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Full-Text Articles in Physical Sciences and Mathematics

A Mechanism For Upscale Growth Of Convection In The Complex Terrain Of The Northeast U.S, Brennan Joseph Stutsrim Aug 2021

A Mechanism For Upscale Growth Of Convection In The Complex Terrain Of The Northeast U.S, Brennan Joseph Stutsrim

Legacy Theses & Dissertations (2009 - 2024)

Upstate New York has a variety of complex terrain that can interact with the background flow to create mesoscale heterogeneities in the lower troposphere. The major valleys of Upstate New York, the Hudson and Mohawk Valleys, often have increased moisture content and stronger surface winds than the higher terrain surrounding them. These features can have a profound effect on the evolution of convective storms, especially in cases characterized by low-to-moderate shear, which tends to favor pulse-like or multicellular convection. Analysis of composite radar imagery has indicated that convective storms often change mode while descending from the Catskills Mountains into the …


Seasonal Differences In The Impacts Of Ipo And Amo On Temperature And Precipitation Over South America, Thomas Favata May 2021

Seasonal Differences In The Impacts Of Ipo And Amo On Temperature And Precipitation Over South America, Thomas Favata

Legacy Theses & Dissertations (2009 - 2024)

The Atlantic Multidecadal Oscillation (AMO) and Interdecadal Pacific Oscillation (IPO) have been shown to impact temperature and precipitation across the globe. However, the seasonal differences in their impacts are not well studied. This study analyzes the seasonal differences in the impacts of the AMO and IPO on South American temperature and precipitation. Observational and reanalysis data with enough temporal coverage to isolate the multidecadal modes were used first to identify the regions impacted by the AMO and IPO through a correlation analysis. Then Empirical Orthogonal Functions (EOF) and a Maximum Covariance Analysis (MCA) were used to determine the seasonal spatial …


Diagnosing High Sinuosity Regimes Associated With Anomalous Greenland Ice-Melt Events Using Self-Organizing Maps, Mansour El Riachy May 2021

Diagnosing High Sinuosity Regimes Associated With Anomalous Greenland Ice-Melt Events Using Self-Organizing Maps, Mansour El Riachy

Legacy Theses & Dissertations (2009 - 2024)

Sinuosity, a metric that describes the waviness of the circumpolar flow, is adapted to quantify modification of the tropospheric polar vortex within longitudinal sectors by localized incursions of warm, moist air from middle latitudes associated with Arctic cyclones (ACs). In this thesis, we identify four corridors of high AC track frequency, on which we center 90° longitudinal sectors comprising the following regions: Pacific, West of Greenland, Atlantic, and Asian. Sectorial sinuosity is calculated for the West of Greenland sector and is used to quantify the amplitude of the 300-hPa flow associated with anomalous Greenland ice-melt events.


On The Structure And Phase Speeds Of The Kelvin Waves And Mjo Over The Indian Ocean, Ahmed Shaaban May 2021

On The Structure And Phase Speeds Of The Kelvin Waves And Mjo Over The Indian Ocean, Ahmed Shaaban

Legacy Theses & Dissertations (2009 - 2024)

Kelvin waves in the stratosphere are well known to behave as radiative gravity waves. Yet, the tropospheric component of these Kelvin waves (and other tropical modes) has often been described as superpositions between the baroclinic modes. By decomposing the Kelvin waves into upward and downward-phase components, we found that only upward-phase Kelvin waves occupy the troposphere, indicating that the tropospheric Kelvin waves are not vertical standing oscillations as previously thought. Fast Kelvin waves were found to obey the structure of radiating gravity waves, like their stratospheric counterpart, more than the moist waves. The unexpected lack of variation in vertical tilt …


Land-Atmosphere-Cloud Interaction : Sensitivity Of Weather Forecast Models To Complex Land Surface Conditions In New York State, Lanxi Min Jan 2021

Land-Atmosphere-Cloud Interaction : Sensitivity Of Weather Forecast Models To Complex Land Surface Conditions In New York State, Lanxi Min

Legacy Theses & Dissertations (2009 - 2024)

The land-atmosphere coupling system is important for the simulation of key quantities like surface temperature, precipitation, and radiative energy. Over the complex terrain of New York State, the land-atmosphere coupling process is quite complex and misrepresenting the coupling processes could lead to strong biases. Evaluating the weather forecasting models is vital for enhancing understanding of physical and processes and further improving the model forecasting. A comprehensive observation network, the New York State Mesonet (NYSM) provides a great opportunity to investigate how the land atmosphere coupling process are simulated over complex terrain region. This research includes three components. In first part, …


An Examination Of The Arctic Environment And Arctic Cyclones During Periods Of Low And High Forecast Skill Of The Synoptic-Scale Flow, Kevin Biernat Jan 2021

An Examination Of The Arctic Environment And Arctic Cyclones During Periods Of Low And High Forecast Skill Of The Synoptic-Scale Flow, Kevin Biernat

Legacy Theses & Dissertations (2009 - 2024)

This dissertation compares Arctic environmental conditions and Arctic cyclones (ACs) between periods of low and high forecast skill of the synoptic-scale flow over the Arctic during summer, hereafter referred to as low-skill periods and high-skill periods, respectively. This dissertation also examines features and processes influencing the evolution and forecast skill of selected categories of ACs.


Seasonal Variations And Long-Term Trend Of Mineral Dust And The Effects Of Dust On Cloud And Precipitations, Yanda Zhang Jan 2021

Seasonal Variations And Long-Term Trend Of Mineral Dust And The Effects Of Dust On Cloud And Precipitations, Yanda Zhang

Legacy Theses & Dissertations (2009 - 2024)

For its enormous emission rate and long-range transport ability, mineral dust is one of the most abundant aerosol species, contributing to about half of the global atmospheric aerosol dry mass burden. A series of studies demonstrated the significant influences of mineral dust on air quality, public health, biogeochemical cycles, and climate systems. In the atmosphere, mineral dust is known to have important impacts on the Earth system through direct effects (scattering and absorbing shortwave and longwave radiations), semi-direct effects (changing atmospheric temperature structure and cloud lifetime), and indirect effects (influencing cloud microphysics processes as cloud condensation nuclei (CCN) and ice-nucleating …


Aerosol And Terrain Effects On Winter Cloud And Precipitation Over New York State, Yuyi Du Jan 2021

Aerosol And Terrain Effects On Winter Cloud And Precipitation Over New York State, Yuyi Du

Legacy Theses & Dissertations (2009 - 2024)

Prediction of regional weather and climate regarding precipitation for a region such as the Northeast US with its complex terrain and aerosol environment constitutes a major challenge. Furthermore, complex thermodynamic structures occur in and around New York State (NYS) owing to its complex topography paired with its coastal regions, ultimately affecting cloud and precipitation microphysics. The microphysical processes within the weather systems that produce orographic precipitation are not fully understood. These processes include, but are not limited to, liquid-ice interactions, ice growth through vapor deposition, riming, and aggregation, cloud-aerosol interactions, and melting and refreezing upon sedimentation to the surface. These …


The Sensitivity Of Convection To Boundary Layer Parameterization In Hurricanes Harvey And Irma 2017, Dylan Card Jan 2021

The Sensitivity Of Convection To Boundary Layer Parameterization In Hurricanes Harvey And Irma 2017, Dylan Card

Legacy Theses & Dissertations (2009 - 2024)

Tropical cyclones (TCs) pose a significant threat to life and property, and exhibit many severe weather hazards as they make landfall, such as storm surge, strong winds, flooding rains, and tornadoes. TC convection is associated with nearly all of these hazards, which can extend hundreds of kilometers inland; thus, understanding the characteristics and organization of convective cells is important to mitigating risk. Observational studies have noted that TC convection tends to organize downshear and that rotating thunderstorms tend to occur in the downshear-right quadrant of the TC. Modeling studies have also shown that convective cells tend to form upshear right …


Identifying The Microphysical Sensitivities Of Mesoscale And Synoptic Precipitation Using An Ensemble Framework, Lauriana Gaudet Jan 2021

Identifying The Microphysical Sensitivities Of Mesoscale And Synoptic Precipitation Using An Ensemble Framework, Lauriana Gaudet

Legacy Theses & Dissertations (2009 - 2024)

Through ensemble sensitivity analysis, this dissertation aims to identify the amount of forecast uncertainty that stems from the representation of mixed-phase cloud microphysics within the Weather Research and Forecasting Model (WRF). The first research thrust focuses on how the evolution of ice crystal shape and choice of ice nucleation parameterization in the Adaptive Habit Microphysics Model (AHM) influences the lake-effect storm that occurred during Intensive Operating Period 4 (IOP4) of the Ontario Winter Lake Effect Systems (OWLeS) Field Campaign. This localized snowstorm produced total liquid-equivalent precipitation amounts up to 17.92 mm during a 16-hour time period, providing a natural laboratory …


Process-Based Evaluation Of Stochastic Perturbed Parameterization Tendencies On Ensemble Forecasts Of Heavy Rainfall Events, Kevin Michael Lupo Jan 2021

Process-Based Evaluation Of Stochastic Perturbed Parameterization Tendencies On Ensemble Forecasts Of Heavy Rainfall Events, Kevin Michael Lupo

Legacy Theses & Dissertations (2009 - 2024)

Stochastic model error schemes, such as the stochastic perturbed parameterization tendencies (SPPT) and independent SPPT (iSPPT) schemes, have become an increasingly utilized method to represent model error associated with uncertain subgrid-scale processes in ensemble prediction systems (EPSs). While much of the current literature focuses on how stochastic methods influence ensemble skill, relatively less attention is given to the processes by which these schemes lead to forecast variability. In this vein, this dissertation examines the physical processes by which the application of SPPT and iSPPT to the microphysics, planetary boundary layer (PBL), and radiation parameterization schemes yields rainfall forecast variability. These …


Physical Characteristics And Microphysical Processing Of Atmospheric Aerosol In Rural And Urban New York State, Joseph Marto Jan 2021

Physical Characteristics And Microphysical Processing Of Atmospheric Aerosol In Rural And Urban New York State, Joseph Marto

Legacy Theses & Dissertations (2009 - 2024)

Atmospheric aerosol has profound impacts on air quality, though particles of differing sizes can have profoundly different characteristics which are understated when measurements are reported as a single parameter (typically number concentration or total mass). To address some of these concerns and to better understand the nature of atmospheric aerosol, continuous particle size distributions have been measured at two sites in New York State. Measurement was performed for particle diameters between 7.6nm - 20µm at Pinnacle State Park (Addison, New York; March 2017-April 2018) and Queens College (May 2018-September 2019) at a 5-minute time resolution. At Pinnacle State Park, aerosol …


Evaluating The Performance Of National Water Model Snow Simulations In The Northeastern United States Using Advanced Mesonet Observations, Patrick William Naple Jan 2021

Evaluating The Performance Of National Water Model Snow Simulations In The Northeastern United States Using Advanced Mesonet Observations, Patrick William Naple

Legacy Theses & Dissertations (2009 - 2024)

Snow is a critical component in the hydrologic cycle and critical to runoff in many regions. While not as deep or persistent as snow in the Western United States (WUS) , snow in the Northeastern US (NEUS) is critical to water resource management and flood forecasting. For hydrological applications, snow is simulated using coupled hydrology models . These models couple numerical weather models, land surface models, and channel routing models that simulate water transport. One such coupled hydrology model is the NOAA National Water Model (NWM), implemented in 2016. The NWM runs a specific configuration of the WRF-Hydro community model. …


The Role Of Ammonia In Atmospheric New Particle Formation And Implications For Cloud Condensation Nuclei, Arshad Arjunan Nair Jan 2021

The Role Of Ammonia In Atmospheric New Particle Formation And Implications For Cloud Condensation Nuclei, Arshad Arjunan Nair

Legacy Theses & Dissertations (2009 - 2024)

Atmospheric ammonia has received recent attention due to (a) its increasing trend across various regions of the globe; (b) the associated direct and indirect (through PM2.5) effects on human health, the ecosystem, and climate; and (c) recent evidence of its role in significantly enhancing atmospheric new particle formation (NPF or nucleation) rates. The mechanisms behind nucleation in the atmosphere are not fully understood, although over the last decade there have been significant developments in our understanding. This dissertation aims at improving our understanding of atmospheric ammonia in the atmosphere, its spatiotemporal variability, its role in atmospheric new particle formation, and …


The Impact Of North Pacific And North Atlantic Baroclinic Cyclones On Downstream Predictability, Adam Wayne Sisco Jan 2021

The Impact Of North Pacific And North Atlantic Baroclinic Cyclones On Downstream Predictability, Adam Wayne Sisco

Legacy Theses & Dissertations (2009 - 2024)

Baroclinic cyclogenesis can act as an impulsive disturbance along the midlatitude waveguide and promote the dispersion of Rossby waves, potentially impacting the predictability of the downstream midlatitude flow. Indeed, several studies have traced medium-range forecast errors and uncertainties to upstream cyclone development, especially when diabatic processes are involved in modifying the upper-tropospheric potential vorticity (PV) distribution. However, it remains unclear why some forecasts downstream of cyclogenesis are particularly uncertain while others are not. This study uses a 30-yr (1985–2014) sample of cool-season North Pacific and North Atlantic baroclinic cyclones and forecasts from the second-generation Global Ensemble Forecast System (GEFS) reforecast …


High-Resolution Simulation Of A Tornado In Bangladesh On 13 May 1996, Katherine Hollinger May 2020

High-Resolution Simulation Of A Tornado In Bangladesh On 13 May 1996, Katherine Hollinger

Atmospheric & Environmental Sciences

The country of Bangladesh has been known to experience some of the deadliest tornado outbreaks in the world. The severe weather season in this region only spans from late March to early May, but can produce significant severe weather outbreaks in that short time. Even with these outbreaks occurring, there has not been extensive analysis completed to evaluate the environmental parameters on these tornado event days in this region.

The goal of this project is to use a Weather Research and Forecasting (WRF) model simulation to evaluate a significant tornado that occurred in the Tangail and Jamalpur districts in Bangladesh …


Examining Terrain Effects On Upstate New York Tornado Events Utilizing High-Resolution Model Simulations, Luke Lebel May 2020

Examining Terrain Effects On Upstate New York Tornado Events Utilizing High-Resolution Model Simulations, Luke Lebel

Atmospheric & Environmental Sciences

The region at the intersection of the Mohawk and Hudson valleys of New York is characterized by complex terrain. It has been hypothesized that this complex terrain may have an impact on the development and evolution of severe convection in the region. Specifically, previous research has hypothesized that terrain-channeled flow in the Hudson and Mohawk valleys contributed to increased low-level wind shear and instability in the valleys during past severe weather outbreaks. However, a lack of observations in the region prevented this hypothesis from being robustly tested.

The goal of this study is to further examine this hypothesis and complement …


The Rapid Weakening Of Hurricane Fred (2009), Christina Talamo May 2020

The Rapid Weakening Of Hurricane Fred (2009), Christina Talamo

Atmospheric & Environmental Sciences

This research project discusses the rapid weakening of Hurricane Fred, a major Category 3 hurricane that occurred in the Atlantic basin during the 2009 Atlantic hurricane season. Between the days of 9 September and 13 September, Fred remained stationary off the coast of Africa in the Atlantic Ocean and never made landfall, all the while consistently weakening over open ocean from a major Category 3 hurricane to a tropical storm. In the Atlantic basin, I will define the rapid weakening, or RW, of a tropical cyclone as a decrease in the storm’s maximum sustained winds by 10.3 m s⁻¹ in …


The Impact Of Warm Conveyor Belt Forecast Uncertainty On Downstream Predictability, Jeremy Berman Jan 2020

The Impact Of Warm Conveyor Belt Forecast Uncertainty On Downstream Predictability, Jeremy Berman

Legacy Theses & Dissertations (2009 - 2024)

Perturbations to the potential vorticity (PV) waveguide can lead to the downstream radiation of Rossby waves, and in turn high-impact weather events. The PV waveguide is often perturbed in association with cyclogenesis, largely due to the latent heat release within the cyclone’s warm conveyor belt (WCB). Previous studies have hypothesized that forecast uncertainty associated with diabatic heating in WCBs can result in large downstream forecast variability; however these studies have not established a direct connection between the two. This hypothesis is evaluated for six cyclogenesis events characterized by highly amplified flow over the North Atlantic using ensemble model simulations.


Examining The Impact Of Synoptic-Scale Waves On Stratospheric Polar Vortex Variability From An Ensemble Forecast Perspective, Michael E. Main Jan 2020

Examining The Impact Of Synoptic-Scale Waves On Stratospheric Polar Vortex Variability From An Ensemble Forecast Perspective, Michael E. Main

Legacy Theses & Dissertations (2009 - 2024)

Major Sudden Stratospheric Warming (SSW) events are characterized by rapid warming of the polar regions at 10 hPa and are accompanied by a reversal of the 10-hPa zonal-mean zonal wind at 60˚N from westerly to easterly. Following an SSW event, stratospheric thermal and momentum anomalies can progress downward and linger near the tropopause for up to 60 days. These anomalies have major impacts on tropospheric sensible weather including increased likelihood of cold air outbreaks and heavy precipitation events. SSW events are largely forced by upward propagation of planetary-scale Rossby waves from the troposphere to the stratosphere. Synoptic-scale waves can contribute …


Ozone And Reactive Oxidized Nitrogen Chemistry In The Northeast U.S, Matthew Ninneman Jan 2020

Ozone And Reactive Oxidized Nitrogen Chemistry In The Northeast U.S, Matthew Ninneman

Legacy Theses & Dissertations (2009 - 2024)

Ongoing reductions in oxides of nitrogen concentrations ([NOx] = nitric oxide ([NO]) + nitrogen dioxide ([NO2])) throughout the continental United States (U.S.) have important implications for tropospheric ozone (O3) and reactive oxidized nitrogen chemistry (NOy ≈ NOx + nitric acid (HNO3) + particle nitrate (pNO3) + peroxy nitrates (PNs) + alkyl nitrates (ANs)). Specifically, decreasing [NOx] concentrations have likely (1) increased the sensitivity of O3 to the [NOx] level, and (2) affected NOy speciation and partitioning. An understanding of the impacts of continued [NOx] reductions is needed to inform current and future air pollution control strategies, especially since the National …


Factors Influencing Rainfall Over The Congo, Ajay Raghavendra Jan 2020

Factors Influencing Rainfall Over The Congo, Ajay Raghavendra

Legacy Theses & Dissertations (2009 - 2024)

The hydrological cycle over tropical rainforests includes some of the most intense thunderstorms and rainfall totals. The energy associated with this convective activity plays an important role in the Earth’s weather and climate system. Therefore, the interannual variability, trends, and future climate projections of the hydrological cycle over tropical rainforests are important topics for research. The Congo rainforest situated over equatorial Africa is the second largest rainforest in the world, and recent studies have documented a >30-year large-scale and long-term drying trend over the Congo since the late-1970s. However, unlike the Amazon rainforest in South America, the Congo rainforest is …


Evaluating Large-Scale And Storm-Scale Characteristics Of Rapidly Intensifying And Slowly Intensifying Tropical Cyclones Using An Analog Approach, Jannetta C. Richardson Jan 2020

Evaluating Large-Scale And Storm-Scale Characteristics Of Rapidly Intensifying And Slowly Intensifying Tropical Cyclones Using An Analog Approach, Jannetta C. Richardson

Legacy Theses & Dissertations (2009 - 2024)

Tropical cyclone (TC) intensity change is modulated by a combination of large-scale and storm-scale processes. On the large-scale, several factors exhibit strong controls on TC rapid intensification (RI): the initial TC intensity, the environmental vertical wind shear (VWS), and the background thermodynamic environment, which determines the TC’s maximum potential intensity (MPI). Previous statistical studies comparing RI and non-RI TCs have shown that TCs undergoing RI tend to be embedded in environments of lower VWS, and have initial intensities that are farther from their MPIs. Although numerous statistical studies have compared the large-scale and storm-scale conditions of RI and non-RI TCs, …


An Analysis Of Temperature Trends In The Northeast United States : 1950-2019, Christopher Selca Jan 2020

An Analysis Of Temperature Trends In The Northeast United States : 1950-2019, Christopher Selca

Legacy Theses & Dissertations (2009 - 2024)

The warming signal associated with anthropogenic climate change shows a significant positive trend globally over the last century. Trends in the magnitude and frequency of annual mean and extreme events do not display a globally uniform signal, as some regions have shown negative trends. This study examines the trends in daily mean and extreme temperatures in the Northeast region of the United States. Station data was selected from the GHCN-D Version 3 data set, using a blend of stations from the weather forecast offices and the cooperative observing network. Station criteria included using a threshold of less than 5% of …


Improving Our Understanding Of The Relationship Between Ocean Heat Uptake And Climate Sensitivity, Michael Cameron Rencurrel Jan 2020

Improving Our Understanding Of The Relationship Between Ocean Heat Uptake And Climate Sensitivity, Michael Cameron Rencurrel

Legacy Theses & Dissertations (2009 - 2024)

One of the ultimate goals of the field of climate science is to determine exactly how sensitive the Earth is to anthropogenic forcing, with far reaching implications both from a scientific and policy standpoint. However, despite decades of observational and model analysis, large uncertainties in Earth's climate sensitivity persist. Recent advances have shown that climate feedbacks, the primary mechanism driving the sensitivity spread, are dependent on the spatial patterns of the surface response, intrinsically linked to how the ocean is working to uptake and transport energy across the globe. Given the importance of reducing the range of climate sensitivity from …


Easterly Waves Over The Eastern Pacific, Victor Manuel Torres Puente Jan 2020

Easterly Waves Over The Eastern Pacific, Victor Manuel Torres Puente

Legacy Theses & Dissertations (2009 - 2024)

The research in this thesis explores different processes associated with the life cycle of Easterly Waves over the tropical Eastern Pacific. These include genesis, structural evolution, intensification and a dissipating stage.


Global Circulation Variability Associated With Mjo Phase Speed, Alexander Marat Tomoff Jan 2020

Global Circulation Variability Associated With Mjo Phase Speed, Alexander Marat Tomoff

Legacy Theses & Dissertations (2009 - 2024)

Differences in the Madden–Julian oscillation (MJO) phase speed help explain some of the variability in the global circulation patterns associated with the MJO. Select mechanisms that identify these distinctive circulation signals are applied to help explain MJO variability associated with different phase speeds. Wavelet filter analysis is first used to compute regression models of the MJO at different phase speeds, isolating the associated patterns in outgoing longwave radiation (OLR), geopotential height, and upper-level wind. Covariance matrices provide a deeper understanding of how the tropical and extratropical patterns compare between two phase speeds at any point in time. Both Fourier and …


The Significance Of The Nontraditional Coriolis Terms In Tropical Large-Scale Dynamics, Heng Wang Jan 2020

The Significance Of The Nontraditional Coriolis Terms In Tropical Large-Scale Dynamics, Heng Wang

Legacy Theses & Dissertations (2009 - 2024)

The nontraditional Coriolis terms (NCTs) turn eastward motion upward and upward motion westward, and vice versa. NCTs are omitted in most of the current global atmospheric models. However, NCTs are significant in tropical large-scale dynamics in at least three aspects. 1) Using an idealized model that can switch NCTs on or off, omitting NCTs biases large-scale flow response to prescribed diabatic forcing mimicking the intertropical convergence zone (ITCZ). The omission yields a westerly wind bias in the heating region ~ 10% of the westerly jet stream. This bias is due to lack of westward NCT when heating-induced upward motion is …


Dynamical Downscaling Of Near-Term Climate Variability And Change For The Main Hawaiian Islands Using Wrf, Katrina Marie Fandrich Jan 2020

Dynamical Downscaling Of Near-Term Climate Variability And Change For The Main Hawaiian Islands Using Wrf, Katrina Marie Fandrich

Legacy Theses & Dissertations (2009 - 2024)

As climate models continue to improve, the demand from resource managers and decision-makers for more accurate climate projections is increasing. However, natural climate variability poses a limit to the confidence in regional climate change projections, particularly for the mid-21st century. The unique geographic location of the Hawaiian Islands and its regional climate provide a challenging opportunity for climate modelers. The goal of this project is to examine both the Pacific Decadal Oscillation (PDO) and anthropogenic climate change for their impacts on near-term rainfall and temperature projections for the Hawaiian Islands. Of primary interest are the questions 1) is there a …


Water Vapor Near-Uv Absorption: Laboratory Spectrum, Field Evidence, And Atmospheric Impacts, Linsen Pei, Qilong Min, Yuyi Du, Zhechen Wang, Bangsheng Yin, Kai Yang, Patrick Disterhoft, Thomas Pongetti, Lei Zhu Nov 2019

Water Vapor Near-Uv Absorption: Laboratory Spectrum, Field Evidence, And Atmospheric Impacts, Linsen Pei, Qilong Min, Yuyi Du, Zhechen Wang, Bangsheng Yin, Kai Yang, Patrick Disterhoft, Thomas Pongetti, Lei Zhu

Environmental Health Sciences Faculty Scholarship

Absorption of solar radiation by water vapor in the near-UV region is a poorly-understood but important issue in atmospheric science. To better understand water vapor near-UV absorption, we constructed a cavity ring-down spectrometer with bandwidth of 5 cm-1 (~0.05 nm) and obtained water vapor absorption cross-sections at 1 nm increments in the 290-350 nm region. Water vapor displays structured absorption over this range with maximum and minimum cross-sections of 8.4×10-25 and 1.6×10-25 cm2/molecule. Major water vapor absorption bands were observed at 293-295, 307-313, 319, 321-322, and 325 nm, with cross-section values higher than 4.0×10-25 …