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Articles 1 - 7 of 7
Full-Text Articles in Nanoscience and Nanotechnology
Optical Direct-Write Nanolithography Based On Self-Assembled Resist, Meghana Akella
Optical Direct-Write Nanolithography Based On Self-Assembled Resist, Meghana Akella
Open Access Theses
Holographic display is being developed for next generation mobile phones. However, manufacturing of miniature gratings for the holographic projectors cost a few thousand dollars today, not making the concept practical for commercial purposes. In this thesis, we discuss the feasibility of self-assembled nanoparticles to manufacture holographic gratings cost-effectively and at the nanoscale. Using our approach, the gratings can be manufactured at the scale of 20nm and the cost per chip is expected to cost a few dollars.^ In this thesis, a hydrophobic SAM was used to modify the surface of silicon. Direct-write UV laser lithography was used for photothermal patterning …
Nickel Aluminum Shape Memory Alloys Via Molecular Dynamics, Keith Ryan Morrison
Nickel Aluminum Shape Memory Alloys Via Molecular Dynamics, Keith Ryan Morrison
Open Access Theses
Shape memory materials are an important class of active materials with a wide range of applications in the aerospace, biomedical, and automobile industries. These materials exhibit the two unique properties of shape memory and superelasticity. Shape memory is the ability to recover its original shape by applying heat after undergoing large deformations. Superelasticity is the ability to undergo large, reversible deformations (up to 10%) that revert back when the load is removed. These special properties originate from a reversible, diffusionless solid-solid phase transformation that occurs between a high temperature austenite phase and a low temperature martensite phase. The development of …
Synthesis And Characterization Of Crystalline Iron Nanoparticles From Zerovalent Iron Sandwich Complexes, Anh Tue Nguyen
Synthesis And Characterization Of Crystalline Iron Nanoparticles From Zerovalent Iron Sandwich Complexes, Anh Tue Nguyen
Open Access Theses
In this project we present a systematic study on the synthesis of crystalline iron nanocubes by thermal decomposition of an iron sandwich complex, ( π-C5H5)Fe0(π-C 6H7), in the presence of oleylamine and oleylamine.HCl as surfactants and n-decane as a solvent. The presence of oleylamine.HCl is essential for the reproducible formation of crystalline iron cores.^ Reaction parameters such as temperature, surfactant concentration, effect of counterion, and organoiron reagent structure were investigated in order to obtain iron nanoparticles with uniform size and shape. The nanoparticles, which were characterized by …
Mechanistic Study Of The Hydrothermal Reduction Of Palladium On The Tobacco Mosaic Virus, Oluwamayowa Oluwarotimi Adigun
Mechanistic Study Of The Hydrothermal Reduction Of Palladium On The Tobacco Mosaic Virus, Oluwamayowa Oluwarotimi Adigun
Open Access Theses
Synthesis of nanorods and nanowires is becoming more and more important due to interest in them in a wide range of disciplines. The genetically engineered tobacco mosaic virus (TMV1Cys) provides a template for synthesis of uniform metal nanorods at mild operating conditions and without the use of any expensive technology compared to conventional synthetic methods. The discovery of the hydrothermal synthetic scheme has allowed the production of higher quality nanorods on the TMV template. However, the mechanism for reduction and growth in this process is still not understood. In this paper, the mechanism of synthesis for producing uniform, controllable palladium …
Particle Deposition On Superhydrophobic Surfaces By Sessile Droplet Evaporation, Mercy G. Dicuangco
Particle Deposition On Superhydrophobic Surfaces By Sessile Droplet Evaporation, Mercy G. Dicuangco
Open Access Theses
Prediction and active control of the spatial distribution of particulate deposits obtained from sessile droplet evaporation is essential in ink-jet printing, nanostructure assembly, biotechnology, and other applications that require localized deposits. In recent years, sessile droplet evaporation on bio-inspired superhydrophobic surfaces has become an attractive method for depositing materials on a site-specific, localized region, but is less explored compared to evaporative deposition on hydrophilic surfaces. It is therefore of interest to understand particle deposition during droplet evaporation on superhydrophobic surfaces to enable accurate prediction and tunable control of localized deposits on such surfaces. The purpose of the present work is …
The Development Of 6.7% Efficient Copper Zinc Indium Selenide Devices From Copper Zinc Indium Sulfide Nanocrystal Inks, Brian Kemp Graeser
The Development Of 6.7% Efficient Copper Zinc Indium Selenide Devices From Copper Zinc Indium Sulfide Nanocrystal Inks, Brian Kemp Graeser
Open Access Theses
As solar cell absorber materials, alloys of CuIn(S,Se)2 and Zn(S,Se) provide an opportunity to reduce the usage of indium along with the ability to tune the band gap. Here we report successful synthesis of alloyed (CuInS2 )0.5(ZnS)0.5 nanocrystals by a method that solely uses oleylamine as the liquid medium for synthesis. The reactive sintering of a thin film of these nanocrystals via selenization at 500 °C results in a uniform composition alloy (CuIn(S,Se)2 )0.5 (Zn(S,Se)) 0.5 layer with micron size grains. Due to the large amount of zinc in the film, the sintered grains exhibit the zinc blende structure instead …
Controlling Protein Release Using Biodegradable Microparticles, Benjamin Patrick Kline
Controlling Protein Release Using Biodegradable Microparticles, Benjamin Patrick Kline
Open Access Theses
Research in the field of protein therapeutics has exploded over the past decade and continues to grow in both academia and in industry. Protein drugs have advantages of being highly specific and highly active making them coveted targets for high profile disease states like cancer and multiple sclerosis. Unfortunately, their many advantages are complemented by their obstacles. Because proteins are highly active and highly specific, the window between efficacy and toxicity is very narrow and drug development can be long and arduous. In addition, protein activity is dependent on its specific folding conformation that is easily disrupted by a variety …