Physical Sciences and Mathematics Commons^™

Distinguishing Primary Versus Secondary Geochemical And Silicon Isotope Characteristics Of Precambrian Chert And Iron Formation, Latisha Ashley Brengman

Doctoral Dissertations

Precambrian chert and banded iron formation (BIF) are defined as chemical sediments precipitated directly from seawater. As such, their geochemistry, including trace elements, rare earth elements (REE), and isotopes (O, Si) may preserve Precambrian seawater conditions. However, the chemical signature of these rocks may not simply reflect seawater, because hydrothermal interactions and metasomatism may produce rocks that petrographically and chemically resemble chert and BIF, including seawater-like compositional characteristics acquired during mineral replacement. Interpreting the major-, trace-, and rare-earth element signatures of these rocks requires the identification of geochemical and isotopic fingerprints that differentiate rocks formed from chemical sedimentation from rocks …

Comparisons Of Point And Average Capillary Pressure - Saturation Functions For Porous Media, Samuel Clark Cropper

Doctoral Dissertations

The relationship between the volume of water occupying pores in soil or rock and its energy state is called the capillary pressure–saturation function. This is an important hydrogeologic property needed for modeling multiphase flow and transport. Standard methods used to determine capillary pressure–saturation behavior produce volume averaged functions rather than point functions. Average functions can produce erroneous simulations in flow models. Analytical expressions permit extraction of point functions from average functions, and predictions of average functions from point function parameters. These concepts are discussed in Chapter I.

Chapter II compares average and point functions from centrifugation of Berea sandstone, glass …

Exploring Martian Magmas: From The Mantle To The Regolith, Arya Sigrid Waltraud Udry

Doctoral Dissertations

The planet Mars is geologically more similar to Earth than to other planets of the solar system. For the past 50 years, new rovers, orbital spacecraft, and new martian meteorites have helped us to understand the geological processes that occurred on Mars. In this dissertation, I investigate a wide range of martian igneous compositions, such as shergottite and nakhlite meteorites, Gusev and Gale surface basalts, and the Northwest Africa (NWA) 7034 breccia. I attempt to better understand magmatic processes that occurred in the martian mantle and crust as well as surficial processes using various petrologic and geochemical tools.

As shown …

Impacts Of Climate Change On The Evolution Of The Electrical Grid, Melissa Ree Allen

Doctoral Dissertations

Maintaining interdependent infrastructures exposed to a changing climate requires understanding 1) the local impact on power assets; 2) how the infrastructure will evolve as the demand for infrastructure changes location and volume and; 3) what vulnerabilities are introduced by these changing infrastructure topologies. This dissertation attempts to develop a methodology that will a) downscale the climate direct effect on the infrastructure; b) allow population to redistribute in response to increasing extreme events that will increase under climate impacts; and c) project new distributions of electricity demand in the mid-21^st century.

The research was structured in three parts. The first …

Gastrointestinal Microbial Diversity And Diagenetic Alteration Of Bone From The American Alligator (Alligator Mississippiensis), Sarah Wheeler Keenan

Doctoral Dissertations

One of the most challenging questions in paleobiology is how bone transforms from a living tissue into a fossil. In life, the gastrointestinal tract microbiome of an animal promotes host health. But, in death, these microbial communities, as well as soil communities, begin to degrade tissue, including bones. Using the American alligator from coastal wetland habitats as a model system, the gastrointestinal tract microbiome was found to contain microbial communities consisting of Fusobacteria, Proteobacteria, Bacteroidetes, and Firmicutes, with variations based on tissue type along the length of the digestive tract. The overall dominance of Fusobacteria is distinct from any other …

Stability, Erosion, And Morphology Considerations For Sustainable Slope Design, Isaac Andres Jeldes Halty

Doctoral Dissertations

The construction of more natural and sustainable earth slopes requires the consideration of erosion and runoff characteristics as an integral part of the design. These effects not only result in high costs for removal of sediment, but also a profound damage to the ecosystem. In this dissertation, innovative techniques are developed such that more natural appearing slopes can be designed to minimize sediment delivery, while meeting mechanical equilibrium requirements. This was accomplished by: a) examining the fundamental failure modes of slopes built with minimum compaction (FRA) to enhance quick establishment of forest, b) investigating the geomechanical and erosion stability of …

Enhancing Usability Of The Multi-Channel Analysis Of Surface Wave (Masw) Technique For Subsurface Physical Property Mapping By Incorporating Random-Array Seismic Acquisition, Prasanta Malati Yeluru

Doctoral Dissertations

Subsurface imaging is very critical to exploit subsurface resources, monitor the fluid movement in the reservoir, mapping tunnels etc. As science advances scientists and other researchers are constantly trying to develop new techniques and methods for subsurface imaging that are more effective, efficient, and are more robust under varying field conditions. The main focus of this research is one such effort to improve and increase the usability of the Multi-channel Analysis of Surface Wave method (MASW) method in determining regolith and rock properties by introducing a new type of receiver arrangement to extend its usage in places that are inaccessible …

Species Discrimination, Systematics, And Ontogeny Of Blastoidea, James William Atwood

Doctoral Dissertations

Blastoids are ideal model organisms with which to study evolutionary processes because nearly all of the skeletal elements are shared among all taxa, there have been recent advances in the understanding of blastoid homology, and they are more commonly preserved fully inflated than any other blastozoan. Because of this homology and preservation, blastoids are the perfect candidate for studies involving geometric morphometrics and systematics. But the potential of blastoids to be a model clade has been extremely hampered by the lack of a modern phylogenetics and classification.

The focus of this dissertation is to increase our understanding of blastoid species …

Geologic Investigations In The Central Georgia Inner Piedmont And The Western Flank Of The Carolina Superterrane: Implications Regarding Acadian And Alleghanian Collisional Orogenesis, Fault Reactivation, And The Mesozoic Breakup Of Pangea, Matthew Tiesher Huebner

Doctoral Dissertations

Detailed geologic mapping, U-Pb geochronology, igneous petrology and whole-rock geochemical analysis, and structural analysis of the Inner Piedmont and Carolina superterrane were conducted to better define the tectonic history of the southern Appalachian orogen; results yield implications for Acadian/Neoacadian and Alleghanian collisional events and Mesozoic breakup of Pangea. Detailed geologic mapping was focused in the Inner Piedmont at the northeastern end of the Pine Mountain window to investigate an aeromagnetic anomaly that was hypothesized to represent the southwestern continuation of the Brindle Creek fault, which separates the Inner Piedmont terranes (Tugaloo and Cat Square). Evidence supports this hypothesis, while contrasting …

Scale-Dependent Heterogeneity In Fracture Data Sets And Grayscale Images, Ankur Roy

Doctoral Dissertations

Lacunarity is a technique developed for multiscale analysis of spatial data and can quantify scale-dependent heterogeneity in a dataset. The present research is based on characterizing fracture data of various types by invoking lacunarity as a concept that can not only be applied to both fractal and non-fractal binary data but can also be extended to analyzing non-binary data sets comprising a spectrum of values between 0 and 1. Lacunarity has been variously modified in characterizing fracture data from maps and scanlines in tackling five different problems. In Chapter 2, it is shown that normalized lacunarity curves can differentiate between …

Stratigraphic And Geochemical Investigation Of The Mesoproterozoic Atar And El Mreiti Groups, Mauritania: Insights Into Carbon Cycling And Ocean Redox Stratification In A Low Oxygen World, Geoffrey J. Gilleaudeau

Doctoral Dissertations

The protracted oxygenation of Earth’s surface environments played a critical role in biospheric evolution during the Proterozoic eon. Initial oxygenation began ~2.3 Ga during the Great Oxidation Event, yet Earth’s oceans did not become fully oxygenated until at least the end of the Neoproterozoic—coincident with the first appearance of metazoans in the fossil record. Patterns of environmental change and evolutionary innovation are more complex and less certain, however, in the prolonged period between these two oxygenation thresholds. The late Mesoproterozoic (1.3 to 1.0 Ga) was marked by increasing biospheric oxygen—evidenced by increased carbon isotopic variability and an increase in marine …

Genetic Analysis Of Bacterial Gene Variations In Sulfidic Springs And The Influence On Geochemistry, Brendan Joseph Headd

Doctoral Dissertations

Culture-independent methods have revolutionized environmental microbiology and geomicrobiology studies and next-generation sequencing and metagenomics techniques continue to reveal the vast genetic diversity of microorganisms. But, these approaches provide comparatively little quantitative information about the roles that naturally occurring microbial gene variations play in local biogeochemical cycling. The goal of this study was to identify how the physical distribution and genetic diversity of microbial genes within a habitat impact environmental geochemistry by examining the biogeography of 16S rRNA genes and bacterial sulfur oxidation (Sox) genes in terrestrial sulfidic springs. 16S rRNA gene pyrosequences were obtained from microbial mats inhabiting eight sulfidic …

Evaluating Predictability In The Community Earth System Model In Response To The Eruption Of Mount Pinatubo, Abigail Laurel Gaddis

Doctoral Dissertations

A central goal of climate research is to determine the perceptible effects of climate change on humans; in other words, the regional and decadal scale effects of carbon dioxide forcing. Identifying the most pronounced and long-lasting responses of climate variables to forcing is important for decadal prediction since forcing terms are a source of predictability on those time scales. Powerful volcanic eruptions provide a transient forcing on the climate system, creating a test bed for climate models. In this study, the Mount Pinatubo eruption is simulated in the Community Earth System Model, CESM1.0, for three model configurations: fully coupled T85 …

Sociobiophysicality, Cold War, And Critical Theory: Human-Ecological Transformation And Contemporary Ecological Subjectivity, Alexander Stoner

Doctoral Dissertations

The United States is an important global player in resource depletion, energy use, waste production, and other indicators that contribute to economic threats to humanity’s ecological future. Critical theory provides conceptual tools that are uniquely well-suited to more fully comprehend the links between economic progress and ecological deterioration. In key regards, the present situation is the continuation as well as amplification of political-economic, social and cultural features that took hold during the Cold War, and which demand rigorous sociological focus, scrutiny and analysis. To date, however, sociology has barely begun to assess the consequences that resulted from the Cold War …

Martian Dune Fields: Aeolian Activity, Morphology, Sediment Pathways, And Provenance, Matthew Chojnacki

Doctoral Dissertations

Wind has likely been the dominant geologic agent for most of Mars’ history. The wide-spread nature of sand dunes there shows that near-surface winds have commonly interacted with plentiful mobile sediments. Early studies of these dunes suggested minimal activity, dominantly unidirectional simple dune morphologies, and little variations in basaltic sand compositions. This dissertation examines martian sand dunes and aeolian systems, in terms of their activity, morphologies, thermophysical properties, sand compositions, geologic contexts, and source-lithologies using new higher-resolution orbital data. Although previous evidence for contemporary dune activity has been limited, results presented in Chapter II show substantial activity in Endeavour Crater, …

Quantitative Integration Of Multiple Near-Surface Geophysical Techniques For Improved Subsurface Imaging And Reducing Uncertainty In Discrete Anomaly Detection, Megan Estelle Carr

Doctoral Dissertations

Currently there is no systematic quantitative methodology in place for the integration of two or more coincident data sets collected using near-surface geophysical techniques. As the need for this type of methodology increases—particularly in the fields of archaeological prospecting, UXO detection, landmine detection, environmental site characterization/remediation monitoring, and forensics—a detailed and refined approach is necessary. The objective of this dissertation is to investigate quantitative techniques for integrating multi-tool near-surface geophysical data to improve subsurface imaging and reduce uncertainty in discrete anomaly detection. This objective is fulfilled by: (1) correlating multi-tool geophysical data with existing well-characterized “targets”; (2) developing methods for …

Formation And Alteration Of Basaltic Soils On Mars, Ian Oliver Mcglynn

Doctoral Dissertations

The current surface of Mars is an arid inhospitable environment, dominated by aeolian processes, composed of largely volcanic rocks that have little apparent indication of pervasive aqueous chemical weathering, and blanketed by dust. Rocks are composed of basalts and the “soil” sediments appear to be largely basaltic-derived, and are chemically similar on a global scale. If the climate was once warmer and wetter during the Noachian period, with environmental conditions favorable to the development of life, physically weathered remnants, such as large quantities of phyllosilicate minerals, should remain. Basaltic soils provide a crucial constraint on chemical and physical weathering processes, …

Characterizing Phyllosilicate Distribution, Abundance, And Origin On Mars, Christina Elizabeth Viviano

Doctoral Dissertations

Secondary phyllosilicates are hydrated minerals formed in the presence of liquid water. On Earth, their formation is often indicative of a neutral, water-rich environment, capable of supporting and preserving organic matter. Different phyllosilicate species may be produced in different pH levels and water-to-rock ratios. The identification of mineralogically diverse phyllosilicates in small, localized exposures on Mars provides a complex record of their formation processes. While discrete outcrops of phyllosilicates have been previously identified in high-resolution visible/near-infrared images of Mars, regional coverage of these phyllosilicate-rich areas at better resolution is limited. Furthermore, spectra of minerals in this wavelength range do not …

Dome Formation During Crustal Extension In The Himalaya: Kinematic And Pressure-Temperature-Time-Deformation Constraints On Extensional Exhumation Along The Southern Margin Of The Tibetan Plateau, Jackie M. Langille

Doctoral Dissertations

The Himalaya and Tibetan Plateau were built by a combination of south-directed thrusting, north-directed extension, and generally east-west-directed extension within the Himalaya and Tibetan Plateau all to accommodate convergence between the Indian and Eurasian plates that began in the Eocene. Normal-sense shear zones that accommodate roughly east-west-directed extension across the southern margin of the Himalaya have exhumed young metamorphic domes across the Himalayan front. These metamorphic domes contain high-grade metamorphic rocks bound by normal-sense shear zones. The purpose of this study is to evaluate how these normal-sense shear zones develop and how they exhume metamorphic domes, which remains poorly understood …

From The Mantle To The Moon: Studies Of Kimberlitic Ilmenites, Meteorite Fusion-Crusts, And The Moscoviense Basin On The Moon, Kevin Glenn Thaisen

Doctoral Dissertations

I have explored a variety of geologic problems in the course of the chapters contained within this dissertation. These include a study relating to the fusion crusts on meteorites, an impact basin of the Moon, and Siberian kimberlitic ilmenites. The first chapter explores two assumptions commonly employed in meteorite analysis; that fusion crust compositions represent the bulk-rock chemistry of the entire meteorite and that the vesicles within the fusion crust result from the release of implanted solar-wind volatiles. Neither of these assumptions was found to hold true in that study. The second chapter explores the unusual nature of the Moscoviense …

Dendroclimatology And Woodland Dynamics On The Volcanic Badlands Of Western New Mexico, U.S.A., Mark Daniel Spond

Doctoral Dissertations

My dissertation research addressed woodland dynamics and dendroclimatology on the volcanic badlands of western New Mexico. The research was intended to complement previous studies by: (1) assessing vegetation structure and composition dynamics at El Malpais National Monument between 1948–2010 using repeat photography; (2) improving knowledge of the influence of climate and land use on vegetation dynamics at El Malpais National Monument; (3) providing a unique tree-ring data set from Rocky Mountain juniper growing on the malpais; (4) elucidating relationships between Pacific teleconnections and radial growth in Rocky Mountain juniper; and (5) improving understanding of the dynamic nature of climate in …

Experimental Investigations Of Fluid–Mineral Interactions In Olivine And Dolomite, Michael Thomas Deangelis

Doctoral Dissertations

Geochemical processes involving the interaction of fluids and minerals occur in nearly every environment on the surface and in the crust of the Earth. The variety of fluid–mineral processes on the Earth is quite diverse, and these various processes can occur under a large range of geochemical conditions. Aqueous dissolution and alteration, hydration, protonation, solution–precipitation, diffusion, and fluid and isotope exchange are among the many fluid–mineral interaction processes that contribute to the overall cycling of elements on Earth. This dissertation uses analog experiments to examine fluid­–mineral interaction processes found in different geological environments and under a range of environmental conditions. …

The Paleoecology And Biogeography Of Ordovician Edrioasteroids, Rene Anne Lewis

Doctoral Dissertations

All organisms are subjected to the living and non-living influences of their surroundings. They derive their energy and essential materials, such as sunlight and nutrients, from their environment, sharing their world not only with members of their own species but also with members of other species. These interactions are central to the survival of the organism, forming reciprocating and integrated systems with other members of their environment. Paleoecology uses the fossil record to interpret and reconstruct life habits of past organisms and environments. By examining well-preserved fossil populations we can assess the relationship between the organisms and their surrounding environment, …

Petrology And Geochemistry Of Olivine-Bearing Diogenites And A Group Of Paired Howardites, Andrew William Beck

Doctoral Dissertations

Asteroid 4 Vesta, the largest differentiated body in the asteroid belt, is a protoplanet, much like those that accreted to form the Earth. Understanding the geology of Vesta furthers understanding of early differentiation processes that occurred on Earth and helps define igneous processes occurring on other differentiated bodies in the early solar system. Howardite, eucrite and diogenite (HED) meteorites, which are thought to have originated from Vesta, can be analyzed to better understand the geology of that asteroid. Here my colleagues and I investigate the petrology and geochemistry of two groups of HEDs. This work is timely, in that the …

Oceanic-Atmospheric And Hydrologic Variability In Long Lead-Time Forecasting, Abdoul Aziz Oubeidillah

Doctoral Dissertations

Water managers throughout the world are challenged with managing scarce resources and therefore rely heavily on forecasts to allocate and meet various water demands. The need for improved streamflow and snowpack forecast models is of the utmost importance. In this research, the use of oceanic and atmospheric variables as predictors was investigated to improve the long lead-time (three to nine months) forecast of streamflow and snowpack. Singular Value Decomposition (SVD) analysis was used to identify a region of Pacific and Atlantic Ocean SSTs and a region of 500 mbar geopotential height (Z500mb) that were teleconnected with streamflow and snowpack. The …

Remote Sensing Of Sediments And Volatiles On The Martian Surface And Terrestrial Analog Sites, Craig James Hardgrove

Doctoral Dissertations

The role of water and volatiles in the solar system is of critical interest in planetary science. Evidence for the past action of water or direct observation of water on a planetary body can indicate the potential to harbor life and is critical to human exploration of the solar system. We study two very different remote sensing techniques that address the issue of identifying water-related processes on the surface of other planetary bodies, and in particular, Mars. The first technique, combined thermal infrared and visible imaging, has been used extensively on Mars for determining the thermal inertia of surface materials. …

Advances In Seismic First-Arrival Tomography, David Paul Gaines

Doctoral Dissertations

Seismic first-arrival tomography is a technique currently experiencing a renaissance in popularity due to the simplicity of implementation and promising results for delineating a variety of subsurface targets. The purpose of this study is to investigate seismic first-arrival tomography in a variety of settings and applications, and thus to provide a solid framework for future work. The study largely consists of two separate themes, hydrogeophysics and low-velocity anomaly detection. Hydrogeophysics is an emerging field whereby measured geophysical properties are used as proxies for physical properties of the subsurface. This study represents one of the first high-resolution hydrogeophysical investigations in the …

Use Of Remote Sensing, Hydrologic Tree-Ring Reconstructions, And Forecasting For Improved Water Resources Planning And Management, Cody Lee Moser

Doctoral Dissertations

Uncertainties were analyzed in three areas (remote sensing, dendroclimatology, and climate modeling) relevant to current water resources management. First, the research investigated the relationships between remotely sensed and in situ Snow Water Equivalent (SWE) datasets in three western U.S. basins. Agreement between SWE products was found to increase in lower elevation areas and later in the snowpack season. Principal Components Analysis (PCA) revealed two distinct snow regions among the datasets and Singular Value Decomposition (SVD) was used to link both data products with regional streamflow. Remotely sensed SWE was found to be sufficient to use in statistically based forecast models …

Holocene Climate And Environmental History Of Laguna Saladilla, Dominican Republic, Maria Anne Caffrey

Doctoral Dissertations

Stratigraphic analyses of lacustrine sediments provide powerful tools for reconstructing past environments. The records that result from these analyses are key to understanding present-day climate mechanisms and how the natural environment may respond to anthropogenic climate change in the future. This doctoral dissertation research investigates climate and environmental history at Laguna Saladilla (19° [degrees] 39' N, 71° [degrees] 42' W; ca. 2 masl), a large (220 ha) lake along the north coast of Hispaniola. I reconstructed changes in vegetation and environmental conditions over the mid to late Holocene based on pollen, microscopic charcoal, and diatoms in an 8.51 m sediment …

Carbon And Sulfur Cycling In Early Paleozoic Oceans, Cara Kim Thompson

Doctoral Dissertations

Here, I evaluate biospheric evolution during the Ordovician using high-resolution inorganic carbon and sulfur (carbonate-associated sulfate and pyrite) isotope profiles for Early Ordovician to early Late Ordovician strata from geographically distant sections in Western Newfoundland and the Argentine Precordillera. Additionally, I present new, high-resolution U-Pb ages for volcanic ash beds within strata of the Argentine Precordillera. Carbon isotope data record subdued variation that is typical of Early- to Middle Ordovician strata worldwide. By contrast, sulfur-isotopic compositions of carbonate-associated sulfate reveal a complex signal of short-term, rhythmic variation superimposed over a longer-term signal. This short-term, rhythmic variation occurs in all sections …