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Articles 1 - 12 of 12
Full-Text Articles in Nanoscience and Nanotechnology
Self-Assembly Of Exfoliated Graphene Flakes As Anticorrosive Coatings For Additive Manufactured Steels, Kaleb Hood, Wen Qian, Yi Xia, Savannah Krupa, Annie Dao, Sarah Ahmed, Samuel Olson, Nam Nguyen, Joseph A. Turner, Jun Jiao
Self-Assembly Of Exfoliated Graphene Flakes As Anticorrosive Coatings For Additive Manufactured Steels, Kaleb Hood, Wen Qian, Yi Xia, Savannah Krupa, Annie Dao, Sarah Ahmed, Samuel Olson, Nam Nguyen, Joseph A. Turner, Jun Jiao
Department of Mechanical and Materials Engineering: Faculty Publications
This study demonstrates the feasibility of using liquid exfoliation of expandable graphite into multilayer exfoliated graphene flakes (EGFs) to form a self-assembled thin film on an air–water interface. The film can coat the surface of additive manufactured (AM) steel substrates to enhance surface properties, specifically AM 316 stainless-steel (AM316), AM 8620 steel (AM8620), and samples of the same alloys made by conventional manufacturing (CM) processes. Liquid exfoliation offers a high yield route for an EGF coating that can cover up to 95% of the sample surface with a single application. The thin, flexible EGFs can coat a rough AM metal …
An Investigation On The Interface Corrosion Behaviors Of Cobalt Interconnects In Chemical Mechanical Polishing Slurry, Kai-Xuan Qin, Peng-Fei Chang, Yu-Lin Huang, Ming Li, Tao Hang
An Investigation On The Interface Corrosion Behaviors Of Cobalt Interconnects In Chemical Mechanical Polishing Slurry, Kai-Xuan Qin, Peng-Fei Chang, Yu-Lin Huang, Ming Li, Tao Hang
Journal of Electrochemistry
Cobalt is widely regarded as the most promising interconnect material for 10 nm node and beyond. The development of a chemical mechanical planarization (CMP) slurry suitable for cobalt interconnect is a critical component for the application of cobalt interconnect. During CMP process of the interconnect layer, the achievement of high-quality surface after planarization is greatly challenged by the metal corrosion in CMP slurry. In this contribution, the corrosion behavior of cobalt in a slurry with potassium persulfate (KPS) as an oxidizer, glycine as a complexing agent, and benzotriazole (BTA) as an inhibitor was investigated. Static erosion rates (SER) of cobalt …
Corrosion Protection Mechanisms Of Trivalent Chromium Based Passivations On Γ-Znni Coated Al6061-T6 Alloy, Kevin Foster
Corrosion Protection Mechanisms Of Trivalent Chromium Based Passivations On Γ-Znni Coated Al6061-T6 Alloy, Kevin Foster
Doctoral Dissertations
“The role of cobalt in trivalent chromium passivations (TCPs) to improve corrosion resistance of γ-ZnNi coated steel and aluminum is based on its effect on hexavalent chromium content in the passive layer. Investigations of both a cobalt-containing and cobalt-free TCP on SAE 1008 steel indicated that both passivations protect well for up to 1000 hours in neutral salt spray exposure (SSE). A repetition on Al 6061-T6 alloy indicated that TCP performed much better than cobalt-free TCP implicating the underlying substrate. Optical and electron micrographs indicated physical changes such as crack thickness, crack density, passivation porosity, and passivation thickness existed between …
Development Of Multilayer Titanium Nitride-Based Coatings As Corrosion Resistant Films For Stainless Steel Bipolar Plates In Pem Fuel Cells, Nicholas Padula
Development Of Multilayer Titanium Nitride-Based Coatings As Corrosion Resistant Films For Stainless Steel Bipolar Plates In Pem Fuel Cells, Nicholas Padula
Legacy Theses & Dissertations (2009 - 2024)
High cost and short lifetime are the two main reasons why the PEM fuel cell has not reached a widespread, disruptive level of commercialization. Conventional graphite bipolar plates are responsible for about 45% of the cost and 85% of the total weight of a single cell. These measures are linked to difficult machining of thick, brittle graphite and processing needed to render graphite non-porous. Stainless steel is suggested as the replacement bipolar plate material due to its favorable mechanical properties, ease of manufacturing and relatively low price, but requires a cost-effective coating as a non-conductive oxide forms on the bare …
Fabrication And Material Characterization Of Copper And Copper-Cnt Micropillars, Siavash Ghanbari, Jeff Darabi
Fabrication And Material Characterization Of Copper And Copper-Cnt Micropillars, Siavash Ghanbari, Jeff Darabi
SIUE Faculty Research, Scholarship, and Creative Activity
In this work, copper micropillars and copper-carbon nanotube (CNT) composite micropillars were fabricated by incorporating an electrodeposition technique with a xurography process. In order to disperse carbon nanotubes in copper-CNT micropillars, various amounts of CNTs were added to the electroplating bath. Surface morphology and phase characterization of copper micropillars and copper-CNT composite micropillars were analyzed by optical microscopy and X-ray diffraction. In addition, the corrosion resistance (Rp) of a bare copper substrate, copper micropillars, and optimum copper-CNT micropillars were studied by electrochemical impedance spectroscopy (EIS) technique in a 3.5 wt. % sodium chloride. Experimental results yielded a corrosion …
In Situ Detection On Electrochemical Chloride Removal Of Reinforcement In Concrete By Combined Ph/Cl- Probes, Jing-Jing Wang, Shi-Gang Dong, Xiao-Juan Zhang, Hong-Wei Lv, Yun-Chang Wu, Rong-Gui Du, Chang-Jian Lin
In Situ Detection On Electrochemical Chloride Removal Of Reinforcement In Concrete By Combined Ph/Cl- Probes, Jing-Jing Wang, Shi-Gang Dong, Xiao-Juan Zhang, Hong-Wei Lv, Yun-Chang Wu, Rong-Gui Du, Chang-Jian Lin
Journal of Electrochemistry
In this work, the concrete samples polluted by chloride ion were electrochemically treated using galvanostatic technique, and the distributions of chloride ion concentration and pH value in the polluted concretes were in-situ monitored by embedding a combined pH/Cl- probe during the electrochemical chloride removal. The corrosion behaviors of reinforcing steel in the concrete were simultaneously studied by using linear polarization and electrochemical impedance spectroscopy techniques (EIS). The micro environment of the concrete and corrosion rate of steel were explored during the electrochemical chloride removal. It was indicated that the Cl- concentration in the concrete pore solution decreased with …
Applications Of Spectroscopic Ellipsometry In Corrosion Investigation, Ling-Jie Li, Yu-Ling He, Jing-Lei Lei, Sheng Tao Zhang
Applications Of Spectroscopic Ellipsometry In Corrosion Investigation, Ling-Jie Li, Yu-Ling He, Jing-Lei Lei, Sheng Tao Zhang
Journal of Electrochemistry
As a highly-sensitive and non-destructive in situ technique, spectroscopic ellipsometry has been widely applied in corrosion investigation to acquire the dynamic information of the “electrode-medium” interface during corrosion. This paper lays out some representative demonstrations in several established optical models used to interpret data obtained with spectroscopic ellipsometry in corrosion investigation. In addition, the latest trends in development of this technique are analyzed.
Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy
Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy
Articles
Traditional anti-corrosion technology has relied heavily on using reducible metal species, predominantly hexavalent chromium (Cr(VI)), for protecting reactive metal alloys such as aluminium which is extensively used in the aerospace sector. However, the impending changes in the use of Cr(VI) in Europe and the United States have forced aerospace manufacturers to examine alternative materials for protecting aluminium. One of the most promising alternatives being investigated are organosilane based sol-gels containing anticorrosion additives. In this work the anti-corrosion properties of magnesium (II) nitrate (Mg(NO3)2) as a inhibitor was investigated at different concentrations (0.1% - 1.0 wt %) in a methyltriethoxysilane (MTEOS) …
Supercritical Water Oxidation Process And Its Application In Treatment Of Industrial Wastewater (Persian Paper), N. Daneshvar, S. Aber, Mir Saeed Seyed Dorraji, M. Zarei, M. H. Rasoulifard
Supercritical Water Oxidation Process And Its Application In Treatment Of Industrial Wastewater (Persian Paper), N. Daneshvar, S. Aber, Mir Saeed Seyed Dorraji, M. Zarei, M. H. Rasoulifard
Mir saeed Seyed Dorraji
In the last two decades, supercritical water has become an interesting medium for chemistry. One of its most investigated applications is the oxidative treatment of aqueous wastes containing organic compound in the so-called “supercritical water oxidation”. In this technology, supercritical water acts as a non-polar solvent. Consequently, even non-polar organic compounds and gases like oxygen become completely miscible with the supercritical fluid. During the supercritical water oxidation (SCWO) process, the organic compounds react completely with oxidant –mostly oxygen- in a single phase reaction forming CO2 and H2O. The hetero-atoms present in the organic wastes are transformed into the mineral acids. …
Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong
Study On Electrochemical Impedance Spectroscopy Of Carbon Steel Eroded In Methyldiethanolamine Solution, Dong-Ping Wei, Rong-Zong Hu, Dan-Mei Pan, Wei-Xiong Huang, Rui Dong
Journal of Electrochemistry
Corrosion behavior of carbon steel in methyldiethanolamine(MDEA) solution was investigated by Electrochemical Impedance Spectroscopy(EIS).The results were showed that the corrosion rate of carbon steel in solution containing dissolved oxygen is higher than that in solution removed of dissolved oxygen before cathodic activation.They were reversed after cathodic activation.The corrosion rate is increased at first and then decreased when the concentration of MDEA is increased in the blank solutions.In the simulated solutions containing quantities of!heat-stable salts(HSS),the corrosion rate is decreased monotonously with increase of the MDEA concentration.As anodic polarization potential is increased,the EIS of carbon steel in HSS simulated solution showed characteristics …
Avoid Sulfuric Acid Corrosion In Metallic Stacks, João F. Gomes
Avoid Sulfuric Acid Corrosion In Metallic Stacks, João F. Gomes
João F Gomes
Acidic gaseous effluents frequently cause corrosion on metallic stacks. This paper presents a method for prevision of probability of corrosion occurrence caused by gaseous effluents containing sulphur oxides which is based on the sulphur trioxide and moisture content measured in stack
Electrodeposition Nanolaminated Growth Of Zinc, Ying Cao, Tian-Hui Shen, Jing-Yuan Yao, Gui-Fu Ding
Electrodeposition Nanolaminated Growth Of Zinc, Ying Cao, Tian-Hui Shen, Jing-Yuan Yao, Gui-Fu Ding
Journal of Electrochemistry
Nanolaminated growth of the electrodeposition of zinc was studied. The structure and size of crystalline in zinc coatings were investigated by using FEG-TEM and XRD. The corrosion tests of the zinc deposition and the Coatings-Neutral salt spray test were performed, the capability in corrosion resistance of the nanolaminated growth was better than that of others.