other C₁₀H₁₇ groups. 7-epi-Clusianone, a type B PPAP with C-7 endo stereochemistry, is being approached by establishing the cis relationship with C(4) allyl group and C(2) methyl ester in the early stage of the synthesis. Then C(2) methyl ester is converted to alkyne aldehyde and syn reduction followed by intramolecular aldol reaction to give bicyclo[3.3.1]nonane structure with …

Soil Water And Crop Growth Processes In A Farmer's Field, Susmitha Surendran Nambuthiri

University of Kentucky Doctoral Dissertations

The study was aimed to provide information on local biomass development during crop growth using ground based optical sensors and to incorporate the local crop status to a crop growth simulation model to improve understanding on inherent variability of crop field. The experiment was conducted in a farmer’s field located near Princeton in Caldwell County, Western Kentucky. Data collection on soil, crop and weather variables was carried out in the farm from 2006 December to 2008 October. During this period corn (Zea mays L.) and winter wheat (Triticum sp) were grown in the field. A 450 m …

Tunneling Spectroscopy Study Of Calcium Ruthenate, Anthony Bautista

University of Kentucky Doctoral Dissertations

The ruthenates are perhaps one of the most diverse group of materials known up to date. These compounds exhibit a wide array of behaviors ranging from the exotic pwave superconductivity in Sr₂RuO₄, to the itinerant ferromagnetism in SrRuO₃, and the Mott-insulating behavior in Ca₂RuO₄. One of the most intriguing compounds belonging to this group is Ca₃Ru₂O₇ which is known to undergo an antiferromagnetic ordering at 56K and an insulating transition at 48K. Most intriguing, however, is the behavior displayed by this compound in the presence …

Kentucky Water Resources Research Institute Annual Technical Report Fy 2009, Kentucky Water Resources Research Institute, University Of Kentucky

KWRRI Annual Technical Reports (USGS’s 104b Grant Program)

The 2009 Annual Technical Report for Kentucky consolidates reporting requirements of the Section 104(b) base grant award into a single document that includes: 1) a synopsis of each research project conducted with grant funds during the period, 2) citations for related publications, reports, and presentations, 3) a description of information transfer activities, 4) a summary of student support during the reporting period, and 5) notable awards and achievements during the year.

General Flips And The Cd-Index, Daniel J. Wells

University of Kentucky Doctoral Dissertations

We generalize bistellar operations (often called flips) on simplicial manifolds to a notion of general flips on PL-spheres. We provide methods for computing the cd-index of these general flips, which is the change in the cd-index of any sphere to which the flip is applied. We provide formulas and relations among flips in certain classes, paying special attention to the classic case of bistellar flips. We also consider questions of "flip-connecticity", that is, we show that any two polytopes in certain classes can be connected via a sequence of flips in an appropriate class.

Measurement Of Single Spin Asymmetries In Semi-Inclusive Deep Inelastic Scattering Reaction N↑(E, Éπ+)X At Jefferson Lab, Kalyan C. Allada

University of Kentucky Doctoral Dissertations

What constitutes the spin of the nucleon? The answer to this question is still not completely understood. Although we know the longitudinal quark spin content very well, the data on the transverse quark spin content of the nucleon is still very sparse. Semi-inclusive Deep Inelastic Scattering (SIDIS) using transversely polarized targets provide crucial information on this aspect. The data that is currently available was taken with proton and deuteron targets.

The E06-010 experiment was performed at Jefferson Lab in Hall-A to measure the single spin asymmetries in the SIDIS reaction n^↑(e,éπ^±/K^±)X using transversely polarized …

Spectroscopy And Structures Of Metal-Cyclic Hydrocarbon Complexes, Jung Sup Lee

University of Kentucky Doctoral Dissertations

Metal-cyclic hydrocarbon complexes were prepared in a laser-vaporization molecular beam source and studied by single-photon zero electron kinetic energy (ZEKE) and IR-UV resonant two-photon ionization (R2PI) spectroscopy. The ionization energies and vibrational frequencies of the metal complexes were measured from the ZEKE spectra. Metal-ligand bonding and low-lying electronic states of the neutral and ionized complexes were analyzed by combining the ZEKE measurements with density functional theory (DFT) calculations. In addition, C-H stretching frequencies were measured from the R2PI spectra.

In this dissertation, metal complexes of 1, 3, 5, 7-cyclo-octatetraene (COT), toluene, p-xylene, mesitylene, hexamethylbenzene, biphenyl, naphthalene, pyrene, perylene, and …

15N Solid-State Nmr Detection Of Flavin Perturbation By H-Bonding In Models And Enzyme Active Sites, Dongtao Cui

University of Kentucky Doctoral Dissertations

Massey and Hemmerich proposed that the different reactivities displayed by different flavoenzymes could be achieved as a result of dominance of different flavin ring resonance structures in different binding sites. Thus, the FMN cofactor would engage in different reactions when it had different electronic structures. To test this proposal and understand how different protein sites could produce different flavin electronic structures, we are developing solid-state NMR as a means of characterizing the electronic state of the flavin ring, via the ¹⁵N chemical shift tensors of the ring N atoms. These provide information on the frontier orbitals. We propose that …

Single View Reconstruction For Human Face And Motion With Priors, Xianwang Wang

University of Kentucky Doctoral Dissertations

Single view reconstruction is fundamentally an under-constrained problem. We aim to develop new approaches to model human face and motion with model priors that restrict the space of possible solutions. First, we develop a novel approach to recover the 3D shape from a single view image under challenging conditions, such as large variations in illumination and pose. The problem is addressed by employing the techniques of non-linear manifold embedding and alignment. Specifically, the local image models for each patch of facial images and the local surface models for each patch of 3D shape are learned using a non-linear dimensionality reduction …

Near-Field Radiative Transfer: Thermal Radiation, Thermophotovoltaic Power Generation And Optical Characterization, Mathieu Francoeur

University of Kentucky Doctoral Dissertations

This dissertation focuses on near-field radiative transfer, which can be defined as the discipline concerned with energy transfer via electromagnetic waves at sub-wavelength distances. Three specific subjects related to this discipline are investigated, namely nearfield thermal radiation, nanoscale-gap thermophotovoltaic (nano-TPV) power generation and optical characterization. An algorithm for the solution of near-field thermal radiation problems in one-dimensional layered media is developed, and several tests are performed showing the accuracy, consistency and versatility of the procedure. The possibility of tuning near-field radiative heat transfer via thin films supporting surface phononpolaritons (SPhPs) in the infrared is afterwards investigated via the computation of …