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2004

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Can We Predict Joint Effects Of Hypoxia And Metals On Fish Survival?, Michael C. Newman Jan 2004

Can We Predict Joint Effects Of Hypoxia And Metals On Fish Survival?, Michael C. Newman

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Fish are suddenly exposed to hypoxic conditions during diverse events such as seiche- or turnover-related water movements, bottom water release from reservoirs, ice-over of eutrophic arctic lakes, and rapid shifts in respiration: photosynthesis associated with cultural eutrophication. In each case, chemical equilibria established under hypoxic conditions that result in metal dissolution and accumulation suddenly shift toward chemical equilibria of oxic conditions. Critical changes in speciation include those determining the free ion activity that, as expressed by the Free Ion Activity Model (FIAM), is often the most bioactive form of a dissolved metal. Metal phase can also change rapidly and, in …