Nanoscience and Nanotechnology Commons^™

Ultrasonic Mapping Of Hybrid Additively Manufactured 420 Stainless Steel, Luz D. Sotelo, Haitham Hadidi, Cody S. Pratt, Michael P. Sealy, Joseph A. Turner

Department of Mechanical and Materials Engineering: Faculty Publications

Metal hybrid additive manufacturing (AM) processes are suitable to create complex structures that advance engineering performance. Hybrid AM can be used to create functionally graded materials for which the variation in microstructure and material properties across the domain is created through a synergized combination of fully coupled manufacturing processes and/or energy sources. This expansion in the engineering design and manufacturing spaces presents challenges for nondestructive evaluation, including the assessment of the sensitivity of nondestructive measurements to functional gradients. To address this problem, linear ultrasound measurements are used to interrogate 420 stainless steel coupons from three manufacturing methods: wrought, AM, and …

The Role Of Microenvironmental Cues And Mechanical Loading Milieus In Breast Cancer Cell Progression And Metastasis, Brandon D. Riehl, Eunju Kim, Tasneem Bouzid, Jung Yul Lim

Department of Mechanical and Materials Engineering: Faculty Publications

Cancer can disrupt the microenvironments and mechanical homeostatic actions in multiple scales from large tissue modification to altered cellular signaling pathway in mechanotransduction. In this review, we highlight recent progresses in breast cancer cell mechanobiology focusing on cell-microenvironment interaction and mechanical loading regulation of cells. First, the effects of microenvironmental cues on breast cancer cell progression and metastasis will be reviewed with respect to substrate stiffness, chemical/topographic substrate patterning, and 2D vs. 3D cultures. Then, the role of mechanical loading situations such as tensile stretch, compression, and flow-induced shear will be discussed in relation to breast cancer cell mechanobiology and …

Quantification Of Nitric Oxide Concentration Using Single-Walled Carbon Nanotube Sensors, Jakob Meier, Joseph Stapleton, Eric M. Hofferber, Abigail Haworth, Stephen D. Kachman, Nicole M. Iverson

Department of Mechanical and Materials Engineering: Faculty Publications

Nitric oxide (NO), a free radical present in biological systems, can have many detrimental effects on the body, from inflammation to cancer. Due to NO’s short half-life, detection and quantification is difficult. The inability to quantify NO has hindered researchers’ understanding of its impact in healthy and diseased conditions. Single-walled carbon nanotubes (SWNTs), when wrapped in a specific single-stranded DNA chain, becomes selective to NO, creating a fluorescence sensor. Unfortunately, the correlation between NO concentration and the SWNT’s fluorescence intensity has been difficult to determine due to an inability to immobilize the sensor without altering its properties. Through the use …

Mechanical Behavior Of Al–Al2cu–Si And Al–Al2cu Eutectic Alloys, Qian Lei, Jian Wang, Amitava Mitra

Department of Mechanical and Materials Engineering: Faculty Publications

In this study, laser rapid solidification technique was used to refine the microstructure of ternary Al–Cu–Si and binary Al–Cu eutectic alloys to nanoscales. Micropillar compression testing was performed to measure the stress–strain response of the samples with characteristic microstructure in the melt pool regions. The laser-remelted Al–Al₂Cu–Si ternary alloy was observed to reach the compressive strength of 1.59 GPa before failure at a strain of 28.5%, which is significantly better than the as-cast alloy with a maximum strength of 0.48 GPa at a failure strain of 4.8%. The laser-remelted Al–Cu binary alloy was observed to reach the compressive …

Sensitive X-Ray And Gamma-Ray Detectors Including Perovskite Single Crystals, Jinsong Huang, Haotong Wei

Department of Mechanical and Materials Engineering: Faculty Publications

Perovskite single crystal X-ray and gamma-ray radiation detector devices include an X-ray and gamma-ray wavelength responsive active layer including a perovskite single crystal. The perovskite single crystal is a perovskite single crystal having a structure of ABX₃ , wherein A is methyl ammonium ( CH₂NH₂+), C_S+, formamidinum ( H₂NCHNH₂+) , or Rb⁺ or a mixture thereof, B is Pb²⁺ which can be partially or completely replaced by other ions including Bi³⁺, Sb³⁺, Sn²⁺ or a mixture thereof, and X is a halide …

Surface Strengthening Of Single-Crystal Alumina By High-Temperature Laser Shock Peening, Fei Wang, X. L. Yan, Lei Liu, Michael Nastasi, Yongfeng Lu, Bai Cui

Department of Mechanical and Materials Engineering: Faculty Publications

This manuscript reports a novel process of high-temperature laser shock peening (HTLSP) for surface strengthening of single-crystal ceramics such as sapphire and reveals its fundamental mechanisms. HTLSP at 1200°C can induce a high compressive residual stress on the surface of sapphire while minimize the damage of laser-driven shock waves. Transmission electron microscopy characteriza- tions revealed high dislocation densities near the surface, suggesting that plastic deformation at an ultrahigh strain rate was generated by the high shock wave pressure. The HTLSP-induced compres- sive residual stress can significantly improve the hardness and fracture toughness of sapphire, while maintain its outstanding optical transmittance.

The Role Of Microenvironmental Cues And Mechanical Loading Milieus In Breast Cancer Cell Progression And Metastasis, Brandon D. Riehl, Eunju Kim, Tasneem Bouzid, Jung Yul Lim

Department of Mechanical and Materials Engineering: Faculty Publications

Cancer can disrupt the microenvironments and mechanical homeostatic actions in multiple scales from large tissue modification to altered cellular signaling pathway in mechanotransduction. In this review, we highlight recent progresses in breast cancer cell mechanobiology focusing on cell-microenvironment interaction and mechanical loading regulation of cells. First, the effects of microenvironmental cues on breast cancer cell progression and metastasis will be reviewed with respect to substrate stiffness, chemical/topographic substrate patterning, and 2D vs. 3D cultures. Then, the role of mechanical loading situations such as tensile stretch, compression, and flow-induced shear will be discussed in relation to breast cancer cell mechanobiology and …

A Method Of Identifying Allographs In Undeciphered Scripts And Its Application To The Indus Valley Script, Shruti Daggumati, Peter Revesz

Department of Mechanical and Materials Engineering: Faculty Publications

This work describes a general method of testing for redundancies in the sign lists of ancient scripts by data mining the positions of the signs within the inscriptions. The redundant signs are allographs of the same grapheme. The method is applied to the undeciphered Indus Valley Script, which stands out from other ancient scripts by having a large proposed sign list that contains dozens of asymmetric signs that have mirrored pairs. By a statistical analysis of mirrored asymmetric signs, this paper shows that the Indus Valley Script was multi-directional and the mirroring of signs often denotes only the direction of …

Direct Numerical Simulation Of A Pulsatile Flow In A Stenotic Channel Using Immersed Boundary Method, Siamak Mirfendereski, Jae Sung Park

Department of Mechanical and Materials Engineering: Faculty Publications

A three-dimensional direct numerical simulation model coupled with the immersed boundary method has been developed to simulate a pulsatile flow in a planar channel with single and double one-sided semicircular constrictions. For relevance to blood flow in large arteries, simulations have been performed at Reynolds numbers of 750 and 1000. Flow physics and resultant wall shear stress (WSS)-based hemodynamic parameters are presented. The instantaneous vortex dynamics, mean flow characteristics, and turbulent energy spectra are evaluated for flow physics. Subsequently, three WSS-based parameters, namely the time-averaged WSS, oscillatory shear index, and relative residence time, are calculated over the stenotic wall and …

Perceived Importance Of Aac Messages To Support Communication In Rehabilitation Settings, Susan Koch Fager, Judith M. Burnfield, Chase M Pfeifer, Tabatha Sorenson

Department of Mechanical and Materials Engineering: Faculty Publications

Purpose: Permanent or temporary speech loss can occur due to a variety of medical conditions and often requires individuals to use augmentative and alternative communication (AAC) strategies and technologies to support communication. The use of AAC in medical and rehabilitation settings is critical to ensure the health, safety and psychological well-being of communicatively vulnerable individuals.

Method: This study surveyed the perceived importance of communication messages within five categories (Basic Needs, Patient-Provider Specific Communication, Social, Feelings, and Messages for Young Children) by individuals with disability who have undergone recent medical care as well as by rehabilitation care providers.

Results: Results indicated …

Feasibility Of Motor-Assisted Elliptical To Improve Walking, Fitness And Balance Following Pediatric Acquired Brain Injury: A Case Series, Judith M. Burnfield, Guilherme Manna Cesar, Thad W. Buster

Department of Mechanical and Materials Engineering: Faculty Publications

Purpose: Walking, fitness, and balance deficits are common following acquired brain injury (ABI). This study assessed feasibility, acceptability, and usefulness of a modified motor-assisted elliptical (ICARE) in addressing walking, fitness, and balance deficits in children with chronic ABIs.

Methods: Three children (> 5 years post-ABI) completed 24 ICARE exercise sessions (exercise time, speed, and time overriding motor-assistance gradually increased) to promote mass repetition of gait-like movements and challenge cardiorespiratory fitness. Parents’ and children’s perceptions of ICARE’s safety, comfort, workout, and usability were assessed. Cardiovascular response, gait and balance outcomes were assessed.

Results: No adverse events occurred. Parent’s …

Preperitoneal Insufflation Pressure Of The Abdominal Wall In A Porcine Model, Riley E. Reynolds, Benjamin Wankum, Sean J. Crimmins, Mark A. Carlson, Benjamin S. Terry

Department of Mechanical and Materials Engineering: Faculty Publications

Background Most complications and adverse events during laparoscopic surgery occur during initial entry into the peritoneal cavity. Among them, preperitoneal insufflation occurs when the insufflation needle is incorrectly placed, and the abdominal wall is insufflated. The objective of this study was to find a range for static pressure which is low enough to allow placement of a Veress needle into the peritoneal space without causing preperitoneal insufflation, yet high enough to separate abdominal viscera from the parietal peritoneum.

Methods A pressure test was performed on twelve fresh porcine carcasses to determine the minimum preperitoneal insufflation pressure and the minimum initial …

A Novel Large Animal Model Of Smoke Inhalation-Induced Acute Respiratory Distress Syndrome, Premila D. Leiphrakpam, Hannah R. Weber, Andrea Mccain, Roser Romaguera Matas, Ernesto Martinez Duarte, Keely L. Buesing

Department of Mechanical and Materials Engineering: Faculty Publications

Background: Acute respiratory distress syndrome (ARDS) is multifactorial and can result from sepsis, trauma, or pneumonia, amongst other primary pathologies. It is one of the major causes of death in critically ill patients with a reported mortality rate up to 45%. The present study focuses on the development of a large animal model of smoke inhalation-induced ARDS in an effort to provide the scientific community with a reliable, reproducible large animal model of isolated toxic inhalation injury-induced ARDS. Methods: Animals (n=21) were exposed to smoke under general anesthesia for 1 to 2 h (median smoke exposure=0.5 to 1 L of …

Assembly Of Close-Packed Ferroelectric Polymer Nanowires Via Interface-Epitaxy With Res2, Dawei Li, Shuo Sun, Kun Wang, Zahra Ahmadi, Jeffrey E. Shield, Stephen Ducharme, Xia Hong

Department of Mechanical and Materials Engineering: Faculty Publications

The flexible, transparent, and low-weight nature of ferroelectric polymers makes them promising for wearable electronic and optical applications. To reach the full potential of the polarization-enabled device functionalities, large-scale fabrication of polymer thin films with well-controlled polar directions is called for, which remains a central challenge. The widely exploited Langmuir–Blodgett, spin-coating, and electrospinning methods only yield polymorphous or polycrystalline films, where the net polarization is compromised. Here, an easily scalable approach is reported to achieve poly(vinylidene fluoride-trifluoroethylene) P(VDF-TrFE) thin films composed of close-packed crystalline nanowires via interface-epitaxy with 1T′-ReS₂. Upon controlled thermal treatment, uniform P(VDF-TrFE) films restructure into …

Reducing Corrosion Of Additive Manufactured Magnesium Alloys By Interlayer Ultrasonic Peening, M. P. Sealy, R. Karunakaran, S. Ortgies, G. Madireddy, A. P. Malshe, K. P. Rajurkar

Department of Mechanical and Materials Engineering: Faculty Publications

Additive manufad (AM) magn alloys corrode rapidly due to tensile stress and coarse microstructures. Cyclically combining (hybridizing) additive manufacturing with interlayer ultrasonic peening was proposed as a solution to improve corrosion resistance of additive manufactured magnesium WE43 alloy through strengthening mechanisms and compressive residual stress. Applying interlayer peening work hardened discrete layers and formed a glocal integrity of regional grain refinement and subsurface compressive residual stress barriers. Tensile residual stress that typically accelerates corrosion decreased 90%. Results showed time-resolved control over corrosion was attainable by interlayer peening, and local corrosion within print cells decreased 57% with respect to as-printed WE43.

Use Of Energy Consumption During Milling To Fill A Measurement Gap In Hybrid Additive Manufacturing, K. L. M. Avegnon, P. Noll, M. R. Uddin, G. Madireddy, R. Williams, A. Achuthan, M. P. Sealy

Department of Mechanical and Materials Engineering: Faculty Publications

Coupling additive manufacturing (AM) with interlayer peening introduces bulk anisotropic properties within a build across several centimeters. Current methods to map high resolution anisotropy and heterogeneity are either destructive or have a limited penetration depth using a nondestructive method. An alternative pseudo-nondestructive method to map high-resolution anisotropy and heterogeneity is through energy consumption during milling. Previous research has shown energy consumption during milling correlates with surface integrity. Since surface milling of additively manufactured parts is often required for post-processing to improve dimensional accuracy, an opportunity is available to use surface milling as an alternative method to measure mechanical properties and …

Recurrence Network Analysis Of Design-Quality Interactions In Additive Manufacturing, Ruimin Chen, Prahalada K. Rao, Yan Lu, Edward W. Reutzel, Hui Yang

Department of Mechanical and Materials Engineering: Faculty Publications

Powder bed fusion (PBF) additive manufacturing (AM) provides a great level of flexibility in the design-driven build of metal products. However, the more complex the design, the more difficult it becomes to control the quality of AM builds. The quality challenge persistently hampers the widespread application of AM technology. Advanced imaging (e.g., X-ray computed tomography scans and high-resolution optical images) has been increasingly explored to enhance the visibility of information and improve the AM quality control. Realizing the full potential of imaging data depends on the advent of information processing methodologies for the analysis of design-quality interactions. This paper presents …

Ultra-Fast Charging In Aluminum-Ion Batteries: Electric Double Layers On Active Anode, Xuejing Shen, Tao Sun, Lei Yang, Alexey Krasnoslobodtsev, Renat F. Sabirianov, Michael P. Sealy, Wai-Ning Mei, Zhanjun Wu, Li Tan

Department of Mechanical and Materials Engineering: Faculty Publications

With the rapid iteration of portable electronics and electric vehicles, developing high-capacity batteries with ultra-fast charging capability has become a holy grail. Here we report rechargeable aluminum-ion batteries capable of reaching a high specific capacity of 200 mAh g^−1. When liquid metal is further used to lower the energy barrier from the anode, fastest charging rate of 10⁴ C (duration of 0.35 s to reach a full capacity) and 500% more specific capacity under high-rate conditions are achieved. Phase boundaries from the active anode are believed to encourage a high-flux charge transfer through the electric double layers. As …

Electrostatic Flocking Of Salt-Treated Microfibers And Nanofiber Yarns For Regenerative Engineering, Alec Mccarthy, Kossi Loic M. Avegnon, Phil A. Holubeck, Demi Brown, Anik Karan, Navatha Shree Sharma, Johnson V. John, Shelbie Weihs, Jazmin Ley, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Electrostatic flocking is a textile technology that employs a Coulombic driving force to launch short fibers from a charging source towards an adhesive-covered substrate, resulting in a dense array of aligned fibers perpendicular to the substrate. However, electrostatic flocking of insulative polymeric fibers remains a challenge due to their insufficient charge accumulation. We report a facile method to flock electrostatically insulative poly(ε-caprolactone) (PCL) microfibers (MFs) and electrospun PCL nanofiber yarns (NFYs) by incorporating NaCl during preflock processing. Both MF and NFY were evaluated for flock functionality, mechanical properties, and biological responses. To demonstrate this platform's diverse applications, standalone flocked NFY …

Twinning-Assisted Dynamic Adjustment Of Grain Boundary Mobility, Qishan Huang, Qi Zhu, Yingbin Chen, Mingyu Gong, Jixue Li, Ze Zhang, Wei Yang, Jian Wang, Haofei Zhou, Jiangwei Wang

Department of Mechanical and Materials Engineering: Faculty Publications

Grain boundary (GB) plasticity dominates the mechanical behaviours of nanocrystalline materials. Under mechanical loading, GB configuration and its local deformation geometry change dynamically with the deformation; the dynamic variation of GB deformability, however, remains largely elusive, especially regarding its relation with the frequently-observed GB-associated deformation twins in nanocrystalline materials. Attention here is focused on the GB dynamics in metallic nanocrystals, by means of well-designed in situ nanomechanical testing integrated with molecular dynamics simulations. GBs with low mobility are found to dynamically adjust their configurations and local deformation geometries via crystallographic twinning, which instantly changes the GB dynamics and enhances the …

Process-Structure Relationship In The Directed Energy Deposition Of Cobalt-Chromium Alloy (Stellite 21) Coatings, Ziyad M. Smoqi, Joshua Toddy, Harold (Scott) Halliday, Jeffrey E. Shield, Prahalada K. Rao

Department of Mechanical and Materials Engineering: Faculty Publications

In this work, we accomplished the crack-free directed energy deposition (DED) of a multi-layer Cobalt- Chromium alloy coating (Stellite 21) on Inconel 718 substrate. Stellite alloys are used as coating materials given their resistance to wear, corrosion, and high temperature. The main challenge in DED of Stellite coatings is the proclivity for crack formation during printing. The objective of this work is to characterize the effect of the input energy density and localized laser-based preheating on the characteristics of the deposited coating, namely, crack formation, microstructural evolution, dilution of the coating composition due to diffusion of iron and nickel from …

Ligand Assisted Growth Of Perovskite Single Crystals With Low Defect Density, Ye Liu, Xiaopeng Zheng, Yanjun Fang, Ying Zhou, Zhenyi Ni, Xun Xiao, Shangshang Chen, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

A low defect density in metal halide perovskite single crystals is critical to achieve high performance optoelectronic devices. Here we show the reduction of defect density in per[1]ovskite single crystals grown by a ligand-assisted solution process with 3‐(decyldimethy[1]lammonio)‐propane‐sulfonate inner salt (DPSI) as an additive. DPSI ligands anchoring with lead ions on perovskite crystal surfaces not only suppress nucleation in solution, but also regulate the addition of proper ions to the growing surface, which greatly enhances the crystal quality. The grown CH₃NH₃PbI₃ crystals show better crystallinity and a 23-fold smaller trap density of 7 × 10 …

Large-Scale Synthesis Of Compressible And Re-Expandable Three-Dimensional Nanofiber Matrices, Alec Mccarthy, Lorenzo Saldana, Daniel Mcgoldrick, Johnson V. John, Mitchell Kuss, Shixuan Chen, Bin Duan, Mark A. Carlson, Jingwei Xie

Department of Mechanical and Materials Engineering: Faculty Publications

Due to their biomimetic properties, electrospun nanofibers have shown great potential in many biomedical fields. However, traditionally-produced nanofibers are typically two-dimensional (2D) membranes limiting their applications. Herein, we report a large-scale synthesis of compressible and reexpandable three-dimensional (3D) nanofiber matrices for potential biomedical applications. The reproducible mass production of such matrices is achieved using a multiple-emitter electrospinning machine with a controlled environment (e.g., temperature, humidity, and air flow rate) followed by an innovative gas-foaming expansion. The modified 20-emitter circular array with 3D-printed needle caps is capable of maintaining stable Taylor cones under extremely high flow rates. The introduction of such …

Ultrasound-Activated Ciliary Bands For Microrobotic Systems Inspired By Starfish, Cornel Dillinger, Nitesh Nama, Daniel Ahmed

Department of Mechanical and Materials Engineering: Faculty Publications

Cilia are short, hair-like appendages ubiquitous in various biological systems, which have evolved to manipulate and gather food in liquids at regimes where viscosity dominates inertia. Inspired by these natural systems, synthetic cilia have been developed and utilized in microfluidics and microrobotics to achieve functionalities such as propulsion, liquid pumping and mixing, and particle manipulation. Here, we demonstrate ultrasound-activated synthetic ciliary bands that mimic the natural arrangements of ciliary bands on the surface of starfish larva. Our system leverages nonlinear acoustics at microscales to drive bulk fluid motion via acoustically actuated small-amplitude oscillations of synthetic cilia. By arranging the planar …

Electron Microscopy Observation Of Electric Field-Assisted Sintering Of Stainless Steel Nanoparticles, Fei Wang, Qin Zhou, Xing-Zhong Li, Yongchul Yoo, Michael Nastasi, Bai Cui

Department of Mechanical and Materials Engineering: Faculty Publications

The intrinsic role of electrical current on the electric field-assisted sintering (EFAS) process of stainless steel 316L nanoparticles has been revealed by both ex situ and in situ experiments. A novel device on the Si chip has been designed and fabricated to fit into the sample holder of a transmission electron microscope for these experiments. The evolution of nanoparticle morphology and microstructures during the EFAS process has been studied using scanning electron microscopy and transmission electron microscopy, which has been combined with the simultaneous measurement of the electric voltage and current changes. A preliminary four-stage mechanism for the EFAS process …

Metallic Surface Doping Of Metal Halide Perovskites, Yuze Lin, Yuchuan Shao, Jun Dai, Tao Li, Yi Liu, Xuezeng Dai, Xun Xiao, Yehao Deng, Alexei Gruverman, Xiao Cheng Zeng, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Intentional doping is the core of semiconductor technologies to tune electrical and optical properties of semiconductors for electronic devices, however, it has shown to be a grand challenge for halide perovskites. Here, we show that some metal ions, such as silver, strontium, cerium ions, which exist in the precursors of halide perovskites as impurities, can n-dope the surface of perovskites from being intrinsic to metallic. The low solubility of these ions in halide perovskite crystals excludes the metal impurities to perovskite surfaces, leaving the interior of perovskite crystals intrinsic. Computation shows these metal ions introduce many electronic states close to …

Nondestructive Evaluation Of Aluminium Foam Panels Subjected To Impact Loading, Gabriella Epasto, Fabio Distefano, Hozhabar Mozafari, Emanoil Linul, Vincenzo Crupi

Department of Mechanical and Materials Engineering: Faculty Publications

Aluminium foam sandwich structures have excellent energy absorption capacity, combined with good mechanical properties and low density. Some of the authors of this paper proposed an innovative Metallic Foam Shell protective device against flying ballast impact damage in railway axles. A closed-cell aluminium foam was chosen for the Metallic Foam Shell device. The main goal of this study was the experimental investigation of the impact responses of aluminium foam panels. Low velocity impact tests were carried out at different energies on different types of aluminium foam panels in order to investigate the effects of some parameters, such as core thickness, …

Recent Advances In Preparation And Testing Methods Of Engine-Based Nanolubricants: A State-Of-The-Art Review, Sayed Akl, Sherif Elsoudy, Ahmed A. Abdel-Rehim, Serag Salem, Mark Ellis

Mechanical Engineering

Reducing power losses in engines is considered a key parameter of their efficiency improvement. Nanotechnology, as an interface technology, is considered one of the most promising strategies for this purpose. As a consumable liquid, researchers have studied nanolubricants through the last decade as potential engine oil. Nanolubricants were shown to cause a considerable reduction in the engine frictional and thermal losses, and fuel consumption as well. Despite that, numerous drawbacks regarding the quality of the processed nanolubricants were discerned. This includes the dispersion stability of these fluids and the lack of actual engine experiments. It has been shown that the …

Social Connectedness And Negative Affect Uniquely Explain Individual Differences In Response To Emotional Ambiguity, Maital Neta, Rebecca L. Brock

Department of Mechanical and Materials Engineering: Faculty Publications

Negativity bias is not only central to mood and anxiety disorders, but can powerfully impact our decision-making across domains (e.g., financial, medical, social). This project builds on previous work examining negativity bias using dual-valence ambiguity. Specifically, although some facial expressions have a relatively clear negative (angry) or positive valence (happy), surprised expressions are interpreted negatively by some and positively by others, providing insight into one’s valence bias. Here, we examine putative sources of variability that distinguish individuals with a more negative versus positive valence bias using structural equation modeling. Our model reveals that one’s propensity toward negativity (operationalized as temperamental …