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Nanoscience and Nanotechnology Commons

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Theses/Dissertations

Purdue University

2014

Physical Sciences and Mathematics

Articles 1 - 7 of 7

Full-Text Articles in Nanoscience and Nanotechnology

Advanced Iii-V / Si Nano-Scale Transistors And Contacts: Modeling And Analysis, Seung Hyun Park Oct 2014

Advanced Iii-V / Si Nano-Scale Transistors And Contacts: Modeling And Analysis, Seung Hyun Park

Open Access Dissertations

The exponential miniaturization of Si CMOS technology has been a key to the electronics revolution. However, the continuous downscaling of the gate length becomes the biggest challenge to maintain higher speed, lower power, and better electrostatic integrity for each following generation. Hence, novel devices and better channel materials than Si are considered to improve the metal-oxide-semiconductor field-effect transistors (MOSFETs) device performance. III-V compound semiconductors and multi-gate structures are being considered as promising candidates in the next CMOS technology. III-V and Si nano-scale transistors in different architectures are investigated (1) to compare the performance between InGaAs of III-V compound semiconductors and …


Structural Characterization Of Multimetallic Nanoparticles, Vineetha Mukundan Oct 2014

Structural Characterization Of Multimetallic Nanoparticles, Vineetha Mukundan

Open Access Dissertations

Bimetallic and trimetallic alloy nanoparticles have enhanced catalytic activities due to their unique structural properties. Using in situ time-resolved synchrotron based x-ray diffraction, we investigated the structural properties of nanoscale catalysts undergoing various heat treatments. Thermal treatment brings about changes in particle size, morphology, dispersion of metals on support, alloying, surface electronic properties, etc. First, the mechanisms of coalescence and grain growth in PtNiCo nanoparticles supported on planar silica on silicon were examined in detail in the temperature range 400-900°C. The sintering process in PtNiCo nanoparticles was found to be accompanied by lattice contraction and L10chemical ordering. …


Dynamic Control Of Plasmonic Resonances With Graphene Based Nanostructures, Naresh Kumar Emani Oct 2014

Dynamic Control Of Plasmonic Resonances With Graphene Based Nanostructures, Naresh Kumar Emani

Open Access Dissertations

Light incident on a metallic structure excites collective oscillations of electrons termed as plasmons. These plasmons are useful in control and manipulation of information in nanoscale dimensions and at high operating frequencies. Hence, the field of plasmonics opens up the possibility of developing nanoscale optoelectronic circuitry for computing and sensing applications. One of the challenges in this effort is the lack of tunable plasmonic resonance. Currently, the resonant wavelength of plasmonic structure is fixed by the material and structural parameters. Post-fabrication dynamic control of a plasmonic resonance is rather limited.^ In this thesis we explore the combination of optoelectrical properties …


Optical Spectroscopy And Langmuir Probe Diagnostics Of Microwave Plasma In Synthesis Of Graphene-Based Nanomaterials, Alfredo D. Tuesta Oct 2014

Optical Spectroscopy And Langmuir Probe Diagnostics Of Microwave Plasma In Synthesis Of Graphene-Based Nanomaterials, Alfredo D. Tuesta

Open Access Dissertations

Along with the revolutionary discovery and development of carbon nanostructures, such as carbon nanotubes and graphitic sheets, has arrived the potential for their application in the fields of medicine, bioscience and engineering due to their exceptional structural, thermal and electrical properties. As roll-to-roll plasma deposition systems begin to provide means for large scale production of these nanodevices, a detailed understanding of the environment responsible for their synthesis is imperative in order to more accurately design and control the growth of carbon nanodevices. To date, the understanding of the chemistry and kinetics that govern the synthesis of carbon nanodevices is only …


Nickel Aluminum Shape Memory Alloys Via Molecular Dynamics, Keith Ryan Morrison Jul 2014

Nickel Aluminum Shape Memory Alloys Via Molecular Dynamics, Keith Ryan Morrison

Open Access Theses

Shape memory materials are an important class of active materials with a wide range of applications in the aerospace, biomedical, and automobile industries. These materials exhibit the two unique properties of shape memory and superelasticity. Shape memory is the ability to recover its original shape by applying heat after undergoing large deformations. Superelasticity is the ability to undergo large, reversible deformations (up to 10%) that revert back when the load is removed. These special properties originate from a reversible, diffusionless solid-solid phase transformation that occurs between a high temperature austenite phase and a low temperature martensite phase. The development of …


Synthesis And Characterization Of Crystalline Iron Nanoparticles From Zerovalent Iron Sandwich Complexes, Anh Tue Nguyen Jul 2014

Synthesis And Characterization Of Crystalline Iron Nanoparticles From Zerovalent Iron Sandwich Complexes, Anh Tue Nguyen

Open Access Theses

In this project we present a systematic study on the synthesis of crystalline iron nanocubes by thermal decomposition of an iron sandwich complex, ( π-C5H5)Fe0(π-C 6H7), in the presence of oleylamine and oleylamine.HCl as surfactants and n-decane as a solvent. The presence of oleylamine.HCl is essential for the reproducible formation of crystalline iron cores.^ Reaction parameters such as temperature, surfactant concentration, effect of counterion, and organoiron reagent structure were investigated in order to obtain iron nanoparticles with uniform size and shape. The nanoparticles, which were characterized by …


The Development Of 6.7% Efficient Copper Zinc Indium Selenide Devices From Copper Zinc Indium Sulfide Nanocrystal Inks, Brian Kemp Graeser Apr 2014

The Development Of 6.7% Efficient Copper Zinc Indium Selenide Devices From Copper Zinc Indium Sulfide Nanocrystal Inks, Brian Kemp Graeser

Open Access Theses

As solar cell absorber materials, alloys of CuIn(S,Se)2 and Zn(S,Se) provide an opportunity to reduce the usage of indium along with the ability to tune the band gap. Here we report successful synthesis of alloyed (CuInS2 )0.5(ZnS)0.5 nanocrystals by a method that solely uses oleylamine as the liquid medium for synthesis. The reactive sintering of a thin film of these nanocrystals via selenization at 500 °C results in a uniform composition alloy (CuIn(S,Se)2 )0.5 (Zn(S,Se)) 0.5 layer with micron size grains. Due to the large amount of zinc in the film, the sintered grains exhibit the zinc blende structure instead …