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Improvement Of Electrical Properties Of Cmc-Pva Doped With Various Contents Of Lino3 As An Application For Hybrid Polymer Electrolytes, Amalia Zulkifli, Norfatihah Mazuki, Ahmad Salihin Samsudin
Improvement Of Electrical Properties Of Cmc-Pva Doped With Various Contents Of Lino3 As An Application For Hybrid Polymer Electrolytes, Amalia Zulkifli, Norfatihah Mazuki, Ahmad Salihin Samsudin
Makara Journal of Technology
The present work was carried out with the development of hybrid polymer electrolytes (HPEs) by using carboxymethyl cellulose (CMC)–polyvinyl alcohol (PVA) doped with different contents of lithium nitrate (LiNO3) for the determination of their structural and conduction properties. The structural analysis was conducted by using Fourier transform infra-red spectroscopy and showed the interaction between the blend host polymer and ionic dopant, which formed via the coordinating site of CMC-PVA and Li+-NO3−. The complexes of CMC-PVA doped LiNO3 led to an increment in ionic conductivity, as observed by electrical impedance spectroscopy, and the sample containing 20 wt% LiNO3 obtained the highest …
Influence Of Lithium Bromide On Electrical Properties In Bio-Based Polymer Electrolytes, Ahmad Faizrin Fuzlin, Bouchta Sahraoui, Ahmad Salihin Samsudin
Influence Of Lithium Bromide On Electrical Properties In Bio-Based Polymer Electrolytes, Ahmad Faizrin Fuzlin, Bouchta Sahraoui, Ahmad Salihin Samsudin
Makara Journal of Technology
This research presents the influence of lithium bromide (LiBr) on the electrical properties of alginate in bio-based polymer electrolytes (BBPEs) system. Bio-based alginate was prepared using the solution casting technique with various LiBr compositions. The ionic conductivity and electrical properties of the prepared BBPEs samples were studied using electrical impedance spectroscopy over a frequency range of 50 Hz–1 MHz. A maximum ionic conductivity of 7.46 × 10−5 S cm-1 was obtained for a sample containing 15 wt. % lithium bromide-doped alginate BBPEs at ambient temperature (303 K). The electrical analysis revealed that the most conductive sample based on alginate-LiBr BBPEs …
Ionic Conductivity And Electrochemical Properties Of Alginate–Nn4no3-Based Biopolymer Electrolytes For Edlc Application, Norfatihah Binti Mazuki, Nur Muhitul Jalilah Rasali, Bouchta Sahraoui, Ahmad Salihin Samsudin
Ionic Conductivity And Electrochemical Properties Of Alginate–Nn4no3-Based Biopolymer Electrolytes For Edlc Application, Norfatihah Binti Mazuki, Nur Muhitul Jalilah Rasali, Bouchta Sahraoui, Ahmad Salihin Samsudin
Makara Journal of Technology
In this work, alginate doped with various contents of ammonium nitrate (NH4NO3) as a solid biopolymer electrolyte (SBE) was prepared via casting by using distilled water as a solvent. Impedance studies on alginate–NH4NO3 SBE films were conducted via impedance spectroscopy. The lowest bulk resistance (Rb) showed that the maximum ionic conductivity of the sample containing 25 wt.% NH4NO3 at ambient temperature (303 K) was 5.56 × 10−5 S cm−1. The temperature dependence of ionic conductivity was evaluated, and results confirmed that electrolytes followed an Arrhenius behavior. The highest conducting sample was fabricated into an electrical double-layer capacitor and characterized in …
Influence Of Nh4f In Dextran Based Biopolymer Electrolytes: Conductivity And Electrical Analysis, Muhamad Hafiz Hamsan, Mohd Fakhrul Zamani Kadir, Shujahadeen Bakar Aziz, Muhammad Amirul Solihin Azha, Saifful Kamaluddin Muzakir
Influence Of Nh4f In Dextran Based Biopolymer Electrolytes: Conductivity And Electrical Analysis, Muhamad Hafiz Hamsan, Mohd Fakhrul Zamani Kadir, Shujahadeen Bakar Aziz, Muhammad Amirul Solihin Azha, Saifful Kamaluddin Muzakir
Makara Journal of Technology
Dextran polymer host was doped with different concentrations of ammonium fluoride (NH4F) via casting technique. In this present work, dextran-NH4F film has been employed to investigate the ionic conductivity using electrochemical impedance spectroscopy from 50 to 5 MHz. The highest room temperature conductivity is achieved at (2.33 ± 0.76) × 10-3 S cm-1 with 40 wt.% NH4F. The electrolyte is found to obey Arrhenius rule at high temperature with activation energy of 0.21 eV. Dielectric analysis has been performed to obtain better understanding on the conductivity pattern. The dielectric parameters e.g. ɛreal, ɛimag, Mreal, and Mimag have been tested as …
Molecularly Conductive Behavior Of Blended Polymer Electrolyte-Based Cmc/Pva, Noor Saadiah Mohd Ali, Dishen Zhang, Yuki Nagao, Ahmad Salihin Samsudin
Molecularly Conductive Behavior Of Blended Polymer Electrolyte-Based Cmc/Pva, Noor Saadiah Mohd Ali, Dishen Zhang, Yuki Nagao, Ahmad Salihin Samsudin
Makara Journal of Technology
This study investigated the electrical conduction and structural behavior of blended polymer electrolyte (BPE)-based carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) in the development of solid-state electrochemical devices. Based on impedance spectroscopy and correlating Fourier transform infrared (FTIR) with thermogravimetric analysis, a framework was proposed to explain the structural enhancement of the BPE system. As revealed by FTIR, the optimum conductivity of CMC/PVA BPEs was 9.21 × 10−6 Scm−1 for 80:20 composition attributed to the intermolecular attraction between the polymers. Thermal stability of the CMC/PVA was influenced by the formation of a hydrogen bond between the hydroxyl (-OH), carboxylate (-COO-), …
A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin
A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin
Makara Journal of Technology
The characterization of biopolymer-based solid polymer electrolytes (SPEs) has been carried out in this present work. Cellulose derivative was chosen due to its superior physical attributes. In this work, NH4Br-doped glycerol plasticized carboxyl methylcellulose-based SPEs were successfully prepared via the solution casting method. The conductivity and dielectric properties of the prepared films were investigated using the impedance analysis which presented ~1.91×10-3 Scm-1 (with addition of 6 wt% of glycerol). In addition, the studied SPE system shows a non-Debye behaviour without a single relaxation time. The findings of the research indicate that the complexes of NH4Br and glycerol in the cellulose …
Influence Of Polyethylene Glycol (Peg) In Cmc-Nh4br Based Polymer Electrolytes: Conductivity And Electrical Study, Nur Khalidah Zainuddin, Ahmad Salihin Samsudin
Influence Of Polyethylene Glycol (Peg) In Cmc-Nh4br Based Polymer Electrolytes: Conductivity And Electrical Study, Nur Khalidah Zainuddin, Ahmad Salihin Samsudin
Makara Journal of Technology
The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable …
Thermal And -Γ –Ray Irradiation Effects On The Ionic Conductivity Of (Licl)X(Montmorillonite)1-X, Safei Purnama, Aziz Khan Jahja, Takeshi Sakuma
Thermal And -Γ –Ray Irradiation Effects On The Ionic Conductivity Of (Licl)X(Montmorillonite)1-X, Safei Purnama, Aziz Khan Jahja, Takeshi Sakuma
Makara Journal of Technology
Compositesof montmorillonite (MMT) - lithium salts have been prepared using a simple process of powders mixing followed by heating. The powders resulting from this method are expected to beionic conductors with a high ionic conductivity characteristics. This characteristics is also further improved by employing gamma-ray irradiation technique at specified irradiation doses. The best results were obtained for the (LiCl)0.5(MMT)0.5 composite with a room temperature ionic conductivity of 2.192 mS/cm, which then increases to ~5 mS/cm after gamma irradiation at a dose of 400 kGy. This value is equivalent to the value of the ionic conductivity of current commercial rechargeable lithium …