Nuclear Engineering Commons^™

Radiation Effects On Metastable States Of Superheated Water, Charles William Alvord

Doctoral Dissertations

Radiation Effects on Metastable States of Superheated Water covers theory, application, and experimentation into the behavior of water at temperatures above the boiling point. The backgrounds of Positron Emission Tomography target design, bubble chambers, and superheat measurements are presented. The quantitative theory of metastable liquids and their characteristic waiting time is discussed. Energetics of bubble formation from two different perspectives are included. Finally, the design of an apparatus for measuring liquid superheats in the presence of radiation is covered in some detail, including several design iterations, first measurements made on the apparatus, and techniques for data reduction.

Optimal Designs Of Mobile Nuclear Engines To Power Manned Vehicles On Mars, Robert D. Woolley

Masters Theses

This work develops original conceptual designs for compact nuclear fission reactor engines to power robust mobile equipment operating on the surface of the planet Mars. This is a nuclear application area not well explored in previous publications. Some novel analytical approaches are developed herein, including the application of optimal control theory to minimize radiation shielding mass. This work also provides the first study of using another planet's atmosphere to implement open-cycle thermal conversion systems.

To power equipment on Mars for extended durations at sustained power levels ranging from one hundred horsepower to several thousand horsepower, there is no practical alternative …

High Temperature Heat Exchanger Annual Report, Anthony Hechanova

Publications (NSTD)

Objectives

• Identify candidate materials for heat exchanger components.

• Test candidate materials for heat exchanger components.

• Design critical components in the interface between the reactor and hydrogen production plant and within the sulfur iodine thermochemical process.

• Fabricate prototypical components.

• Test prototypical components.

Distribution Iteration: A Robust Alternative To Source Iteration For Solving The Discrete Ordinates Radiation Transport Equations In Slab And Xy- Geometries, Nicholas J. Prins

Theses and Dissertations

The discrete ordinates method is widely used to solve the Boltzmann transport equation for neutral particle transport for many engineering applications. Source iteration is used to solve the discrete ordinates system of equations, but can be slow to converge in highly scattering problems. Synthetic acceleration techniques have been developed to address this shortcoming; however, recent research has shown synthetic acceleration to lose effectiveness or diverge for certain problems. LTC Wager introduced an alternative to source iteration and demonstrated it in slab geometry. Here the method is further developed, enhancing efficiency in various ways, and demonstrated in XY-geometry as well as …

Spatially Resolved Optical Absorption Spectrometry And Single Crystal Diffraction On Metamict Materials, Alison Savage, Oliver Tschauner, Sergey Tkachev

Undergraduate Research Opportunities Program (UROP)

A major goal in developing storage medium for radioactive waste is the identification of chemically suitable and durable material for storage in repositories (Lumpkin 2006). Radiation damage induces enhanced chemical diffusion and structural breakdown of the host materials, which can lead to contamination of the surrounding environment. During this project four different naturally occurring materials which are common carriers of thorium and uranium were examined : gadolinite, perrierite, allanite, and pyrochlore of which the first three are silicates and pyrochlore being an oxide. Their spectra and absorptions bands were examined to identify prominent features due to radiation damage. The goal …

Dose Modeling And Statistical Assessment Of Hot Spots For Decommissioning Applications, Eric Warner Abelquist

Doctoral Dissertations

A primary goal of this research was to develop a technically defensible approach for modeling the receptor dose due to smaller "hot spots" of residual radioactivity. Nearly 700 combinations of environmental pathways, radionuclides and hot spot sizes were evaluated in this work. The hot spot sizes studied ranged from 0.01 m² to 10 m², and included both building and land area exposure pathways. Dose modeling codes RESRAD, RESRAD-BUILD, and MicroShield were used to assess hot spot doses and develop pathway-specific area factors for eleven radionuclides. These area factors are proposed for use within the existing Multiagency Radiation …

An Improved Knockout-Ablation-Coalescence Model For Prediction Of Secondary Neutron And Light-Ion Production In Cosmic Ray Interactions, Sirikul Sriprisan

Doctoral Dissertations

An analytical knockout-ablation-coalescence model capable of making quantitative predictions of the neutron and light-ion spectra from high-energy nucleon-nucleus and nucleus-nucleus collisions is being developed for use in space radiation protection studies. The FORTRAN computer code that implements this model is called UBERNSPEC. The knockout or abrasion stage of the model is based on Glauber multiple scattering theory. The ablation part of the model uses the classical evaporation model of Weisskopf-Ewing. In earlier work, the knockout-ablation model was extended to incorporate important coalescence effects into the formalism. Recently, the coalescence model was reformulated in UBERNSPEC and alpha coalescence incorporated. In addition, …

A Methodology For Establishing Zones Of Acceptable Caas Coverage For A New Storage Facility Utilizing Mcnp 5 In Adjoint, Zia A. Tompkins

Masters Theses

ANSI/ANS 8.3 “Criticality Accident Alarm System”, Appendix B states “Determining the adequacy of criticality alarm detector placement is far from an exact process”. With this statement in mind a novel method for establishing areas of acceptable Criticality Accident Alarm System (CAAS) coverage was developed and demonstrated utilizing Los Alamos’ Monte Carlo N-Particle Code 5 (MCNP5) in multigroup Adjoint. Validation of the methodology was shown in the comparison of benchmark calculations with empirical results of Sandia testing and with hand calculations utilizing ANS 8.3. Demonstration involved the determination of zones of CAAS coverage from detector sensitivity maps generated by MCNP5 for …

The Solubility And Diffusivity Of Helium In Mercury With Respect To Applications At The Spallation Neutron Source, Matthew W. Francis

Doctoral Dissertations

Models for solubility of noble gases in liquid metals are reviewed in detail and evaluated for the combination of mercury and helium for applications at the Spallation Nuetron Source (SNS) at Oak Ridge National Laboratory (ORNL). Gas solubility in mercury is acknowledged to be very low; therefore, mercury has been used in ASTM standard methods as a blocking media for gas solubility studies in organic fluids and water. Models from physical chemistry predict a Henry coefficient for helium in mercury near 3.9x10¹⁵ Pa-molHg/molHe, but the models have large uncertainties and are not verified with data. An experiment is designed …

Nuclear Energy, Steve Kraft

Native American Forum on Nuclear Issues

Abstract:

-Why Nuclear Energy?

-The lesson of the last 20 years in U.S. electricity policy:

– Diversified fuel and technology portfolio is essential

– All fuels and technologies (nuclear, coal, natural gas, renewables, efficiency) have a legitimate role

-The challenge for the future:

– Preserving/restoring diversified portfolio

– Ensuring resource adequacy, particularly in competitive markets

-Expanded use of nuclear energy is part of the answer

– Integrated used fuel management supports nuclear competitiveness

Neutron Detection Utilizing Gadolinium Doped Hafnium Oxide Films, Bryan D. Blasy

Theses and Dissertations

Gadolinium (Gd) doped hafnium oxide (HfO₂) was deposited onto a silicon substrate using pulsed laser deposition. Synchrotron radiation was used to perform Gd L3-edge extended X-ray absorption fine structure (EXAFS) measurements on 3%, 10%, and 15% doped HfO₂ samples. The interatomic distances determined from Fourier transformation and fitting the data show Gd occupying the hafnium site in the HfO₂ lattice, there was no clustering of Gd atoms, and the Gd ion retains monoclinic local symmetery for all levels of doping. Current as a function of voltage experiments identified the films as having poor diode characteristics with …

Evaluating The Response Of Polyvinyl Toluene Scintillators Used In Portal, Kelly D. Rakes

Theses and Dissertations

The goal of this research work was to determine if there exists, and to what extent, variability in the pulse-height spectrum, and resolution produced by ɤ-photon induced scintillation events in polyvinyl toluene scintillators. Scintillator panels of the same type as those used in portal detector units currently operated by the Department of Homeland Security, made of polyvinyl toluene and measuring 12 x 15 x 2 in were purchased from three vendors. Each vendor supplied two scintillators, one wrapped by the vendor with aluminum foil coated mylar, and two unwrapped. The scintillators where exposed to an ≈ 8µCi source collimated …

Micro-Etched Platforms For Thermal Inactivation Of Bacillus Anthracis And Bacillus Thuringiensis Spores, Leslie S. Hawkins

Theses and Dissertations

This research developed and applied microlithography techniques to etch microscope slide platforms in order to measure thermal inactivation of Bacillus thuringiensis and Bacillus anthracis spores, two closely related Bacillus species. B.t. is widely used as a surrogate for B.a. in response studies and in some field studies. This work addressed the previously identified problem of measuring both spore growth and spore thermal kill threshold using the traditional method of spreading a diluted spore solution on a plate. The micro-etched platforms forced spore separation thereby preventing neighbor growth from obscuring germination and initial vegetative growth measurements using a microscope. The technique …

Discrete Counting Of Short Lived Isotopes With Low Background Detectors, David E. Mather

Theses and Dissertations

We consider radiation counting experiments used to measure quantities of materials that are short-lived with respect to the count durations. The HPS 13.31 statistical analysis seriously overestimates the uncertainty when the quantity and background are very low. We consider the case in which the objective is to quantify the number of atoms, n, that were present in a sample when it was drawn. Mathews and Gerts [JRNC, 2008] analyzed this case and developed formulas for the probability distribution of n, in order to develop experiment design processes that minimize the smallest detectable quantity of material, thus maximizing sensitivity for the …

Preliminary Evidence Of Field Induced Rhenium Etching By Xef₂ At High Vacuum, M. Aghazarian, D. N. Ruzic, Carlos Henry Castano Giraldo

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Preliminary evidence of enhanced etching of rhenium by XeF2 under the influence of an electric field (3.36 GV/m) is presented. Scanning electron microscope photographs of sharp rhenium tips show etching of at least 0.40 µm ±0.07 in 32 min at the point of maximum electric field, indicating a field enhanced etching rate of 13 nm/min ±2. A control experiment shows a maximum spontaneous etching of rhenium by XeF2 of 0.1 µm ±0.07 in 30 min, indicating a maximum possible spontaneous etching rate of rhenium by XeF2 of 3 nm/min ±2. The spontaneous rate of tungsten by XeF2 reported in the …

Evaluation Of Cs/Sr Waste Form For Long Term Storage And Disposal, Gary Cerefice

Waste Forms Campaign (TRP)

The goal of this project is to examine the potential long term performance of the proposed aluminosilicate waste/storage form for the isolation and eventual direct disposal of the cesium and strontium separated from recycled nuclear fuel. In the first phase of this work, researchers will investigate the sintering procedure to prepare the drum-like aluminosilicate waste/storage form from the as-received aluminosilicate powder, and then examine the basic physical properties, phase structure and microstructure of the sintered aluminosilicate with /without mixing solution with several ppm Cs/Sr. In the second phase, researchers will evaluate the interaction of the proposed waste form with structural …

Knowledge-Based Information Resource Management System For Materials Of Sodium-Cooled Fast Reactor, Sean Hsieh

Reactor Campaign (TRP)

In the development of advanced fast reactors, materials and coolant/material interactions pose a critical barrier for higher temperature and longer core life designs. For advanced burner reactors (sodium cooled) such as EBR-II and FFTF, experience has shown that the qualified structural materials and fuel cladding severely limits the economic performance. In other liquid metal cooled reactor concepts, advanced materials and better understanding and control of coolant and materials interactions are necessary for realizing the potentials.

Liquid sodium has been selected as the primary coolant candidate for Gen. IV nuclear energy systems. Global Nuclear Partnership (GNEP) Advanced Burned Reactor (ABR) has …

Reactivity Control Schemes For Fast Spectrum Space Nuclear Reactors, Aaron E. Craft, Jeffrey C. King

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Several different reactivity control schemes are considered for future space nuclear reactor power systems. Each of these control schemes uses a combination of boron carbide absorbers and/or beryllium oxide reflectors to achieve sufficient reactivity swing to keep the reactor subcritical during launch and to provide sufficient excess reactivity to operate the reactor over its expected 7-15 year lifetime. The size and shape of the control system directly impacts the size and mass of the space reactor's reflector and shadow shield, leading to a tradeoff between reactivity swing and total system mass. This paper presents a trade study of drum, shutter, …

Correlation Of Tellurium Inclusions And Carrier Lifetime In Detector Grade Cadmium Zinc Telluride, Ezzat S. Elshazly, Gary C. Tepper

Mechanical and Nuclear Engineering Publications

Carrier lifetimes and telluriuminclusion densities in detector grade cadmiumzinc telluride crystals grown by the high pressure Bridgman method were optically measured using pulsed laser microwavecavity perturbation and infrared microscopy. Excess carriers were produced in the material using a pulsed laser with a wavelength of 1064 nm and pulse width of 7 ns, and the electronic decay was measured at room temperature. Spatial mapping of lifetimes and defect densities in cadmiumzinc telluride was performed to determine the relationship between telluriumdefect density and trapping. A strong correlation was found between the volume fraction of telluriuminclusions and the carrier trapping time.

The Nonlinear Dynamics Of Tapping Mode Atomic Force Microscopy With Capillary Force Interactions, Nicole N. Hashemi, H. Dankowicz, M.R. Paul

Nastaran Hashemi

We study the nonlinear dynamics of a tapping mode atomic force microscope with tip-surface interactions that include attractive, repulsive, and capillary force contributions using numerical techniques tailored for hybrid or discontinuous dynamical systems that include forward-time simulation with event handling and numerical pseudo-arclength continuation. We find four branches of periodic solutions that are separated by windows of complex and irregular dynamics. The branches of periodic solutions end where the cantilever comes into grazing contact with event surfaces in state space, corresponding to the onset of capillary interactions and the onset of repulsive forces associated with contact. These windows of irregular …

The Dissipated Power In Atomic Force Microscopy Due To Interactions With A Capillary Fluid Layer, Nicole N. Hashemi, M.R. Paul, H. Dankowicz, W. Jhe

Nastaran Hashemi

We study the power dissipated by the tip of an oscillating micron-scale cantilever as it interacts with a sample using a nonlinear model of the tip-surface force interactions that includes attractive, adhesive, repulsive, and capillary contributions. The force interactions of the model are entirely conservative and the dissipated power is due to the hysteretic nature of the interaction with the capillary fluid layer. Using numerical techniques tailored for nonlinear and discontinuous dynamical systems we compute the exact dissipated power over a range of experimentally relevant conditions. This is accomplished by computing precisely the fraction of oscillations that break the fluid …

Separation Of Technetium From Uranium And Waste Form Synthesis, Kenneth Czerwinski

Waste Forms Campaign (TRP)

In this project, systematic investigations on the Tc-Zr binary metal system will be evaluated for the first time. The synthesis of metallic Tc as well as its alloys with Zr will be evaluated. In order to provide valuable data to AFC R&D, the thermodynamic equilibrium phases, as well as their performance under repository conditions, will be examined.

The research objectives of this project are as follows:

• Evaluate anion exchange methods for achieving the separation of Tc from U.

• Synthesize metallic Tc from the separated product.

• Synthesize and characterize Tc alloys.

• Investigate Tc-corrosion and Tc-leaching of binary …

Evaluation Of Cs/Sr Waste Form For Long Term Storage And Disposal, Gary Cerefice, Longzhou Ma

Waste Forms Campaign (TRP)

To facilitate long-term storage, the disposal containers will need to be able to survive for the entire storage interval. The first aspect of the project will explore the potential interaction of the aluminosilicate waste form with the storage canister materials to determine if there is any corrosion or chemical interaction concerns for the storage of the materials. At the end of the storage interval, most of the cesium (¹³⁷Cs) in the waste form will have decayed to its daughter, barium (¹³⁷Ba). While this decay provides a significant reduction in the decay heat generated by the waste …

Development Of Integrated Process Simulation System Model For Spent Fuel Treatment Facility Design, Yitung Chen, Sean Hsieh

Separations Campaign (TRP)

The major objectives will lead to the creation of a framework that combines all the strengths of AMUSE’s complicated calculations, well-established commercial system process package, and ISOPro’s flexible parameter optimization modules. Development of the process simulation code can be done using the solvent extraction process at Argonne National Laboratory in collaboration with the research team from the Mechanical Engineering Department at UNLV.

Research accomplishments:

• Completed final version of the ISOPro User Manual associated with summarized ISOPro source codes.

• Redesigned and completed use case and design class diagrams (DCD) of the ISOPro package using ArgoUML.

• Improved ISOPro system …

Reactor Physics Studies For The Afci Reactor-Accelerator Coupling Experiments Project, Denis Beller

Transmutation Sciences Physics (TRP)

The specific research objective of this three-year project was to design and conduct accelerator driven experiments, to help demonstrate the ability to design, compute, and conduct ADS experiments and to predict and measure source importance, coupling efficiency, sub-critical reactor kinetics and source-driven transients. In addition, databases were created for both steady state and transient ADS experiments for the nuclear community to develop and test new computational codes and methods. The importance of a driving neutron source in various regions of different subcritical assemblies was mapped. Experiments were conducted and compared to calculations with radiation transport and thermal hydraulics codes such …

Fundamental And Applied Experimental Investigations Of Corrosion Of Steel By Lbe Under Controlled Conditions: Kinetics, Chemistry Morphology, And Surface Preparation, John Farley, Allen L. Johnson

Transmutation Sciences Materials (TRP)

Advanced nuclear processes and facilities (e.g., transmutation of nuclear waste, fast reactors, and spallation neutron sources) impose special demands on materials, which must withstand high temperatures, high radiation fields, and chemical corrosion. Proposed schemes for transmuting nuclear waste require a nonmoderating coolant such as lead-bismuth eutectic (LBE) or liquid sodium. While LBE corrodes most steels, small amounts of oxygen in the LBE greatly reduces the corrosion rate, and could ideally re-grow a damaged oxide layer in situ. The protective oxide layer would thus be self-healing. However, a fundamental understanding of the role of oxygen and passivating oxide layers is presently …

Effect Of Silicon Content On The Corrosion Resistance And Radiation-Induced Embrittlement Of Materials For Advanced Heavy Liquid Metal Nuclear Systems, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The beneficial effects of Si on both the metallurgical and corrosion properties of Cr-Mo steels have previously been demonstrated at UNLV. Therefore, additions of Si ranging from 0.5-2.0 weight percent (wt%) was attempted in this investigation to explore Si effect on both the high temperature tensile properties and corrosion behavior of T91 grade steel. Corrosion studies in the presence of molten LBE could not be performed due to a lack of proper experimental facilities at UNLV. Therefore, detailed corrosion studies involving Si-containing T91 grade steels were performed in an aggressive aqueous solution of acidic pH. Further, significant efforts have been …

Theoretical Modeling Of Protective Oxide Layer Growth In Non-Isothermal Lead Alloy Coolant Systems, Yitung Chen, Taide Tan, Jinsuo Zhang, Jichun Li

Transmutation Sciences Materials (TRP)

In advanced nuclear energy systems, lead alloys emerge as strong candidates for transmutation and advanced reactor systems as nuclear coolants and spallation neutron targets. However, it is widely recognized that corrosion of materials caused by lead alloys presents a critical barrier to their industrial use. A few experimental research and development projects have been set up by different groups such as at Los Alamos National Laboratory to study the corrosion phenomena in their test facilities and to develop mitigation techniques and materials. One of the central or main techniques under development is to use active control of oxygen thermodynamic activity …

Development Of Nanostructure Based Corrosion-Barrier Coatings On Steel For Transmutation Applications, Biswajit Das

Transmutation Sciences Materials (TRP)

Advanced transmutation systems require structural materials that are able to withstand high neutron fluxes, high thermal cycling, and high resistance to chemical corrosion. The current candidate materials for such structures are ferritic and ferritic-martensitic steels due to their strong resistance to swelling, good microstructural stability under irradiation, and the retention of adequate ductility at typical reactor operating temperatures.

In parallel, lead-bismuth eutectic (LBE) has emerged as a potential spallation target material for efficient production of neutrons, as well as a coolant in the accelerator system. While LBE has excellent properties as a nuclear coolant, it is also highly corrosive to …

Combined Radiation Detection Methods For Assay Of Higher Actinides In Separation Processes, Denis Beller, Charlotta Sanders, Warnick Kernan

Safeguards Campaign (TRP)

In the MPAC project, faculty and students are investigating the potential to use combined neutron and gamma-ray detector systems to measure quantities and isotopic constituents contained during separations and intermediate storage. This will require knowledge of the nuclear and decay characteristics of materials during processing, the development of conceptual designs of monitoring systems, radiation transport studies to develop an understanding of operational regimes, and experiments to confirm performance. In addition, both passive and active concepts will be investigated, including collaborations with the Idaho Accelerator Center at Idaho State University (ISU) to use electron linear accelerators for producing photoneutrons in situ, …