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Full-Text Articles in Physical Sciences and Mathematics

Ultrahigh Energy Storage Properties In (Sr0.7bi0.2)Tio3-Bi(Mg0.5zr0.5)O3 Lead-Free Ceramics And Potential For High-Temperature Capacitors, Xi Kong, Letao Yang, Zhenxiang Cheng, Shujun Zhang Jan 2020

Ultrahigh Energy Storage Properties In (Sr0.7bi0.2)Tio3-Bi(Mg0.5zr0.5)O3 Lead-Free Ceramics And Potential For High-Temperature Capacitors, Xi Kong, Letao Yang, Zhenxiang Cheng, Shujun Zhang

Australian Institute for Innovative Materials - Papers

2020 by the authors. Due to the enhanced demand for numerous electrical energy storage applications, including applications at elevated temperatures, dielectric capacitors with optimized energy storage properties have attracted extensive attention. In this study, a series of lead-free strontium bismuth titanate based relaxor ferroelectric ceramics have been successfully synthesized by high temperature solid-state reaction. The ultrahigh recoverable energy storage density of 4.2 J/cm3 under 380 kV/cm, with the high efficiency of 88%, was obtained in the sample with x = 0.06. Of particular importance is that this ceramic composition exhibits excellent energy storage performance over a wide work temperature up …


Dielectric And Piezoelectric Properties Of Textured Lead-Free Na0.5bi0.5tio3-Based Ceramics, Nannan Dong, Xiaoyi Gao, Fangquan Xia, Hanxing Liu, Hua Hao, Shujun Zhang Jan 2019

Dielectric And Piezoelectric Properties Of Textured Lead-Free Na0.5bi0.5tio3-Based Ceramics, Nannan Dong, Xiaoyi Gao, Fangquan Xia, Hanxing Liu, Hua Hao, Shujun Zhang

Australian Institute for Innovative Materials - Papers

This work provides a comparative study of the dielectric and piezoelectric properties of randomly oriented and textured 0.88Na 0.5 Bi 0.5 TiO 3 -0.08K 0.5 Bi 0.5 TiO 3 -0.04BaTiO 3 (88NBT) ceramics. Textured ceramics were fabricated by template grain growth (TGG) method using NaNbO 3 (NN) for templates. For textured ceramics with 4 wt% NN templates, a Lotgering factor of 96% and piezoelectric coefficient d 33 of 185 pC/N were obtained. Compared to the randomly oriented ceramics, textured ceramics show lower strain hysteresis (H = 7.6%), higher unipolar strain of 0.041% with corresponding large signal piezoelectric coefficient d 33* …


Perovskite R3c Phase Agcuf3: Multiple Dirac Cones, 100% Spin Polarization And Its Thermodynamic Properties, Minquan Kuang, Tingzhou Li, Zhenxiang Cheng, Houari Khachai, Rabah Khenata, Tie Yang, Tingting Lin, Xiaotian Wang Jan 2019

Perovskite R3c Phase Agcuf3: Multiple Dirac Cones, 100% Spin Polarization And Its Thermodynamic Properties, Minquan Kuang, Tingzhou Li, Zhenxiang Cheng, Houari Khachai, Rabah Khenata, Tie Yang, Tingting Lin, Xiaotian Wang

Australian Institute for Innovative Materials - Papers

Very recently, experimentally synthesized R3c phase LaCuO3 was studied by Zhang, Jiao, Kou, Liao & Du [J. Mater. Chem. C (2018), 6, 6132-6137], and they found that this material exhibits multiple Dirac cones in its non-spin-polarized electronic structure. Motivated by this study, the focus here is on a new R3c phase material, AgCuF3, which has a combination of multiple Dirac cones and 100% spin polarization properties. Compared to the non-spin-polarized system LaCuO3, the spin-polarized Dirac behavior in AgCuF3 is intrinsic. The effects of on-site Coulomb interaction, uniform strain and spin-orbit coupling were added to examine the stability of its multiple …


Preparation And Physical Properties Of A Cr3al Filmwith A Do3structure, Weiqi Zhao, Xuefang Dai, X M. Zhang, Z Mo, Xiaotian Wang, G F. Chen, Zhenxiang Cheng, Guodong Liu Jan 2019

Preparation And Physical Properties Of A Cr3al Filmwith A Do3structure, Weiqi Zhao, Xuefang Dai, X M. Zhang, Z Mo, Xiaotian Wang, G F. Chen, Zhenxiang Cheng, Guodong Liu

Australian Institute for Innovative Materials - Papers

A Cr3Al compound with a DO3 structure has previously been predicted to be nearly half metal and a promising spintronics material; however, its synthesis has not been reported. Here, a Cr3Al compound with a DO3 structure is successfully prepared in thin-film form by the magnetron sputtering method. It was found that the substrate temperature is crucial to the atomic ordering, thin-film density and lattice constant. The lattice constant varies with different substrate temperatures and is smaller than the theoretical equilibrium lattice constant. Theoretical investigations on the electronic structures and magnetic properties indicate that the Cr3Al compound with a DO3 structure …


Charge Storage In Wo³ Polymorphs And Their Application As Supercapacitor Electrode Material, Vaibhav Lokhande, Abhishek Lokhande, Gon Namkoong, Jin Hyeok Kim, Taeksoo Ji Jan 2019

Charge Storage In Wo³ Polymorphs And Their Application As Supercapacitor Electrode Material, Vaibhav Lokhande, Abhishek Lokhande, Gon Namkoong, Jin Hyeok Kim, Taeksoo Ji

Electrical & Computer Engineering Faculty Publications

Tungsten oxide is a versatile material with different applications. It has many polymorphs with varying performance in energy storage application. We report simple and facile way to synthesize four phases of tungsten oxide from same precursor materials only by changing the pH and temperature values. Monoclinic, hexagonal, orthorhombic and tetragonal phase obtained, were analyzed and tested for supercapacitor application. The electrochemical analysis of four phases indicates that the hexagonal phase is best-suited electrode material for supercapacitor. The hexagonal phase exhibits higher specific capacitance (377.5 Fg-1 at 2 mVs-1), higher surface capacitive contribution (75%), better stability and rate …


Improvement Of Thermoelectric Properties And Their Correlations With Electron Effective Mass In Cu1.98sxse1−X, Lanling Zhao, Frank Yun Fei, Jun Wang, Funing Wang, Chunlei Wang, Jichao Li, Ji-Yang Wang, Zhenxiang Cheng, Shi Xue Dou, Xiaolin Wang Jan 2017

Improvement Of Thermoelectric Properties And Their Correlations With Electron Effective Mass In Cu1.98sxse1−X, Lanling Zhao, Frank Yun Fei, Jun Wang, Funing Wang, Chunlei Wang, Jichao Li, Ji-Yang Wang, Zhenxiang Cheng, Shi Xue Dou, Xiaolin Wang

Australian Institute for Innovative Materials - Papers

Sulphur doping effects on the crystal structures, thermoelectric properties, density-of-states, and effective mass in Cu1.98SxSe1−x were studied based on the electrical and thermal transport property measurements, and first-principles calculations. The X-ray diffraction patterns and Rietveld refinements indicate that room temperature Cu1.98SxSe1−x (x=0, 0.02, 0.08, 0.16) and Cu1.98SxSe1−x (x=0.8, 0.9, 1.0) have the same crystal structure as monoclinic-Cu2Se and orthorhombic-Cu2S, respectively. Sulphur doping can greatly enhance zT values when x is in the range of 0.8≤x≤1.0. Furthermore, all doped samples show stable thermoelectric compatibility factors over a broad temperature range from 700 to 1000K, which could greatly benefit their practical applications. …


Systematic Elongation Of Thienyl Linkers And Their Effect On Optical And Electrochemical Properties In Carbazole-Bodipy Donor-Acceptor Systems, Alina Brzeczek, Katarzyna Piwowar, Wojciech Domagala, Mikotaj M. Mikotajczyk, Krzysztof Walczak, Pawel W. Wagner Jan 2016

Systematic Elongation Of Thienyl Linkers And Their Effect On Optical And Electrochemical Properties In Carbazole-Bodipy Donor-Acceptor Systems, Alina Brzeczek, Katarzyna Piwowar, Wojciech Domagala, Mikotaj M. Mikotajczyk, Krzysztof Walczak, Pawel W. Wagner

Australian Institute for Innovative Materials - Papers

Synthesis, spectral and electrochemical properties of a series of new panchromatic BODIPY donor-acceptor-donor derivatives, comprising carbazole conjugated with systematically elongated framework by thiophene-based linkers were investigated. It has been found that elongation of the π-system with one thiophene unit shifts the spectra toward near infrared, while incorporation of next thiophene derivatives has only limited influence on the lowest energy transition, causing no further shift of absorption maxima. Elongation of π-conjugation of the donor arm tunes the electron properties, influencing the ionization potential (IP) and electron affinity (EA) values of the molecules. The experimental results are supported by quantum chemical computations …


Β -Nmr Investigation Of The Depth-Dependent Magnetic Properties Of An Antiferromagnetic Surface, David L. Cortie, T Buck, M Dehn, V L. Karner, R F. Kiefl, C D. P Levy, R M. L Mcfadden, G D. Morris, I Mckenzie, M R. Pearson, Xiaolin Wang, W A. Macfarlane Jan 2016

Β -Nmr Investigation Of The Depth-Dependent Magnetic Properties Of An Antiferromagnetic Surface, David L. Cortie, T Buck, M Dehn, V L. Karner, R F. Kiefl, C D. P Levy, R M. L Mcfadden, G D. Morris, I Mckenzie, M R. Pearson, Xiaolin Wang, W A. Macfarlane

Australian Institute for Innovative Materials - Papers

By measuring the prototypical antiferromagnet α-Fe2O3, we show that it is possible to determine the static spin orientation and dynamic spin correlations within nanometers from an antiferromagnetic surface using the nuclear spin polarization of implanted 8Liþ ions detected with β-NMR. Remarkably, the firstorder Morin spin reorientation in single crystal α-Fe2O3 occurs at the same temperature at all depths between 1 and 100 nm from the (110) surface; however, the implanted nuclear spin experiences an increased 1=T1 relaxation rate at shallow depths revealing soft-surface magnons. The surface-localized dynamics decay towards the bulk with a characteristic length of ϵ ¼ 11 1 …


Improved Superconducting Properties In The Mg11b2 Low Activation Superconductor Prepared By Low-Temperature Sintering, Fang Cheng, Yongchang Liu, Zongqing Ma, M Shahriar Al Hossain, Mehmet Somer Jan 2016

Improved Superconducting Properties In The Mg11b2 Low Activation Superconductor Prepared By Low-Temperature Sintering, Fang Cheng, Yongchang Liu, Zongqing Ma, M Shahriar Al Hossain, Mehmet Somer

Australian Institute for Innovative Materials - Papers

Mg11B2 has a great application prospect in the superconducting coils for fusion reactor as the "low activation superconductors". The un-doped Mg11B2 and Cu-doped Mg11B2 bulks using 11B as a boron precursor were fabricated by low-temperature sintering in present work. It was found that the prepared Mg11B2 low activation superconductors exhibit better Jc performance than all of other Mg11B2 samples reported in previous studies. As for Cu doped Mg11B2, minor Cu addition can obviously improve the Mg11B2 grain crystallization and reduce the amount of MgO impurity. Hence, improved grain connectivity and higher Jc at low fields is obtained in Cu doped …


Ferroelectric And Magnetic Properties Of Aurivillius Bim+1ti3fem−3o3m+3 Thin Films, Tingting Jia, Hideo Kimura, Zhenxiang Cheng, Hongyang Zhao Jan 2015

Ferroelectric And Magnetic Properties Of Aurivillius Bim+1ti3fem−3o3m+3 Thin Films, Tingting Jia, Hideo Kimura, Zhenxiang Cheng, Hongyang Zhao

Australian Institute for Innovative Materials - Papers

Aurivillius Bim+1Ti3Fem−3O3m+3 (m = 4, 5, 6) thin films have been deposited by a pulsed laser deposition system. The x-ray diffraction patterns indicate the formation of orthorhombic phase. The remanent polarization (2Pr) of Bim+1Ti3Fem−3O3m+3 thin films is decreased with the m-number. Positive-up-negative-down measurements indicate the presence of ferroelectric (FE) polarization in as-obtained thin films. Piezoresponse force microscopy investigations confirm the existence of FE domains and the switchable polarization. Weak magnetic moment is detected in the Aurivillius films at room temperature. The present work …


Modulation Of Photocatalytic Properties By Strain In 2d Biobr Nanosheets, Haifeng Feng, Zhongfei Xu, Liang Wang, Youxing Yu, David R. G Mitchell, Dandan Cui, Xun Xu, Ji Shi, Takumi Sannomiya, Yi Du, Weichang Hao, S X. Dou Jan 2015

Modulation Of Photocatalytic Properties By Strain In 2d Biobr Nanosheets, Haifeng Feng, Zhongfei Xu, Liang Wang, Youxing Yu, David R. G Mitchell, Dandan Cui, Xun Xu, Ji Shi, Takumi Sannomiya, Yi Du, Weichang Hao, S X. Dou

Australian Institute for Innovative Materials - Papers

BiOBr nanosheets with highly reactive {001} facets exposed were selectively synthesized by a facile hydrothermal method. The inner strain in the BiOBr nanosheets has been tuned continuously by the pH value. The photocatalytic performance of BiOBr in dye degradation can be manipulated by the strain effect. The low-strain BiOBr nanosheets show improved photocatalytic activity. Density functional calculations suggest that strain can modify the band structure and symmetry in BiOBr. The enhanced photocatalytic activity in low-strain BiOBr nanosheets is due to improved charge separation attributable to a highly dispersive band structure with an indirect band gap.


An Investigation Of The Nanomechanical Properties Of 0.5ba(Ti0.8zr0.2)O3-0.5(Ba0.7ca0.3)Tio3 Thin Films, Zhong-Lan Cai, Zeng-Mei Wang, Huan-Huan Wang, Zhenxiang Cheng, Baowen Li, Xin-Li Guo, Hideo Kimura, Akira Kasahara Jan 2015

An Investigation Of The Nanomechanical Properties Of 0.5ba(Ti0.8zr0.2)O3-0.5(Ba0.7ca0.3)Tio3 Thin Films, Zhong-Lan Cai, Zeng-Mei Wang, Huan-Huan Wang, Zhenxiang Cheng, Baowen Li, Xin-Li Guo, Hideo Kimura, Akira Kasahara

Australian Institute for Innovative Materials - Papers

For practical application, the functional piezoelectric film in microelectromechanical systems should meet the requirement of physical properties, as well as the mechanical properties. In this article, 0.5Ba(Ti0.8Zr0.2)O3-0.5(Ba0.7Ca0.3)TiO3 (0.5BZT-0.5BCT) thin films with varied properties were prepared on (100) Si substrates via a sol-gel technique at different annealing temperatures. The effects of the annealing temperature on the morphology, piezoelectricity, hardness, and elastic modulus were studied. Particular attention was paid to the surface frictional behavior of films, and the changes in the friction force can be radically explained in terms of differences in the hardness/elastic modulus ratio and the residual stress of films. …


Anomalies In Magnetoelastic Properties Of Dyfe11.2nb0.8 Compound, Jianli Wang, M F. Md Din, Shane J. Kennedy, Zhenxiang Cheng, Stewart J. Campbell, Justin A. Kimpton, S X. Dou Jan 2015

Anomalies In Magnetoelastic Properties Of Dyfe11.2nb0.8 Compound, Jianli Wang, M F. Md Din, Shane J. Kennedy, Zhenxiang Cheng, Stewart J. Campbell, Justin A. Kimpton, S X. Dou

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of DyFe11.2Nb0.8 compound have been investigated by high intensity, high resolution synchrotron x-ray diffraction, ac magnetic susceptibility, and dc magnetization measurements as well as Mössbauer spectroscopy (5-300 K). The easy magnetization direction at room temperature is along the c-axis. With decreasing temperature, the magnetocrystalline anisotropy changes from easy-axis to easy-cone at Tsr2 (∼202 K), then to easy plane at Tsr1 (∼94 K). The thermal expansion coefficient obtained from the synchrotron x-ray study exhibits clear anomalies around both of the spin reorientation transition temperatures. The 57Fe hyperfine interaction parameters and …


A Facile Method To Enhance Ferroelectric Properties In Pvdf Nanocomposites, Mohammad Mahdi Abolhasani, Fatemeh Zarejousheghani, Zhenxiang Cheng, Minoo Naebe Jan 2015

A Facile Method To Enhance Ferroelectric Properties In Pvdf Nanocomposites, Mohammad Mahdi Abolhasani, Fatemeh Zarejousheghani, Zhenxiang Cheng, Minoo Naebe

Australian Institute for Innovative Materials - Papers

Poly(vinylidene fluoride) (PVDF)/nanoclay composites were prepared using melt compounding. The effect of acrylic rubber (ACM) as a compatibilizer on different polymorph formation and on the ferroelectric properties of nanocomposites were investigated. The intercalation and morphological structure of the samples were studied using X-ray diffraction (XRD) and transmission electron microscopy (TEM). The infrared spectroscopy and X-ray analysis revealed the coexistence of beta and gamma crystalline forms in PVDF-clay nanocomposite, while in partially miscible PVDF/ACM/clay hybrids, three polymorphs of alpha, beta and g coexisted. The coefficients of electric field-polarization (E-P) Taylor expansion were calculated based on the Lorentz theory. Using a genetic …


Influence Of Biopolymer Loading On The Physiochemical And Electrochemical Properties Of Inherently Conducting Polymer Biomaterials, Paul J. Molino, Peter C. Innis, Michael J. Higgins, Robert M. I Kapsa, Gordon G. Wallace Jan 2015

Influence Of Biopolymer Loading On The Physiochemical And Electrochemical Properties Of Inherently Conducting Polymer Biomaterials, Paul J. Molino, Peter C. Innis, Michael J. Higgins, Robert M. I Kapsa, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

The physicochemical and electrochemical properties of polypyrrole (PPy) doped with the biological dopant dextran sulphate (DS) were shown to be significantly altered as a function of varying the salt concentration (0.2, 2 or 20 mg/ml) in the polymerisation electrolyte. Films grown in the presence of 0.2 mg/ml DS generated the highest potential during galvanostatic growth, with the potential decreasing with each subsequent increase in DS concentration. The electroactivity of the polymers was similar for all three DS concentrations, with the 20 mg/ml film drawing slightly more current upon reduction in PBS. Increasing the DS concentration reduced film interfacial roughness and …


Sodium And Lithium Storage Properties Of Spray-Dried Molybdenum Disulfide-Graphene Hierarchical Microspheres, Sujith Kalluri, Kuok Hau Seng, Zaiping Guo, Aijun Du, Konstantin K. Konstantinov, Hua-Kun Liu, S X. Dou Jan 2015

Sodium And Lithium Storage Properties Of Spray-Dried Molybdenum Disulfide-Graphene Hierarchical Microspheres, Sujith Kalluri, Kuok Hau Seng, Zaiping Guo, Aijun Du, Konstantin K. Konstantinov, Hua-Kun Liu, S X. Dou

Australian Institute for Innovative Materials - Papers

Developing nano/micro-structures which can effectively upgrade the intriguing properties of electrode materials for energy storage devices is always a key research topic. Ultrathin nanosheets were proved to be one of the potential nanostructures due to their high specific surface area, good active contact areas and porous channels. Herein, we report a unique hierarchical micro-spherical morphology of well-stacked and completely miscible molybdenum disulfide (MoS2) nanosheets and graphene sheets, were successfully synthesized via a simple and industrial scale spray-drying technique to take the advantages of both MoS2 and graphene in terms of their high practical capacity values and high …


Porous Amorphous Ge/C Composites With Excellent Electrochemical Properties, Xiu Li, Wei Guo, Qian Wan, Jianmin Ma Jan 2015

Porous Amorphous Ge/C Composites With Excellent Electrochemical Properties, Xiu Li, Wei Guo, Qian Wan, Jianmin Ma

Australian Institute for Innovative Materials - Papers

Porous amorphous germanium/carbon (Ge/C) composites, which were synthesized through the reduction/carbonization of germanium oxide/oleic acid precursors, could exhibit a high-capacity, high-rate and long-life performance due to the synergistic effect of the porous structure and carbon.


Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou Oct 2014

Magnetic Properties And Magnetocaloric Effect Of Ndmn2-Xcuxsi2 Compounds, M F. Md Din, Jianli Wang, M Avdeev, Q F. Gu, R Zeng, S J. Campbell, S J. Kennedy, S X. Dou

Shi Xue Dou

Structural and magnetic properties of NdMn2−x Cu xSi2 compounds (x = 0-1.0) have been investigated by high intensity x-ray and resolution neutron diffraction (3-450 K), specific heat, dc magnetization, and differential scanning calorimetry measurements. Substitution of Cu for Mn leads to an increase in the lattice parameter a but a decrease in c at room temperature. Two magnetic phase transitions have been found for NdMn2−x Cu xSi2 compounds with TN for the antiferromagnetic ordering of Mn-sublatttice and TC for the Nd-sublattice ferromagnetic ordering, respectively. TC increases significantly with increasing Cu content from 36 K at x = 0 to 100 …


Enhancing Superconducting Properties Of Mgb2 Pellets By Addition Of Amorphous Magnetic Ni-Co-B Nanoparticles, Mislav Mustapic, Josip Horvat, Md Shahriar Hossain, Zeljko Skoko, S X. Dou Apr 2014

Enhancing Superconducting Properties Of Mgb2 Pellets By Addition Of Amorphous Magnetic Ni-Co-B Nanoparticles, Mislav Mustapic, Josip Horvat, Md Shahriar Hossain, Zeljko Skoko, S X. Dou

Josip Horvat

Amorphous magnetic Ni-Co-B nanoparticles with an average size of 5 nm were added to precursor powders of MgB2 superconductor. The preparation procedure for MgB2 pellets was optimized for obtaining the best critical current density (Jc) at elevated magnetic fields. Addition of Ni-Co-B decreases the Jc for heat treatment of precursor powders at 650 ° C. Heat treatments at 770 ° C and higher improve Jc at 20 and 5 K. This improvement occurs at both temperatures through the increase of the effective connectivity between MgB2 crystals. Vortex pinning was enhanced at 5 K, but not at 20 K. Ni-Co-B nanoparticles …


Surface Properties And Interaction Forces Of Biopolymer-Doped Conductive Polypyrrole Surfaces By Atomic Force Microscopy, Jani M. Pelto, Suvi P. Haimi, Aliisa S. Siljander, Susanna S. Miettinen, Kirsi M. Tappura, Michael J. Higgins, Gordon G. Wallace Mar 2014

Surface Properties And Interaction Forces Of Biopolymer-Doped Conductive Polypyrrole Surfaces By Atomic Force Microscopy, Jani M. Pelto, Suvi P. Haimi, Aliisa S. Siljander, Susanna S. Miettinen, Kirsi M. Tappura, Michael J. Higgins, Gordon G. Wallace

Gordon Wallace

Surface properties and electrical charges are critical factors elucidating cell interactions on biomaterial surfaces. The surface potential distribution and the nanoscopic and microscopic surface elasticity of organic polypyrrole-hyaluronic acid (PPy-HA) were studied by atomic force microscopy (AFM) in a fluid environment in order to explain the observed enhancement in the attachment of human adipose stem cells on positively charged PPy-HA films. The electrostatic force between the AFM tip and a charged PPy-HA surface, the tip-sample adhesion force, and elastic moduli were estimated from the AFM force curves, and the data were fitted to electrostatic double-layer and elastic contact models. The …


Bio-Ink Properties And Printability For Extrusion Printing Living Cells, Johnson H. Y Chung, Sina Naficy, Zhilian Yue, Robert Kapsa, Anita Quigley, Simon E. Moulton, Gordon G. Wallace Mar 2014

Bio-Ink Properties And Printability For Extrusion Printing Living Cells, Johnson H. Y Chung, Sina Naficy, Zhilian Yue, Robert Kapsa, Anita Quigley, Simon E. Moulton, Gordon G. Wallace

Gordon Wallace

Additive biofabrication (3D bioprinting) makes it possible to create scaffolds with precise geometries, control over pore interconnectivity and architectures that are not possible with conventional techniques. Inclusion of cells within the ink to form a “bio-ink” presents the potential to print 3D structures that can be implanted into damaged/diseased tissue to promote highly controlled cell-based regeneration and repair. The properties of an ‘ink’ are defined by its formulation and critically influence the delivery and integrity of structure formed. Importantly, the ink properties need to conform to biological requirements necessary for the cell system that they are intended to support and …


Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou Mar 2014

Magnetic Properties And Magnetocaloric Effect Of Ndmn2−Xtixsi2 Compounds, M F. Md Din, Jianli Wang, S J. Campbell, R Zeng, W D. Hutchison, M Avdeev, S J. Kennedy, S X. Dou

Shi Xue Dou

The structural and magnetic properties of the intermetallic compounds NdMn2−xTixSi2(x = 0, 0.1, 0.2, and 0.3) have been studied by x-ray and high resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range 3–450 K. The Curie temperature and Néel temperature of NdMn2Si2 decrease from TC = 36 K and TN = 380 K to TC = 14 K and TN = 360 K, respectively, on substitution of Ti (x = 0.3) for Mn. The magnetocaloric effect at the first order ferromagnetic phase transition at TC, has been investigated in detail. Under a …


Enhancing Superconducting Properties Of Mgb2 Pellets By Addition Of Amorphous Magnetic Ni-Co-B Nanoparticles, Mislav Mustapic, Josip Horvat, Md Shahriar Hossain, Zeljko Skoko, S X. Dou Mar 2014

Enhancing Superconducting Properties Of Mgb2 Pellets By Addition Of Amorphous Magnetic Ni-Co-B Nanoparticles, Mislav Mustapic, Josip Horvat, Md Shahriar Hossain, Zeljko Skoko, S X. Dou

Shi Xue Dou

Amorphous magnetic Ni-Co-B nanoparticles with an average size of 5 nm were added to precursor powders of MgB2 superconductor. The preparation procedure for MgB2 pellets was optimized for obtaining the best critical current density (Jc) at elevated magnetic fields. Addition of Ni-Co-B decreases the Jc for heat treatment of precursor powders at 650 ° C. Heat treatments at 770 ° C and higher improve Jc at 20 and 5 K. This improvement occurs at both temperatures through the increase of the effective connectivity between MgB2 crystals. Vortex pinning was enhanced at 5 K, but not at 20 K. Ni-Co-B nanoparticles …


Thermoelectric Properties Of Ca3co4o9 And Ca2.8bi0.2co4o9 Thin Films In Their Island Formation Mode, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou Mar 2014

Thermoelectric Properties Of Ca3co4o9 And Ca2.8bi0.2co4o9 Thin Films In Their Island Formation Mode, Priyanka Jood, Germanas Peleckis, Xiaolin Wang, S X. Dou

Shi Xue Dou

Ca3Co4O9 and Ca2.8Bi 0.2Co4O9 thin films were fabricated on LaAlO3 (LAO) substrate using pulsed laser deposition technique and were studied for their thermoelectric (TE) properties in Stranski-Krastanov mode for the first time. The thin films consisted of 3D clusters/islands on a 14-nm thick 2D layer with cluster density being higher for Ca 2.8Bi0.2Co4O9 thin films. The clusters also represent areas of dislocation and therefore act as carrier scattering centers, which leads to a temperature-activated type conductivity. Seebeck coefficient as high as 136 and 163 u V/K was measured for the Ca 3Co4O9 and Ca2.8Bi 0.2Co4O9 thin films, respectively, which is …


Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa Mar 2014

Band Structure, Magnetic, And Transport Properties Of Two Dimensional Compounds Sr2-Xgdxcoo4, Q W Yao, Xiaolin Wang, H Kimura, S X. Dou, Konstantin Konstantinov, Z X. Cheng, F Hong, H Zhao, H Qiu, Kiyoshi Ozawa

Shi Xue Dou

The layered perovskite compound Sr2-xGdxCoO 4 has not yet been subjected to detailed study so far. In this report, structures, transport, magnetic properties, and first principle calculations will be reported for the two dimensional compounds Sr 2-xGdxCoO4 (x 0.5, 0.75, 1, 1.25). Rietveld refinement revealed that these compounds are crystallized in K2NiF 4-type structures with space group I4/mmm. It was found that the lattice parameter c decreases as x increases. Through the Curies Weiss fitting of the temperature dependent magnetization, it was found that the Sr 1.25Gd0.75CoO4 sample exhibits a weak ferromagnetic to paramagnetic transition at about 62 K, with …


The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou Mar 2014

The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou

Shi Xue Dou

The lithium/sulfur battery is a promising electrochemical system with high capacity, which is well-known to undergo a complex multistep reaction during the discharge process. Two types of electrolytes including poly (ethylene glycol) dimethyl ether (PEGDME)-based and 1.3 - dioxolane (DOL)/ dimethoxyethane (DME)-based electrolytes were investigated here. Furthermore, LiNO3 additive was introduced into the electrolyte in order to effectively eliminate the overcharge effect. The lithium sulfur battery with 1.0 M LiN(CF3SO2)2 in PEGME with 0.1 M LiNo3 shows highly stable reversible capacity of 624.8 mAh g-1 after 200 cycles and improved average coulombic efficiency of 98 percent.


Modeling Transport Properties Of Inhomogeneous Superconductor-Metal Composites, A Borroto, L Del Rio, M Arronte, Tom Johansen, E Altshuler Jan 2014

Modeling Transport Properties Of Inhomogeneous Superconductor-Metal Composites, A Borroto, L Del Rio, M Arronte, Tom Johansen, E Altshuler

Australian Institute for Innovative Materials - Papers

We propose a model for a superconductor-metal composite that allows to derive intrinsic transport properties of the superconducting phase based on 2D images of its cross section, and a minimal set of parameters. The method is tested experimentally by using, as model composite, a "transversal bridge" made on a Bi2Sr2Ca2Cu3O10+x (BSCCO)-Ag multi-filamentary tape. It is shown that the approach allows to predict the measured I−⟨E⟩ curves of the filaments. In addition, one can determine the critical current anisotropy between the longitudinal and transverse directions of the Ag-BSCCO tape, and also of …


Impacts Of Crystal Orientation Of Gaas On The Interfacial Structures And Electrical Properties Of Hf0.6la0.4ox Films, Tingting Jia, Hideo Kimura, Hongyang Zhao, Qiwen Yao, Zhenxiang Cheng, Xinghong Cheng, Yuehui Yu Jan 2014

Impacts Of Crystal Orientation Of Gaas On The Interfacial Structures And Electrical Properties Of Hf0.6la0.4ox Films, Tingting Jia, Hideo Kimura, Hongyang Zhao, Qiwen Yao, Zhenxiang Cheng, Xinghong Cheng, Yuehui Yu

Australian Institute for Innovative Materials - Papers

One of the major challenges in realizing the GaAs channel in the metal oxide semiconductor field effect transistor is the degrading in electron transport properties at the interface between GaAs and the gate oxide. In this study, Hf0.6La0.4Ox gate oxide films were deposited at a low temperature (200 °C) on GaAs(111)A and GaAs(100) substrates by plasma enhanced atomic layer deposition. Microstructure analysis indicates that residuals of gallium oxide, arsenic oxide, and As element remained at the interface of Hf0.6La0.4Ox/GaAs(100). On contrast, a smoother interface is observed between Hf0.6 …


Magnetic Properties And Magnetocaloric Effect In Layered Ndmn1.9ti0.1si2, M F. Md Din, Jianli Wang, Shane J. Kennedy, Stewart J. Campbell, S X. Dou Jan 2014

Magnetic Properties And Magnetocaloric Effect In Layered Ndmn1.9ti0.1si2, M F. Md Din, Jianli Wang, Shane J. Kennedy, Stewart J. Campbell, S X. Dou

Australian Institute for Innovative Materials - Papers

The structural and magnetic properties of the NdMn1.9Ti0.1Si2 compund have been studied by high-intensity x-ray and high-resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range of 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9Ti0.1Si2 are indicated as TC ~ 22 K and TN ~ 374 K respectively. The first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd)+Fmc] around TC is found in layered NdMn1.9Ti0.1Si2 and is …


Hydrostatic Piezoelectric Properties Of [011] Poled Pb(Mg 1/3nb2/3)O3-Pbtio3 Single Crystals And 2-2 Lamellar Composites, Lili Li, Shujun Zhang, Zhuo Xu, Xuecang Geng, Fei Wen, Jun Luo, Thomas R. Shrout Jan 2014

Hydrostatic Piezoelectric Properties Of [011] Poled Pb(Mg 1/3nb2/3)O3-Pbtio3 Single Crystals And 2-2 Lamellar Composites, Lili Li, Shujun Zhang, Zhuo Xu, Xuecang Geng, Fei Wen, Jun Luo, Thomas R. Shrout

Australian Institute for Innovative Materials - Papers

The hydrostatic piezoelectric properties of [011] poled Pb(Mg 1/3Nb2/3)O3-PbTiO3 (PMN-PT) crystals and corresponding 2-2 crystal/epoxy composites were investigated. The crystal volume ratio and compositional dependencies of the hydrostatic charge and voltage coefficients (dh and gh) and hydrostatic figure of merit (FOM) dh x gh were determined, where large FOM value of 3.2 pm2/N with high stability as a function of hydrostatic pressure was achieved for rhombohedral crystal composites. In addition, the stress amplification effects of the face-plate and different epoxy matrixes were investigated, with maximum FOM value being on the order of 92 pm2/N, indicating that 2-2 crystal/epoxy composites are …