Physical Sciences and Mathematics Commons^™

Infrared Spectra And Magnetic Properties Of Fluorine Substituted Copper (Ii) Alkanoates, Jose G. Rodriguez

Masters Theses

"The purpose of this study was to prepare some selected copper(II) fluorcalkanoates, investigate their magnetic susceptibilities, study the infrared spectra of these salts and compare these properties to those of the unfluorinated copper(II) alkanoates….

The experimental data obtained indicate that the copper(II) trifluoroacetate, perfluoropropanoate and perfluorosuccinate does not form a binuclear cage structure. Copper(II) 3-(trifluoromethyl) butanoate with a magnetic moment of 1.4 should possess a binuclear case structure similar to copper( II) acetate monohydrate. The structure for copper( II) perfluoroglutarate monohydrate with a magnetic moment of 1.63 B.M. should have a structure somewhere between the two aforementioned structures"--Abstract, page ii.

Preparation And Spectra Of Some New Alkyl Ammonium Salts Of The Tetrachlorocuprate (Ii) Ion., Paul Douglas Griffin

Masters Theses

"Several compounds containing the complex tetrachlorocuprate(II) anion, CuCl₄⁼, and various alkyl or aryl cations were prepared. These include bis(methylammonium)tetrachlorocuprate(II), bis(isopropylammoniumtetrachlorocuprate(II), 1,3-propanediammoniumtetrachlorocuprate(II), bis(furfuryl-ammonium)tetrachlorocuprate(II), and a series of ethylene ammonium salts. Some unsuccessful and difficult preparations are described. Spectra were taken in acetone, 4-butyrolactone, and methanoleaf An explanation of the effects of various solvents on the absorption spectrum and structure of the complex ion is given"--Abstract, page ii.

Noble Gases In The Earth And Its Atmosphere, Robert Anthony Canalas

Masters Theses

"Abundance of noble gases extracted from Fig Tree Shale exhibit a marked deviation from the gas content of eclogitic rocks purported to be mantle material. The abundances of the heavy noble gases in shale were found to exceed the highest known meteoritic values. The abundances of the lighter noble gases were found to be comparable to the abundances of these gases in typical chondrites.

Temperature gradient analyses show that excess heavy gases are released at low temperatures. This is interpreted to indicate a preferential adsorption of the heavy noble gases on fine-grained sediments when these gases were being released from …

Mechanisms Of Base-Catalyzed Reactions: Part Iii: The Acidities Of Some Hydroxylic Compounds In T-Butyl Alcohol., Charles Frederick Seger

Masters Theses

"The K_HA of water and five alcohols were determined in t̲-butyl alcohol employing sodium and potassium t̲-butoxides. The order of acidity is methanol>water>ethanol> 2-propanol~cyclohexanol>methanol. It was also shown that potassium t̲-butoxide was twice as strong a base as sodium t̲-butoxide. A spectrophotometric method was employed with p-nitroaniline as the indicator. Calculations were made employing the methods of Stearns and Wheland and of Hine and Hine"--Abstract, page iii.

The Acidic Transformaion Products Of Indoles Formed By Basidiomycetes, Chung-Ke Chang

Masters Theses

"A survey of the ability of basidiomycetes to convert tryptophan, tryptamine and indole acetic acid to other acidic indoles has been made.

The product formed from tryptamine by Tricholoma nudum was identified as indole acetic acid. The product formed by Cantharellus cibarius from D-tryptophan was identified as N-acetyl-D-tryptophan. The products were purified and identified by means of paper chromatography, thin layer chromatography, infrared spectroscopy and melting points.

The conversion of tryptamine and D-tryptophan was also studied in cultures of Leucopaxillus paradoxus, Hygrophorus conicus and Naucoria confragosa. H. conicus, L. paradoxus and N. confragosa transformed tryptamine and indole acetic acid into …

An Investigation Of The Reaction Of Benzhydryl Chloride With Potassium T-Butoxide In Dmso, Lawson Gibson Wideman

Masters Theses

"The ultimate aim of this study was to elucidate the mechanism of formation of tetraphenylethylene from benzhydryl chloride and potassium t-butoxide in dimethyl sulfoxide. The development of a suitable technique for following the reaction rate and of an analytical method to determine the extent of the reaction became an important object in this project"--Introduction, page 2.

An X-Ray Study Of The Lead Titanate-Bismuth Chromate System, Tsen-Tsou Shih

Masters Theses

"The lead titanate-bismuth chromate system was studied employing x-ray diffraction techniques at both room and high temperatures. Samples were prepared by sintering stoichiometric mixtures of the corresponding oxides followed by air quenching. Bismuth chromate was prepared by resintering and air quenching for four times. The results of the analyses show the structure of BiCrO₃ to be tetragonal with 8 molecules per unit cell. Solid solutions exist over the range 100 to 35 mole percent PbTiO₃ of the binary system, although small amounts of other phases are present in some regions. X-ray data at room temperature indicate the tetragonal perovskite structure …

The Activity Of Succinic Dehydrogenase And Indole Acetic Acid Oxidase In Cell-Free Preparations Of Hygrophorous Conicus, Jagdish M. Mehta

Masters Theses

"The enzyme indole acetic acid oxidase is produced by the fungus Hygrophorous conicus when it is grown in the presence of indole acetic acid (IAA) or tryptamine. The IAA acts both as an inducer and a substrate for this intracellular enzyme. The product of the oxidation catalyzed by the IAA oxidase is oxindole acetic acid (OIAA).

The rate of growth and the rate of formation of the enzyme IAA oxidase by H.conicus were studied in different media. Of these, a nitrate medium containing 0.5 per cent Yeast extract (Y.E.) was found to be the best for the production of H.conicus …

Studies On The Conversion Of Indole Acetic Acid And Oxindole Acetic Acid By Hygrophorous Conicus, Barbara Ruth Patterson

Masters Theses

"The fungus, Hygrophorous conicus, produces the enzyme, indole acetic acid oxidase, when grown in the presence of indole acetic acid (IAA) or tryptamine. The IAA acts both as an inducer and a substrate for this intracellular enzyme. The product of the oxidation catalyzed by the IAA oxidase is oxindole acetic acid (OIAA). Since the IAA and OIAA absorb maximally at two different wavelengths the use of spectrophotometric analysis was possible for assaying for the IAA oxidase activity. Paper chromatography was used for qualitative identification of the IAA and OIAA. The rate of growth and the rate of formation of the …

A Graphical Method Of Estimating Heat Capacities Of Hydrocarbons, Pu-Ying Liu

Masters Theses

"Heat capacity arises because the individual particles comprising a substance are able to move and thus take up kinetic energy and usually also potential energy as the temperature rises. In many substances electrons do not absorb energy until very high temperatures are reached. Thus most heat capacity effects are interpreted in terms of the motion of the atoms neglecting electronic transitions. The total internal energy of a material is, therefore, equal to the sum of the energies due to translational and rotational motion of the molecules and to the vibrational motion of the atoms making up the molecules...The objective of …

I. An Investigation Of The Organic Compounds In The Media And Mycelium Of Naucoria Confragosa. Ii. Study Of The Extra-Cellular Pigments Of An Unknown Fungus, Yueh-Tsun Chen

Masters Theses

"The fungal metabolites excreted into the culture fluid by basidiomycetes growing on synthetic glucose media as well as formed in the mycelia of the organisms were investigated in this thesis. Earlier unpublished work had shown that Maucoria confragosa excreted into the medium compounds which were thought to be phenols. Insufficient material was recovered from an ethyl acetate extract of the medium in the present study for further investigation. Colorimetric methods were employed both for the quantitative estimation of reducing sugar not consumed by the microorganisms as well as for a measure of the total organic solids present in the spent …

Thermal Hydrolysis And Structure Studies On Cobalt (Ii) Acetate, Russell J. Hesch

Masters Theses

"The object of this study was to investigate the structure of cobalt (II) acetate, isolated from glacial acetic acid, without recourse to standard x-ray methods"--Introduction, page 1.

Stereochemistry Of Chlorinated Diels-Alder Adducts, Harry R. Musser

Masters Theses

"Hexachlorocyclopentadiene and related compounds have been studied extensively in connection with Diels-Alder reactions. Many of the adducts formed are used as intermediates in insecticide syntheses. It is of interest to study the stereochemistry of the adducts of one of the hexachlorocyclopentadiene derivaites. 5,5-Dimethoxy-1,2,3,4-tetrachlorocyclopentadiene and various dienophiles, when allowed to react, yield compounds of the bridges bicyclo [2.2.1] hept-2-ene series. The study of the endo and/or exo configuration of various functional groups such as carboxyl, aldehyde, and hydroxymethyl can be related to the known exo-5-hydroxymethyl1-1,2,3,4-tetrachlorobicyclo-[2.2.1] help-2-ene-7-one"--Introduction, page [1].

Transformations Of Tryptamine And Tryptophan By Basidiomycetes, Hsaio-Lung Cheng

Masters Theses

"The product formed from tryptamine by Trichloloma nudum was identified as indoleacetic acid (IAA) and from tryptophan by Cantharellus cibrarius as indolelactic acid (ILA). The products were extracted from the spent media with organic solvents. Purification and identification of the crystalline transformation products were accomplished by means of paper chromatography, spectrophotometry and thin layer chromatography.

The conversion of tryptamine and tryptophan was also studied in cultures of Lencopaxillus paradoxus, Pluteus granularis and Pleuatus ostreatus. Only Pluteus granularis was found to transform tryptamine into IAA. Lencopaxillus paradoxus transformed tryptamine into oxindoleacetic acid (OIAA).

Paper chromatography proved to be useful …

An X-Ray Study Of The Lead Zirconate-Bismuth Ferrate System, Pen-Chu Chou

Masters Theses

"The lead zirconate-bismuth ferrate system was studied employing x-ray and microscopic analysis. Samples were prepared by sintering stoichiometric mixtures of the corresponding oxides followed by air quenching. The results of the analyses show the system to be probably solid solutions over the entire compositional range, although small amounts of other phases are present in some regions.

X-ray data indicate a multiple cell, orthorhombic phase, to exist over the range 100-30 mole percent PbZrO₃ . From 100-82 mole percent PbZrO₃ , the addition of BiFeO₃ reduces the distortion of the phase such that a nearly cubic x-ray pattern is obtained at …

Coprecipitation Of Metal Salts With Organic Coprecipitants, Omar E. El-Arini

Masters Theses

"Coprecipitation studies were carried out for the more insoluble salts of six common metals and five anion systems. Three metal sulfides, namely, CuS, CdS and NiS, were the only metal salts studied that indicated nearly complete coprecipitation with phenolphthalein as carrier precipitate. The same salts showed almost no coprecipitation with B-naphthol as carrier precipitate. Solvent extraction of CuS with chloroform showed no significant amount of extraction had taken place. The data obtained in this work did not disclose any relationship between the extent of coprecipitation and the solubility product constant of the salt present. The main difficulty encountered at this …

Distribution Of Sodium Perchlorate Between Tributyl Phosphate And Water, John A. Tengler

Masters Theses

"The questions posed by Carroll (23) concerning a TBP-H₂O system and an alkali salt -which is appreciably soluble in TBP have been partially answered by the experiments described in this thesis"--Conclusions, page 38.

Correlation Between Drying Times Of A Vinyl Copolymer Solution And Properties Of Dried Films., Abd El-Rahman M. Naser

Masters Theses

"One of the common methods used in film formation is the solvent evaporation method. As the evaporation starts the viscosity increases due to the inability of the solvent to keep the chains apart, which leads to a drag between molecules.

The rate of evaporation of the solvent (loss of solvent) cannot be equated with the rate of drying, since the latter depends on the results of the loss of solvents in terms of viscosity and plastic properties. The drying time can be defined as the rate at which a film increases its viscosity and thus changes the properties of a …

Solubility And Structure Studies Of Nickel (Ii) Acetate, Richard J. Baird

Masters Theses

"The effects of ammonium acetate on the solubility of anhydrous nickel (II) acetate in anhydrous acetic acid was investigated and was found to behave similar to the zinc (II), copper (II), and cobalt (II) systems. Problems with equilibrium, encountered by previous investigators, were overcome. The determination of the structure of nickel (II) acetate hemiacetate was atacked by infrared studies, preparation of adducts, cryoscopic studies, magnetic susceptibility measurements, and absorption spectra. It was found that nickel (II) acetate hemiacetate is octahedrally coordinated with two coordination sites vacant. It was shown that the binuclear cage structure common to copper (II), chromium (II), …

Magnetic Structure Investigations At The Nuclear Center, R. Ballestracci, E. F. Bertaut, J. Coing-Boyat, A. Delapalme, William Joseph James, R. Lemaire, R. Pauthenet, G. Roult

Chemistry Faculty Research & Creative Works

The magnetic structure of the compounds UOS, ß-CoSO₄, YCO₅, and HoCO₅ is briefly described.

UOS is antiferromagnetic. The Néel temperature is T_n=55°K. The magnetic cell is doubled in the c direction with a ++ - - sequence of U moments along c. The apparent spin is S∼1. The negative interaction corresponds to U-O-U links.

In ß-CoSO₄ (high-temperature modification, space group Pbnm), Co atoms are in 000, 00½, ½½½, ½½0. Here three different antiferromagnetic spin modes, mutually perpendicular, A_x(+ - - +), G_y(+-+-), and C_z(++ - - …

The Reaction Of Sodium Iodide In Acetone With Halogenated Epoxides -- A Mechanism Study, Thomas E. Breuer

Masters Theses

"l-bromo-2,3-epoxybutane reacted with sodium iodide in acetone to give 3-iodo-l,2-epoxybutane in 70.1 per cent yield. 3-bromo-l,2-epoxybutane produced l-iodo-2,3-epoxybutane in 69.9 per cent yield when it was allowed to react with a solution of sodium iodide in acetone. No other product could be isolated after either reaction, although it is possible that another compound may have been produced in very small amounts. The iodoepoxides were oxidized to the corresponding α-iodoacid in approximately ninety per cent yield by silver oxide"--Summary, page 40.

The Anodic Dissolution Of Zinc In Aqueous Solutions, Glenn E. Stoner

Masters Theses

"The increasing demand for protective metals as coatings and non-corrosive alloys has stimulated extensive research on the fundamental behavior of metals in corrosive media.

One of the problems still unsolved is the nature of the mechanism of the anodic dissolution of metals like zinc, magnesium, beryllium, cadmium, and aluminum in aqueous salt solutions. Several schools of investigators have proposed different and opposing theories to explain the discrepancies which often arise between coulometric data and the weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for the anodic dissolution of zinc …

Permeation Of Water Vapor Through Linear Polymer Films, Mohammed S. Rifai

Masters Theses

"Film formation from thermoplastic resin solutions Is Influenced by secondary intermolecular forces. Consider what may happen when organic coatings change from a liquid to a solid state. In the liquid state it is logical to consider the linear polymer molecules as agglomerates being dispersed in the volatile component rather than being present In solution. These molecular agglomerates are referred to as micelles. They have various degrees of orientation depending on the extent and the location of dipole forces in both polymer and solvent molecules.

When a coating is applied the solvent starts to evaporate and the micelles are driven closer …

The Separation Of Germanium From Lead, Cadmium, And Zinc By Ion Exchange, Myra Sue Anderson

Masters Theses

"The object of this study was to investigate the ion exchange behavior of germanium in order to find a quantitative separation method applicable to the analysis of germanium in zinc ores.

Germanium had been predicted and described as eka-silicon by Mendeleeff, and was discovered by Winkler in 1886. The importance of the metal has increased very much since World War II because of its use as a semiconductor in diodes and transistors.

All commercial scale germanium is now produced as a by-product of base metal processing. Although the United States Bureau of Mines is conducting a program for the recovery …

The Dielectric Strength Of Some Anti-Corrosive Paints, George Albert Chappell Iii

Masters Theses

"Corrosion has been one of the costly problems to industry because each year losses due to corrosion are in excess of six billion dollars. Corrosion is caused by the tendency of all metals to become oxidized and return to their natural state. Oxidation may be suppressed by restraining the flow of electrons from the system, thereby inhibiting corrosion.

One effective means to prevent rusting is by applying a barrier of paint between the system and the corrosive atmosphere. Not all paints, however, are equally effective as corrosion inhibitors. At present, the only effective means of determining the corrosion resistant ability …

A Study Of The Colloidal Properties Of Zirconium And Promethium By Electrodialysis And Liquid-Liquid Extraction, James N. Click

Masters Theses

"The purpose of this investigation was to study the solution chemistry of zirconium by investigating the colloidal behavior of natural zirconium and zirconium-95, utilizing electrodialysis and liquid-liquid extraction techniques. Also incorporated into this study was the investigation of optimum conditions for the extraction of the natural zirconium and zirconium-95 with thenoyl trifluoracetone. A limited amount of work was done on the colloidal nature of promethium-147"--Introduction, pages 2-3.

A Study Of The Behavior Of Zirconium In Aqueous Solutions And The Separation Of Radioactive Zirconium By Electrodialysis, Charles William Brauer Jr.

Masters Theses

"Nuclear reactor installations designed for power production must of necessity operate at higher energy levels than their experimental precursors. As these facilities increase in number, better solutions must be found for both technical and economic problems.

The disposal of waste materials is of primary importance and will require greater effort if satisfactory disposal methods are to keep pace with the increase of waste materials, produced by the increasing number of new nuclear facilities. The radioactive materials present in this waste material may constitute a valuable by-product from these operations if suitable and economic recovery procedures are developed. If the development …

Perfection Of The Lattice Of Dislocation-Free Silicon, Studied By The Lattice-Constant And Density Method, Martin E. Straumanis, Pierre Borgeaud, William Joseph James

Materials Science and Engineering Faculty Research & Creative Works

The lattice-constant and density method revealed that a high-purity silicon crystal free of dislocations has a perfect lattice without an excess of vacant sites or interstitials (n′=8.0000 4) within the limits of error, in agreement with the results obtained with the decoration method. The lattice constant of vacuum heated silicon powder of semiconductor purity was 5.43070±0.00004 A; that of the nonheat-treated powder was 5.43081 A at 25°C. The constants determined from crystal chips by the rotating crystal method were lower: between 5.43028-5.43048 A at 25°C. As the constants of each series of measurements could be reproduced very well (s=±0.00004 A), …

Evaluation Of The Force Constants Of Non-Polar Gases From Viscosity Data, Kei-Sin Wei

Masters Theses

"The analytical expressions for the transport coefficients (i.e. viscosity, thermal conductivity, and diffusivity) of an ideal gas can be derived from the kinetic theory of gases. It is also possible to make these analytical expressions adequate for real gases if the intermolecular forces of attraction and repulsion for these gases have been taken into consideration.

The intermolecular forces have been studied by many investigators. The Lennard-Jones potential is one of the most realistic semi-empirical statements which represents particularly the intermolecular forces of attraction and repulsion for non-polar gases.

The values of the Lennard-Jones potential parameters or the force constants of …

Oxygen Permeability Of Free Paint Films, Janice I. Kellerman

Masters Theses

"As early as the mid 1800’s investigations were performed on the gas passage through rubber, but it is only comparatively recently that plastic polymeric materials have come into prominence. One interesting aspect of much experimentation begun was that of permeability, and it was soon evident that, in general, polymeric materials have extremely low permeability of gases. This is, in essence, the basis for use of plastics as packaging materials, balloons, and in many other designs and fabrications where it is desirous and/or necessary to exclude air.

There are several variables which must be taken into consideration in the evaluation of …