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Chemistry

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Missouri University of Science and Technology

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Full-Text Articles in Physical Sciences and Mathematics

Water Splitting By Mixed Chalcogenide Catalysts, Isabella Feltenstein Apr 2021

Water Splitting By Mixed Chalcogenide Catalysts, Isabella Feltenstein

Undergraduate Research Conference at Missouri S&T

The depleting supply of fossil fuels has led to deeper investigation of water-splitting as a sustainable energy source. Specifically, using transition metal chalcogenides to catalyze the water-splitting reaction through oxygen and hydrogen evolution reactions. While the decreasing electronegativity of the chalcogenide group increases their activity, it also decreases their stability, leading to the investigation of mixed anion chalcogenides in order to keep both the stability and activity high. This research will further the understanding and efficiency of water-splitting for energy storage and inspire more research in the future. In these experiments, cobalt telluroselenide (Cox-Tey-Sez) and nickel telluroselenide (Nix-Tey-Sez) catalysts were …


Chemically Resolved Nuclear Spin Relaxation, Megan Sly Apr 2021

Chemically Resolved Nuclear Spin Relaxation, Megan Sly

Undergraduate Research Conference at Missouri S&T

In Nuclear Magnetic Resonance (NMR) Spectroscopy, the excitation of nuclear spins is used to generate spectra of radiofrequency resonance signals. The signal frequencies are typically used to determine the structure of chemical compounds, while the relaxation of the spins to thermodynamic equilibrium provides useful information about the molecular vicinity of a material. When a chemical compound occurs in different molecular environments, a single resonance signal can have multiple relaxation times. To quantify how much material is in how many different environments, a multi-exponential analysis was developed resolving resonance signals and relaxation times in two-dimensional contour plots. Samples of known resonance …


Amorphous Carbon Aerogels From Xerogel Powders, Daniel Greenan Apr 2021

Amorphous Carbon Aerogels From Xerogel Powders, Daniel Greenan

Undergraduate Research Conference at Missouri S&T

Carbon aerogels are well known for their high surface areas and high porosities. Their applications have been demonstrated in a wide range of areas such as CO2 capture, electrodes for electrochemical cells, etc. They are typically made from pyrolysis of carbonizable polymeric aerogels, which in turn are synthesized via sol-gel methods. Preparation of those polymeric aerogels involves supercritical fluid drying of wet-gels by replacing the pore-filling solvent with liquid CO2 that can be vented off as a gas, thus allowing pores to retain their shape and size. In contrast, here a new alternative route is proposed for the synthesis of …


2nd Annual Undergraduate Research Conference Abstract Book, University Of Missouri--Rolla Apr 2006

2nd Annual Undergraduate Research Conference Abstract Book, University Of Missouri--Rolla

Undergraduate Research Conference at Missouri S&T

No abstract provided.